A Bird's Eye View of Atropisomers Featuring a Five-Membered Ring

Enantioselective Alkyne Conjugate Addition Enabled by Readily Tuned Atropisomeric P,N-Ligands

(2017) Sourabh Mishra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy

(2017) Vivek S. Raut et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic asymmetric arylation of indoles enabled by azo groups

(2017) Liang-Wen Qi et al.   Nature Chemistry

Controlling the C(sp3)–C(sp2) Axial Conformation in the Enantioselective Friedel–Crafts-Type Alkylation of β-Naphthols with Inden-1-ones

(2017) Nicola Di Iorio et al.   ORGANIC LETTERS

Phosphine-Catalyzed Asymmetric (3+2) Annulations of δ-Acetoxy Allenoates with 2-Naphthols

(2017) Dong Wang et al.   ORGANIC LETTERS

Incorporation of Axial Chirality into Phosphino-Imidazoline Ligands for Enantioselective Catalysis

(2017) Paulo H. S. Paioti et al.   ACS Catalysis

Diastereofacial π-Stacking as an Approach To Access an Axially Chiral P,N-Ligand for Asymmetric Catalysis

(2017) Balaji V. Rokade et al.   ACS Catalysis

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Synthesis of Axially Chiral Thiohydantoin Derivatives

(2016) Sevgi Sarigul et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Synthesis of Amino Skipped Diynes

(2016) Paulo H. S. Paioti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atropisomerism in 3-arylthiazolidine-2-thiones. A combined dynamic NMR and dynamic HPLC study

(2016) A. Ciogli et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tetrahedron Symposia-in-Print

(2016)   TETRAHEDRON

Stereoselective synthesis of N-arylindoles and related compounds with axially chiral N–C bonds

(2016) Shunsuke Kinoshita et al.   TETRAHEDRON

Combining Organocatalysis with Central-to-Axial Chirality Conversion: Atroposelective Hantzsch-Type Synthesis of 4-Arylpyridines

(2015) Ophélie Quinonero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Quinoline Alkynylation

(2015) Mukesh Pappoppula et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Organocatalyzed Asymmetric Synthesis of Axially, Planar, and Helical Chiral Compounds

(2015) Seiji Shirakawa et al.   Chemistry-An Asian Journal

Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds

(2015) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A twist of nature – the significance of atropisomers in biological systems

(2015) Jamie E. Smyth et al.   NATURAL PRODUCT REPORTS

Potential-Driven Chirality Manifestations and Impressive Enantioselectivity by Inherently Chiral Electroactive Organic Films

(2014) Francesco Sannicolò et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Enantioselective Construction of Polyaromatic Architectures

(2014) Ophélie Quinonero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Axially Chiral BODIPY DYEmers: An Apparent Exception to the Exciton Chirality Rule

(2014) Torsten Bruhn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications

(2014) Stéphane Bellemin-Laponnaz et al.   CHEMICAL REVIEWS

Bis(N-Confused Porphyrin) as a Semirigid Receptor with a Chirality Memory: A Two-Way Host Enantiomerization through Point-to-Axial Chirality Transfer

(2014) Piotr J. Chmielewski et al.   CHEMISTRY-A EUROPEAN JOURNAL

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Asymmetric Synthesis of Atropisomeric Compounds with an N‒C Chiral Axis

(2014) Isao Takahashi et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

A new pyrrolidine-derived atropisomeric amino alcohol as a highly efficient chiral ligand for the asymmetric addition of diethylzinc to aldehydes

(2014) Ferenc Faigl et al.   TETRAHEDRON LETTERS

Biological Stereoselectivity of Atropisomeric Natural Products and Drugs

(2013) Arie Zask et al.   CHIRALITY

Total Synthesis of the Antitumor Antibiotic (±)-Streptonigrin: First- and Second-Generation Routes for de Novo Pyridine Formation Using Ring-Closing Metathesis

(2013) Timothy J. Donohoe et al.   JOURNAL OF ORGANIC CHEMISTRY

Design, Preparation, and Implementation of an Imidazole-Based Chiral Biaryl P,N-Ligand for Asymmetric Catalysis

(2013) Flavio S. P. Cardoso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed asymmetric allylic alkylation of indoles by C–N bond axially chiral phosphine ligands

(2013) Takashi Mino et al.   TETRAHEDRON-ASYMMETRY

Effective cholesteric liquid crystal inducers based on axially chiral alleno-acetylenes

(2013) Sander J. Wezenberg et al.   RSC Advances

Determination of barriers to rotation of axially chiral 5-methyl-2-(o-aryl)imino-3-(o-aryl)thiazolidine-4-ones

(2012) Sule Erol et al.   CHIRALITY

Synthesis of atropisomeric 1-phenylpyrrole-derived amino alcohols: New chiral ligands

(2012) Ferenc Faigl et al.   CHIRALITY

Proton Grease: An Acid Accelerated Molecular Rotor

(2012) Brent E. Dial et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

exo-Selective inverse-electron-demand hetero Diels–Alder reactions of norbornene with 5-benzylidine-2-arylimino-3-aryl-thiazolidine-4-thiones at room temperature

(2012) Sule Erol et al.   TETRAHEDRON

Diastereoselective synthesis of 3,3-disubstituted oxindoles from atropisomeric N-aryl oxindole derivatives

(2012) Atsuo Nakazaki et al.   TETRAHEDRON LETTERS

Practical and efficient synthesis of the (R)-atropisomer of a 4-phenyl 1,2,4-triazole derivative as a selective GlyT1 inhibitor

(2012) Takashi Sugane et al.   TETRAHEDRON-ASYMMETRY

Palladium-Catalyzed Enantioselective Intramolecular Hydroarylation of Alkynes To Form Axially Chiral 4-Aryl 2-Quinolinones

(2011) Tetsuro Shibuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A highly efficient kinetic resolution of Morita–Baylis–Hillman adducts achieved by N–Ar axially chiral Pd-complexes catalyzed asymmetric allylation

(2011) Feijun Wang et al.   CHEMICAL COMMUNICATIONS

Towards the Limit of Atropochiral Stability: H-MIOP, an N-Heterocyclic Carbene Precursor and Cationic Analogue of the H-MOP Ligand

(2011) Ibrahim Abdellah et al.   CHEMISTRY-A EUROPEAN JOURNAL

Planar Chirality of Imidazole-Containing Macrocycles - Understanding and Tuning Atropisomerism

(2011) Emilie Van Den Berge et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Developments in Chiral Binaphthyl-Derived Brønsted/Lewis Acids and Hydrogen-Bond-Donor Organocatalysis

(2011) Sebastian Schenker et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Assessing Atropisomer Axial Chirality in Drug Discovery and Development

(2011) Steven R. LaPlante et al.   JOURNAL OF MEDICINAL CHEMISTRY

Atropisomerism-Induced Facial Selectivity in Nitrile Oxide Cycloadditions with 5-Methylenehydantoins

(2011) Anna M. Said et al.   JOURNAL OF ORGANIC CHEMISTRY

Resolution of 1-[2-carboxy-6-(trifluoromethyl)phenyl]-1H-pyrrole-2-carboxylic acid with methyl (R)-2-phenylglycinate, reciprocal resolution and second order asymmetric transformation

(2011) Ferenc Faigl et al.   TETRAHEDRON-ASYMMETRY

Spiroheterocycles via Regioselective Cycloaddition Reactions of Nitrile Oxides with 5-Methylene-1H-pyrrol-2(5H)-ones

(2010) Nicola J. Beattie et al.   AUSTRALIAN JOURNAL OF CHEMISTRY

Photochemical type II reaction of atropchiral benzoylformamides to point chiral oxazolidin-4-ones. Axial chiral memory leading to enantiomeric resolution of photoproducts

(2010) Josepha L. Jesuraj et al.   CHEMICAL COMMUNICATIONS

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Resolution of the Atropochiral Biminap Ligand and Applications in Asymmetric Catalysis

(2010) Ibrahim Abdellah et al.   Chemistry-An Asian Journal

Total Synthesis of (±)-Marinopyrrole A and Its Library as Potential Antibiotic and Anticancer Agents

(2010) Chunwei Cheng et al.   JOURNAL OF COMBINATORIAL CHEMISTRY

Total Synthesis of (±)-Marinopyrrole A via Copper-Mediated N-Arylation

(2010) Argyrios A. Kanakis et al.   ORGANIC LETTERS

Guest-Accelerated Molecular Rotor

(2010) Brent E. Dial et al.   ORGANIC LETTERS

N-Aryl indole-derived C–N bond axially chiral phosphine ligands: synthesis and application in palladium-catalyzed asymmetric allylic alkylation

(2010) Takashi Mino et al.   TETRAHEDRON-ASYMMETRY

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

A Designer Axially Chiral Amino Sulfonamide as an Efficient Organocatalyst for Direct Asymmetricanti-Selective Mannich Reactions andsyn-Selective Cross-Aldol Reactions

(2009) Taichi Kano et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and optical resolution of 1-[(3-carboxy-1,1′-biphenyl)-2-yl]-1H-pyrrole-2-carboxylic acid

(2009) Ferenc Faigl et al.   CHIRALITY

Atropochiral (C,C)-chelating NHC-ylide ligands: synthesis and resolution of palladium(ii) complexes thereof

(2009) Ibrahim Abdellah et al.   DALTON TRANSACTIONS

A New Class of Stable, Saturated N-Heterocyclic Carbenes withN-Naphthyl Substituents: Synthesis, Dynamic Behavior, and Catalytic Potential

(2009) Ludovic Vieille-Petit et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Molecular playdough: conformationally programmable molecular receptors based on restricted rotation

(2009) Roger D. Rasberry et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Kinetic resolution of allylic esters in palladium-catalyzed asymmetric allylic alkylations using C–N bond axially chiral aminophosphine ligands

(2009) Takashi Mino et al.   TETRAHEDRON-ASYMMETRY

An Atropo‐Stereogenic Diphosphane Ligand with a Proximal Cationic Charge: Specific Catalytic Properties of a Palladium Complex Thereof

(2008) Nathalie Debono et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Identification and Characterization of a New Family of Catalytically Highly Active Imidazolin-2-ylidenes

(2008) Xinjun Luan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Marinopyrroles, Antibiotics of an Unprecedented Structure Class from a MarineStreptomycessp.

(2008) Chambers C. Hughes et al.   ORGANIC LETTERS

Axially chiral N-(o-aryl)-2-thioxo-oxazolidine-4-one and rhodanine derivatives: enantiomeric separation and determination of racemization barriers

(2008) Esra Müjde Yılmaz et al.   TETRAHEDRON-ASYMMETRY

Atropisomerism in the 2-Arylimino-N-(2-hydroxyphenyl)thiazoline Series:  Influence of Hydrogen Bonding on the Racemization Process

(2007) Christian Roussel et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and stereochemical stability of new atropisomeric 1-(substituted phenyl)pyrrole derivatives

(2007) Ferenc Faigl et al.   TETRAHEDRON