A specific demetalation of Fe–N4 catalytic sites in the micropores of NC_Ar + NH3 is at the origin of the initial activity loss of the highly active Fe/N/C catalyst used for the reduction of oxygen in PEM fuel cells
出版年份 2018 全文链接
标题
A specific demetalation of Fe–N4 catalytic sites in the micropores of NC_Ar + NH3 is at the origin of the initial activity loss of the highly active Fe/N/C catalyst used for the reduction of oxygen in PEM fuel cells
作者
关键词
-
出版物
Energy & Environmental Science
Volume 11, Issue 2, Pages 365-382
出版商
Royal Society of Chemistry (RSC)
发表日期
2017-12-12
DOI
10.1039/c7ee02302b
参考文献
相关参考文献
注意：仅列出部分参考文献，下载原文获取全部文献信息。- Is the rapid initial performance loss of Fe/N/C non precious metal catalysts due to micropore flooding?
- (2017) Ja-Yeon Choi et al. Energy & Environmental Science
- Elucidating the Importance of Pore Structure in Determining the Double-Layer Capacitance of Nanoporous Carbon Materials
- (2017) Jocelyn E. Zuliani et al. Journal of Physical Chemistry C
- Platinum group metal-free electrocatalysts: Effects of synthesis on structure and performance in proton-exchange membrane fuel cell cathodes
- (2017) Michael J. Workman et al. JOURNAL OF POWER SOURCES
- Thermodynamic Stability in Acid Media of FeN 4 -Based Catalytic Sites Used for the Reaction of Oxygen Reduction in PEM Fuel Cells
- (2017) Vassili P. Glibin et al. JOURNAL OF THE ELECTROCHEMICAL SOCIETY
- Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
- (2017) Hoon T. Chung et al. SCIENCE
- Engineering nanostructures of PGM-free oxygen-reduction catalysts using metal-organic frameworks
- (2017) Hanguang Zhang et al. Nano Energy
- Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks
- (2017) Heather M. Barkholtz et al. Materials Horizons
- Fe–N–C Catalyst Graphitic Layer Structure and Fuel Cell Performance
- (2017) Michael J. Workman et al. ACS Energy Letters
- Current Status and Future Development of Catalyst Materials and Catalyst Layers for Proton Exchange Membrane Fuel Cells: An Industrial Perspective
- (2017) Dustin Banham et al. ACS Energy Letters
- Highly Functional Bioinspired Fe/N/C Oxygen Reduction Reaction Catalysts: Structure-Regulating Oxygen Sorption
- (2016) Yingfang Yao et al. ACS Applied Materials & Interfaces
- Commensurability Effects in Viscosity of Nanoconfined Water
- (2016) Mehdi Neek-Amal et al. ACS Nano
- In Situ Polymer Graphenization Ingrained with Nanoporosity in a Nitrogenous Electrocatalyst Boosting the Performance of Polymer-Electrolyte-Membrane Fuel Cells
- (2016) Xiaogang Fu et al. ADVANCED MATERIALS
- Networking Pyrolyzed Zeolitic Imidazolate Frameworks by Carbon Nanotubes Improves Conductivity and Enhances Oxygen-Reduction Performance in Polymer-Electrolyte-Membrane Fuel Cells
- (2016) Chao Zhang et al. ADVANCED MATERIALS
- Hierarchically porous Fe-N-doped carbon nanotubes as efficient electrocatalyst for oxygen reduction
- (2016) Jin-Cheng Li et al. CARBON
- Evolution of N-Coordinated Iron–Carbon (FeNC) Catalysts and Their Oxygen Reduction (ORR) Performance in Acidic Media at Various Stages of Catalyst Synthesis: An Attempt at Benchmarking
- (2016) Kuldeep Mamtani et al. CATALYSIS LETTERS
- Probing active sites in iron-based catalysts for oxygen electro-reduction: A temperature-dependent 57 Fe Mössbauer spectroscopy study
- (2016) Moulay Tahar Sougrati et al. CATALYSIS TODAY
- Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
- (2016) Minhua Shao et al. CHEMICAL REVIEWS
- Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction
- (2016) Jingkun Li et al. Energy & Environmental Science
- A Review on Metal-Free Doped Carbon Materials Used as Oxygen Reduction Catalysts in Solid Electrolyte Proton Exchange Fuel Cells
- (2016) M. Klingele et al. Fuel Cells
- Recent Progress in Synthesis, Characterization and Evaluation of Non-Precious Metal Catalysts for the Oxygen Reduction Reaction
- (2016) J. K. Dombrovskis et al. Fuel Cells
- Enhanced performance of non-PGM catalysts in air operated PEM-fuel cells
- (2016) Heather M. Barkholtz et al. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
- Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
- (2016) Vanessa Armel et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- A General Approach to Preferential Formation of Active Fe–Nx Sites in Fe–N/C Electrocatalysts for Efficient Oxygen Reduction Reaction
- (2016) Young Jin Sa et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Molecular transport through capillaries made with atomic-scale precision
- (2016) B. Radha et al. NATURE
- Nanotechnology for environmentally sustainable electromobility
- (2016) Linda Ager-Wick Ellingsen et al. Nature Nanotechnology
- Minimizing Operando Demetallation of Fe-N-C Electrocatalysts in Acidic Medium
- (2016) Chang Hyuck Choi et al. ACS Catalysis
- Highly active and porous graphene encapsulating carbon nanotubes as a non-precious oxygen reduction electrocatalyst for hydrogen-air fuel cells
- (2016) Pouyan Zamani et al. Nano Energy
- Beyond the top of the volcano? – A unified approach to electrocatalytic oxygen reduction and oxygen evolution
- (2016) Michael Busch et al. Nano Energy
- Carbon nanocomposite catalysts for oxygen reduction and evolution reactions: From nitrogen doping to transition-metal addition
- (2016) Gang Wu et al. Nano Energy
- Recent advances in the design of tailored nanomaterials for efficient oxygen reduction reaction
- (2016) Haifeng Lv et al. Nano Energy
- Is iron involved in the lack of stability of Fe/N/C electrocatalysts used to reduce oxygen at the cathode of PEM fuel cells?
- (2016) Gaixia Zhang et al. Nano Energy
- Investigation of Oxygen Reduction Activity of Catalysts Derived from Co and Co/Zn Methyl-Imidazolate Frameworks in Proton Exchange Membrane Fuel Cells
- (2016) Lina Chong et al. ChemElectroChem
- On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction
- (2015) Justus Masa et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Metal-Free Catalysts for Oxygen Reduction Reaction
- (2015) Liming Dai et al. CHEMICAL REVIEWS
- Activity, Performance, and Durability for the Reduction of Oxygen in PEM Fuel Cells, of Fe/N/C Electrocatalysts Obtained from the Pyrolysis of Metal-Organic-Framework and Iron Porphyrin Precursors
- (2015) Lijun Yang et al. ELECTROCHIMICA ACTA
- A review of the stability and durability of non-precious metal catalysts for the oxygen reduction reaction in proton exchange membrane fuel cells
- (2015) Dustin Banham et al. JOURNAL OF POWER SOURCES
- Modeling of Low-Temperature Fuel Cell Electrodes Using Non-Precious Metal Catalysts
- (2015) Nathaniel D. Leonard et al. JOURNAL OF THE ELECTROCHEMICAL SOCIETY
- Square ice in graphene nanocapillaries
- (2015) G. Algara-Siller et al. NATURE
- Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
- (2015) Andrea Zitolo et al. NATURE MATERIALS
- Heteroatom-Doped Graphitic Carbon Catalysts for Efficient Electrocatalysis of Oxygen Reduction Reaction
- (2015) Jintao Zhang et al. ACS Catalysis
- Carbon-based electrocatalysts for advanced energy conversion and storage
- (2015) J. Zhang et al. Science Advances
- Heteroatom-Doped Carbon Nanostructures as Oxygen Reduction Reaction Catalysts in Acidic Media: An Overview
- (2014) Kuldeep Mamtani et al. CATALYSIS LETTERS
- A comparison of N-containing carbon nanostructures (CN x ) and N-coordinated iron–carbon catalysts (FeNC) for the oxygen reduction reaction in acidic media
- (2014) Deepika Singh et al. JOURNAL OF CATALYSIS
- Anatomy of Adsorption in Open-End and Closed-End Slit Mesopores: Adsorption, Desorption, and Equilibrium Branches of Hysteresis Loop
- (2014) Yonghong Zeng et al. Journal of Physical Chemistry C
- Analyzing Structural Changes of Fe–N–C Cathode Catalysts in PEM Fuel Cell by Mößbauer Spectroscopy of Complete Membrane Electrode Assemblies
- (2014) Ulrike I. Kramm et al. Journal of Physical Chemistry Letters
- Long-Range Electron Transfer over Graphene-Based Catalyst for High-Performing Oxygen Reduction Reactions: Importance of Size, N-doping, and Metallic Impurities
- (2014) Chang Hyuck Choi et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Degradation of Fe/N/C catalysts upon high polarization in acid medium
- (2014) Vincent Goellner et al. PHYSICAL CHEMISTRY CHEMICAL PHYSICS
- Precise and Ultrafast Molecular Sieving Through Graphene Oxide Membranes
- (2014) R. K. Joshi et al. SCIENCE
- Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction
- (2013) Gang Wu et al. ACCOUNTS OF CHEMICAL RESEARCH
- Recent progress in non-precious metal catalysts for PEM fuel cell applications
- (2013) Drew C. Higgins et al. CANADIAN JOURNAL OF CHEMICAL ENGINEERING
- Non-porous reference carbon for N2 (77.4 K) and Ar (87.3 K) adsorption
- (2013) A. Silvestre-Albero et al. CARBON
- A carbon-nanotube-supported graphene-rich non-precious metal oxygen reduction catalyst with enhanced performance durability
- (2013) Gang Wu et al. CHEMICAL COMMUNICATIONS
- Stability of iron species in heat-treated polyaniline–iron–carbon polymer electrolyte fuel cell cathode catalysts
- (2013) Magali Ferrandon et al. ELECTROCHIMICA ACTA
- Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications
- (2013) Jens Peter Paraknowitsch et al. Energy & Environmental Science
- How fast does water flow in carbon nanotubes?
- (2013) Sridhar Kumar Kannam et al. JOURNAL OF CHEMICAL PHYSICS
- Unimpeded Permeation of Water Through Helium-Leak-Tight Graphene-Based Membranes
- (2012) R. R. Nair et al. SCIENCE
- A review on non-precious metal electrocatalysts for PEM fuel cells
- (2011) Zhongwei Chen et al. Energy & Environmental Science
- Unveiling N-Protonation and Anion-Binding Effects on Fe/N/C Catalysts for O2 Reduction in Proton-Exchange-Membrane Fuel Cells
- (2011) Juan Herranz et al. Journal of Physical Chemistry C
- High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
- (2011) G. Wu et al. SCIENCE
- Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
- (2011) Eric Proietti et al. Nature Communications
- Chemically Derived Graphene Oxide: Towards Large-Area Thin-Film Electronics and Optoelectronics
- (2010) Goki Eda et al. ADVANCED MATERIALS
- Electronic properties and atomic structure of graphene oxide membranes
- (2010) D. Pacilé et al. CARBON
- The unique nature of H+in water
- (2010) Evgenii S. Stoyanov et al. Chemical Science
- Graphene Oxide: Structural Analysis and Application as a Highly Transparent Support for Electron Microscopy
- (2009) Neil R. Wilson et al. ACS Nano
- Determination of the Potentiostatic Stability of PEMFC Electro Catalysts at Elevated Temperatures
- (2009) V. A. T. Dam et al. Fuel Cells
Publish scientific posters with Peeref
Peeref publishes scientific posters from all research disciplines. Our Diamond Open Access policy means free access to content and no publication fees for authors.
Learn MoreAsk a Question. Answer a Question.
Quickly pose questions to the entire community. Debate answers and get clarity on the most important issues facing researchers.
Get Started