Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide

Direct Trifluoromethylthiolation of Unactivated C(sp3)H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate

(2015) Hao Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Oxidative Aliphatic CH Trifluoromethylthiolation

(2015) Shuo Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective access to CF3S-substituted dihydrofurans from homopropargylic alcohols with trifluoromethanesulfenamide

(2015) Dao-Qian Chen et al.   CHEMICAL COMMUNICATIONS

Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

(2015) Tao Yang et al.   CHEMICAL COMMUNICATIONS

Mild and Soft Catalyzed Trifluoromethylthiolation of Boronic Acids: The Crucial Role of Water

(2015) Quentin Glenadel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Vinyl Trifluoromethyl Thioethers via Copper-Mediated Trifluoromethylthiolation of Vinyl Bromides

(2015) Yangjie Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed

(2015) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic and Highly Enantioselective Selenolactonization

(2015) Wenxue Niu et al.   ORGANIC LETTERS

Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

(2015) Jie Luo et al.   ORGANIC LETTERS

Lewis Acid Mediated Trifluoromethylthio Lactonization/Lactamization

(2015) Chunfa Xu et al.   ORGANIC LETTERS

Trifluoromethylthiolation of Allylsilanes and Silyl Enol Ethers with Trifluoromethanesulfonyl Hypervalent Iodonium Ylide under Copper Catalysis

(2015) Sadayuki Arimori et al.   ORGANIC LETTERS

N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

(2014) Chunfa Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf-StableN-(trifluoromethylthio)phthalimide

(2014) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

(2014) Jian-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

(2014) Jie Sheng et al.   CHEMICAL COMMUNICATIONS

Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

(2014) Quentin Lefebvre et al.   CHEMICAL COMMUNICATIONS

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization

(2014) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective and Scalable Synthesis of Trifluoromethanesulfenamides and Fluorinated Unsymmetrical Disulfides using a Shelf-Stable Electrophilic SCF3Reagent

(2014) Roman Pluta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrophilic Trifluoromethylthiolation of Carbonyl Compounds

(2014) Sébastien Alazet et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Trifluoromethylthiolation of Alcohols under Mild Reaction Conditions: Conversion of ROH into RSCF3

(2014) Pavlo Nikolaienko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trifluoromethyl Ethers and –Thioethers as Tools for Medicinal Chemistry and Drug Discovery

(2014) Gregory Landelle et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Lewis Base Catalyzed, Enantioselective, Intramolecular Sulfenoamination of Olefins

(2014) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins. Mechanistic Aspects: A Remarkable Case of Negative Catalysis

(2014) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Facile and General Approach to 3-((Trifluoromethyl)thio)-4H-chromen-4-one

(2014) Haoyue Xiang et al.   ORGANIC LETTERS

Copper-Catalyzed Direct Trifluoromethylthiolation of Benzylic C–H Bonds via Nondirected Oxidative C(sp3)–H Activation

(2014) Chao Chen et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylthiolation of Aryl Halides with Diverse Directing Groups

(2014) Jiabin Xu et al.   ORGANIC LETTERS

Palladium-Catalyzed Trifluoromethylthiolation of Aryl C–H Bonds

(2014) Chunfa Xu et al.   ORGANIC LETTERS

Copper-Catalyzed Synthesis of α-Trifluoromethylthio-Substituted Ketones

(2014) Yangjie Huang et al.   ORGANIC LETTERS

In Situ Generation of Electrophilic Trifluoromethylthio Reagents for Enantioselective Trifluoromethylthiolation of Oxindoles

(2014) Xing-Li Zhu et al.   ORGANIC LETTERS

Copper-Catalyzed Intramolecular Oxytrifluoromethylthiolation of Unactivated Alkenes

(2014) Liping Zhu et al.   ORGANIC LETTERS

Silver-Mediated Radical Aryltrifluoromethylthiolaton of Activated Alkenes

(2014) Feng Yin et al.   ORGANIC LETTERS

A mild and fast photocatalytic trifluoromethylation of thiols in batch and continuous-flow

(2014) Natan J. W. Straathof et al.   Chemical Science

Copper-catalyzed trifluoromethylthiolation of aryl and vinyl boronic acids with a shelf-stable electrophilic trifluoromethylthiolating reagent

(2014) Kai Kang et al.   Organic Chemistry Frontiers

Formation of CSCF3Bonds through Direct Trifluoromethylthiolation

(2013) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

(2013) Sébastien Alazet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Electrophilic Trifluoromethylthiolation of β-Ketoesters: A Case of Reactivity and Selectivity Bias for Organocatalysis

(2013) Xueqiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF3-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation

(2013) Teerawut Bootwicha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Enantioselective, and Highly Chemoselective Bromocyclization of Olefinic Dicarbonyl Compounds

(2013) Yi Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethyl Thiolation-Mild and Efficient Synthesis of Trifluoromethyl Thioethers

(2013) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations

(2013) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins

(2013) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C2-Symmetric Cyclic Selenium-Catalyzed Enantioselective Bromoaminocyclization

(2013) Feng Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters

(2013) Yu-Dong Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Trifluoromethylthiolation of Allylsilanes with Trifluoromethanesulfanamide

(2013) Jianbo Liu et al.   ORGANIC LETTERS

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Air-Stable Copper Reagent for Nucleophilic Trifluoromethylthiolation of Aryl Halides

(2012) Zhiqiang Weng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Asymmetric Halofunctionalization of Alkenes-A Critical Perspective

(2012) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sequential Electrophilic Trifluoromethanesulfanylation–Cyclization of Tryptamine Derivatives: Synthesis of C(3)-Trifluoromethanesulfanylated Hexahydropyrrolo[2,3-b]indoles

(2012) Yi Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Bromoaminocyclization Using Amino–Thiocarbamate Catalysts

(2011) Ling Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Bromolactonization Using Amino-thiocarbamate Catalyst

(2010) Ling Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparative and Mechanistic Studies toward the Rational Development of Catalytic, Enantioselective Selenoetherification Reactions

(2010) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes

(2009) Aurélien Ferry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New trends in the chemistry of α-fluorinated ethers, thioethers, amines and phosphines

(2009) Baptiste Manteau et al.   JOURNAL OF FLUORINE CHEMISTRY

Microwave-assisted aliphatic fluorine–chlorine exchange using triethylamine trihydrofluoride (TREAT-HF)

(2009) Jennifer M. Kremsner et al.   TETRAHEDRON LETTERS

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of Trifluoromethanesulfinamidines and -sulfanylamides

(2008) Aurélien Ferry et al.   JOURNAL OF ORGANIC CHEMISTRY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS