Fickle Reactivity of Allenes in Transition-Metal-Catalyzed C−H Functionalizations

Cobalt-Catalyzed Annulation Reactions via C−H Bond Activation

(2018) Sekar Prakash et al.   ChemCatChem

Bisannulation of Benzamides and Cyclohexadienone-Tethered Allenes Triggered by Cp*Rh(III)-Catalyzed C–H Activation and Relay Ene Reaction

(2018) De-Shen Kong et al.   ORGANIC LETTERS

Synthesis of 1,2-Dihydroquinolines by Co(III)-Catalyzed [3 + 3] Annulation of Anilides with Benzylallenes

(2018) Ramajayam Kuppusamy et al.   ACS Catalysis

Palladium-Catalyzed Oxidative Annulation of ortho-Alkenylanilines and Allenes: An Access to Benzo[b]azepines

(2017) Lisha Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Manganese(I)-Catalyzed Direct C–H Allylation of Arenes with Allenes

(2017) Shi-Yong Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Formal (5 + 2) Annulation between ortho-Alkenylanilides and Allenes

(2017) Borja Cendón et al.   ORGANIC LETTERS

Regioselective Annulation of Aryl Sulfonamides with Allenes through Cobalt-Promoted C–H Functionalization

(2017) Tianlong Lan et al.   ORGANIC LETTERS

Dienyl esters synthesis: Palladium-catalyzed C–H olefination of electron-deficient alkenes with allenoates

(2017) Xiao-Feng Xia et al.   TETRAHEDRON

Cobalt(III)-Catalyzed Hydroarylation of Allenes via C–H Activation

(2017) Sachiyo Nakanowatari et al.   ACS Catalysis

Recent advances in catalytic asymmetric synthesis of allenes

(2017) Wen-Dao Chu et al.   Catalysis Science & Technology

Synthesis of Phosphaisoquinolin-1-one by Annulation of Aryl Phosphinamides with Allenes through a Cobalt-Promoted C−H Functionalization

(2017) Xia Yao et al.   Asian Journal of Organic Chemistry

Cobalt-catalyzed C–H activation and regioselective intermolecular annulation with allenes

(2017) Tianlei Li et al.   Organic Chemistry Frontiers

Metal-Catalyzed Annulations through Activation and Cleavage of C−H Bonds

(2016) Moisés Gulías et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed sp2 -C−H Activation: Intermolecular Heterocyclization with Allenes at Room Temperature

(2016) Neetipalli Thrimurtulu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Regiocontrolled Coupling of Aromatic and Vinylic Amides with α-Allenols To Form γ-Lactams via Rhodium(III)-Catalyzed C–H Activation

(2016) Zhi Zhou et al.   ORGANIC LETTERS

C–H bond activation in the total syntheses of natural products

(2016) Pengyu Tao et al.   Science China-Chemistry

Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome

(2016) Noelia Casanova et al.   ACS Catalysis

Cobalt(III)-Catalyzed [5 + 1] Annulation for 2H-Chromenes Synthesis via Vinylic C–H Activation and Intramolecular Nucleophilic Addition

(2016) Ramajayam Kuppusamy et al.   ACS Catalysis

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Rhodium-Catalyzed (5+1) Annulations Between 2-Alkenylphenols and Allenes: A Practical Entry to 2,2-Disubstituted 2H-Chromenes

(2015) Noelia Casanova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrative Direct CH Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis

(2015) Yudai Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates

(2015) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions

(2015) Luis C. Misal Castro et al.   CHEMISTRY LETTERS

Ruthenium(II)-Catalyzed CH Functionalizations with Allenes: Versatile Allenylations and Allylations

(2015) Sachiyo Nakanowatari et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed [4+1] Annulation of Aromatic and Vinylic Carboxylic Acids with Allenes: An Efficient Method Towards Vinyl-Substituted Phthalides and 2-Furanones

(2015) Parthasarathy Gandeepan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Density Functional Theory Study of Rh(III)-Catalyzed C–H Activations and Intermolecular Annulations between Benzamide Derivatives and Allenes

(2015) Zhong Xing et al.   INORGANIC CHEMISTRY

RhIII-Catalyzed [4 + 1] Annulations of 2-Hydroxy- and 2-Aminobenzaldehydes with Allenes: A Simple Method toward 3-Coumaranones and 3-Indolinones

(2015) Ramajayam Kuppusamy et al.   ORGANIC LETTERS

Rhodium-catalyzed C–H functionalization-based approach to eight-membered lactams

(2015) Shangze Wu et al.   Chemical Science

A C–H bond activation-based catalytic approach to tetrasubstituted chiral allenes

(2015) Shangze Wu et al.   Nature Communications

Palladium-Catalyzed Cyclization Reactions of Allenes in the Presence of Unsaturated Carbon–Carbon Bonds

(2014) Juntao Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

The conversion of allenes to strained three-membered heterocycles

(2014) C. S. Adams et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2014) Xiao-Feng Xia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic C–H Activation of Phenylethylamines or Benzylamines and Their Annulation with Allenes

(2014) Aleix Rodríguez et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Dearomatizing (3 + 2) Annulation of 2-Alkenylphenols and Alkynes

(2014) Andrés Seoane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed C–H Activation with Allenes To Synthesize Conjugated Olefins

(2014) Tian-Jun Gong et al.   ORGANIC LETTERS

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Arene CH Bond Functionalization Coupling with Cyclization of Allenes

(2013) Rong Zeng et al.   ADVANCED SYNTHESIS & CATALYSIS

[3]Dendralene Synthesis: Rhodium(III)-Catalyzed Alkenyl CH Activation and Coupling Reaction with Allenyl Carbinol Carbonate

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Allenes by the [3+2] Annulation of Aryl Ketimines

(2013) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition metal-catalyzed Cvinyl–Cvinyl bond formation via double Cvinyl–H bond activation

(2013) Xiaojie Shang et al.   CHEMICAL SOCIETY REVIEWS

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Ortho-Allylation of Aromatic Carboxamides with Allyl Ethers

(2013) Sobi Asako et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature Synthesis of Trisubstituted Allenylsilanes via Regioselective C–H Functionalization

(2013) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Straightforward Assembly of Benzoxepines by Means of a Rhodium(III)-Catalyzed C–H Functionalization of o-Vinylphenols

(2013) Andrés Seoane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Catalytic Syntheses of Allenes: A Critical Assessment

(2013) Robynne K. Neff et al.   ACS Catalysis

Dendralenes Branch Out: Cross-Conjugated Oligoenes Allow the Rapid Generation of Molecular Complexity

(2012) Henning Hopf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2012) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Activation: A Complementary Tool in the Total Synthesis of Complex Natural Products

(2012) David Y.-K. Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Annulation of Allenes with Indole-2-carboxylic Acid Derivatives: Synthesis of Indolo[2,3-c]pyrane-1-ones via Ar–I Reactivity or C–H Functionalization

(2012) R. Rama Suresh et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides with Allenes

(2012) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes

(2011) Shilu Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Gold-Catalyzed Nucleophilic Cyclization of Functionalized Allenes: A Powerful Access to Carbo- and Heterocycles

(2011) Norbert Krause et al.   CHEMICAL REVIEWS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

syn-Selective Rhodium(I)-Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence

(2010) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[PdCl2(MeCN)2]-Catalyzed Highly Regio- and Stereoselective Allylation of Electron-Rich Arenes with 2,3-Allenoates

(2010) Zhao Fang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Allenes as Three-Carbon Units in Catalytic Cycloadditions: New Opportunities with Transition-Metal Catalysts

(2010) Fernando López et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhenium-Catalyzed Diastereoselective Synthesis of Aminoindanes via the Insertion of Allenes into a C−H Bond

(2010) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Metal-Catalyzed Allylation of Organoboranes and Organoboronic Acids

(2010) F. Pigge   SYNTHESIS-STUTTGART

Electrophilic Addition and Cyclization Reactions of Allenes

(2009) Shengming Ma   ACCOUNTS OF CHEMICAL RESEARCH

2-Arylbenzofuran Derivatives fromMorus cathayana

(2009) Gang Ni et al.   JOURNAL OF NATURAL PRODUCTS

Dinuclear Gold−Silver Resting States May Explain Silver Effects in Gold(I)-Catalysis

(2009) Dieter Weber et al.   ORGANIC LETTERS

Direct Prenylation of Aromatic and α,β-Unsaturated Carboxamides via Iridium-Catalyzed C−H Oxidative Addition−Allene Insertion

(2009) Yong Jian Zhang et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Intramolecular Hydroarylation of Allenes

(2008) Michael A. Tarselli et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold(I)-catalyzed intermolecular hydroarylation of allenes with nucleophilic arenes: scope and limitations

(2008) Michael A. Tarselli et al.   TETRAHEDRON