期刊
MATERIALS LETTERS
卷 210, 期 -, 页码 363-365出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.matlet.2017.09.065
关键词
Carbon materials; Nanoparticles; Sol-gel preparation; Lithium-ion batteries; Energy storage and conversion
资金
- National Natural Science Foundation of China [21574095, 51473106]
- Suzhou Science-Technology-Development Plan (nano special) [ZXG201415]
It's meaningful to design and fabricate novel high-performance carbon anode materials for lithium ion batteries (LIBs). Herein, 3-aminophenol-formaldehyde resin/silica nanorods were synthesized via a sol-gel transcription method, using cetyltrimethyl ammonium bromide as the template and pentanol as co-structure directing agent. After carbonization at 600 degrees C and removal of silica, carbonaceous nanorods with N content of 7.87 wt% and specific surface area of 551.3 m(2) g(-1) were obtained. They showed a stable discharge capacity of 696.7 mAh g(-1) after 400 cycles. Carbonaceous nanorods (comprising 9.6 wt% b-SiC) with N content of 1.22 wt% and specific surface area of 1079.1 m(2) g(-1) were also obtained at 1400 degrees C. They showed a stable discharge capacity of 457.9 mAh g(-1) after 400 cycles. The results prove that the synthesized N-doped carbonaceous nanorods are good anode candidates for LIBs. (C) 2017 Elsevier B.V. All rights reserved.
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