Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation

Catalytic asymmetric trifluoromethylthiolation via enantioselective [2,3]-sigmatropic rearrangement of sulfonium ylides

(2017) Zhikun Zhang et al.   Nature Chemistry

Chiral Selenide-Catalyzed Enantioselective Construction of Saturated Trifluoromethylthiolated Azaheterocycles

(2017) Jie Luo et al.   ORGANIC LETTERS

Enantioselective Squaramide-Catalyzed Trifluoromethylthiolation–Sulfur–Michael/Aldol Cascade Reaction: One-Pot Synthesis of CF3S-Containing Spiro Cyclopentanone–Thiochromanes

(2017) Bo-Liang Zhao et al.   ORGANIC LETTERS

Development of Chalcogenide Catalysts towards Trifluoromethylthiolation

(2017) Xiaodan Zhao et al.   SYNLETT

Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide

(2016) Xiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

(2016) Xing-Ping Zeng et al.   CHEMICAL REVIEWS

Monomeric Cinchona Alkaloid-Based Catalysts for Highly Enantioselective Bromolactonisation of Alkynes

(2016) Michael Wilking et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selenide-Catalyzed Stereoselective Construction of Tetrasubstituted Trifluoromethylthiolated Alkenes with Alkynes

(2016) Jin-Ji Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation

(2016) Satobhisha Mukherjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intramolecular Desymmetric Aryl CO Coupling for the Enantioselective Construction of Chiral Dihydrobenzofurans and Dihydrobenzopyrans

(2015) Wenqiang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Enantioselective Desymmetrization of 1,3-Diols through Intramolecular Hydroalkoxylation of Allenes

(2015) Weiwei Zi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Oxidative Aliphatic CH Trifluoromethylthiolation

(2015) Shuo Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Intermolecular Desymmetrization of Azetidines

(2015) Zhaobin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zirconium-Catalyzed Desymmetrization of Aminodialkenes and Aminodialkynes through Enantioselective Hydroamination

(2015) Kuntal Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

(2015) Jie Luo et al.   ORGANIC LETTERS

Nonenzymatic enantioselective synthesis of all-carbon quaternary centers through desymmetrization

(2015) Kimberly S. Petersen   TETRAHEDRON LETTERS

Enantioselective Copper-Catalyzed Carboetherification of Unactivated Alkenes

(2014) Michael T. Bovino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Arylative Cyclization of Alkynones by 1,4-Iridium Migration

(2014) Benjamin M. Partridge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Access to Polycyclic Derivatives by Triflate-Catalyzed Intramolecular Hydroarylation

(2014) Bastien Cacciuttolo et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Lewis Base Catalyzed, Enantioselective, Intramolecular Sulfenoamination of Olefins

(2014) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acid Catalyzed Highly Enantioselective Desymmetrization of 2-Substituted and 2,2-Disubstituted 1,3-Diols via Oxidative Cleavage of Benzylidene Acetals

(2014) Shan-Shui Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Bromoetherification and Desymmetrization of Olefinic 1,3-Diols with C2-Symmetric Sulfides

(2014) Zhihai Ke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins. Mechanistic Aspects: A Remarkable Case of Negative Catalysis

(2014) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic, crystallographic and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes

(2014) Scott E. Denmark et al.   Nature Chemistry

In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles

(2014) Xing-Li Zhu et al.   ORGANIC LETTERS

Sandmeyer trifluoromethylthiolation of arenediazonium salts with sodium thiocyanate and Ruppert–Prakash reagent

(2014) Grégory Danoun et al.   Chemical Science

Desymmetrization ofmeso-2,5-Diallylpyrrolidinyl Ureas through Asymmetric Palladium-Catalyzed Carboamination: Stereocontrolled Synthesis of Bicyclic Ureas

(2013) Nicholas R. Babij et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis

(2013) Xueqiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF3-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation

(2013) Teerawut Bootwicha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CH Arylation Strategy for Functionalized Dibenzazepinones with Quaternary Stereocenters

(2013) Tanguy Saget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Enantioselective, and Highly Chemoselective Bromocyclization of Olefinic Dicarbonyl Compounds

(2013) Yi Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Fluorinated α-Sulfonyl Carbanions: Enantioselective Synthesis and Electrophilic Capture, Racemization Dynamics, and Structure

(2013) Gunther Hellmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations

(2013) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins. Preparative and Stereochemical Aspects

(2013) Scott E. Denmark et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins

(2013) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective, Desymmetrizing Bromolactonization of Alkynes

(2013) Michael Wilking et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

(2013) Xiu-Fen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C2-Symmetric Cyclic Selenium-Catalyzed Enantioselective Bromoaminocyclization

(2013) Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters

(2013) Yu-Dong Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anion-Induced Enantioselective Cyclization of Diynamides to Pyrrolidines Catalyzed by Cationic Gold Complexes

(2012) Asmaa Kamal Mourad et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrisation of meso-diols mediated by non-enzymatic acyl transfer catalysts

(2012) Álvaro Enríquez-García et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Intramolecular Alkene Carboetherification: Synthesis of Fused-Ring and Bridged-Ring Tetrahydrofurans

(2012) Yan Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Desymmetrization: Synthesis of Five-Membered-Ring Compounds Containing All-Carbon Quaternary Stereocenters

(2012) Kohsuke Aikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Flexible Gold-Catalyzed Regioselective Oxidative Difunctionalization of Unactivated Alkenes

(2011) Teresa de Haro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via Desymmetrization of 2,2-Disubstituted 1,3-Propanediols

(2011) Ji Young Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desymmetrization of cyclohexadienones via cinchonine derived thiourea-catalyzed enantioselective aza-Michael reaction and total synthesis of (-)-Mesembrine

(2011) Qing Gu et al.   Chemical Science

Preparative and Mechanistic Studies toward the Rational Development of Catalytic, Enantioselective Selenoetherification Reactions

(2010) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Copper-Catalyzed Intramolecular Carboamination of Alkenes for the Synthesis of Hexahydro-1H-benz[f]indoles

(2010) Lei Miao et al.   ORGANIC LETTERS

Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes

(2009) Aurélien Ferry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

Enantioselective CC Bond Activation of Allenyl Cyclobutanes: Access to Cyclohexenones with Quaternary Stereogenic Centers

(2008) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Catalysis in Organic Synthesis

(2008) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION