CuI -Catalyzed Pentafluoroethylation of Aryl Iodides in the Presence of Tetrafluoroethylene and Cesium Fluoride: Determining the Route to the Key Pentafluoroethyl CuI Intermediate

Metal Heptafluoroisopropyl (M-hfip) Complexes for Use as hfip Transfer Agents

(2018) Nicholas O. Andrella et al.   ORGANOMETALLICS

Preparation of tetrafluoroethylene from the pyrolysis of pentafluoropropionate salts

(2017) Daniel A. Hercules et al.   JOURNAL OF FLUORINE CHEMISTRY

Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene

(2017) Takuya Kawashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Regioselective Monodefluoroborylation of Polyfluoroalkenes en Route to Diverse Fluoroalkenes

(2017) Hironobu Sakaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine and Gold: A Fruitful Partnership

(2016) Javier Miró et al.   CHEMICAL REVIEWS

Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation

(2016) David A. Petrone et al.   CHEMICAL REVIEWS

Synthesis of Diaryl Sulfones at Room Temperature: Cu-Catalyzed Cross-Coupling of Arylsulfonyl Chlorides with Arylboronic Acids

(2015) Feng Hu et al.   ChemCatChem

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Copper-mediated One-pot Synthesis of Trifluorostyrene Derivatives from Tetrafluoroethylene and Arylboronate

(2015) Kotaro Kikushima et al.   CHEMISTRY LETTERS

Nickel-Catalyzed Formation of Fluorine-Containing Ketones via the Selective Cross-Trimerization Reaction of Tetrafluoroethylene, Ethylene, and Aldehydes

(2015) Masato Ohashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2,2,3,3-Tetrafluoronickelacyclopentanes Generated via the Oxidative Cyclization of Tetrafluoroethylene and Simple Alkenes: A Key Intermediate in Nickel-Catalyzed C–C Bond-Forming Reactions

(2015) Masato Ohashi et al.   ORGANOMETALLICS

Hydrofluorination of Alkynes Catalysed by Gold Bifluorides

(2014) Fady Nahra et al.   ChemCatChem

Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

(2014) Chuanfa Ni et al.   CHEMICAL REVIEWS

Stable but Reactive Perfluoroalkylzinc Reagents: Application in Ligand-Free Copper-Catalyzed Perfluoroalkylation of Aryl Iodides

(2014) Kohsuke Aikawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Designer HF-Based Fluorination Reagent: Highly Regioselective Synthesis of Fluoroalkenes and gem-Difluoromethylene Compounds from Alkynes

(2014) Otome E. Okoromoba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluoroalkylcopper(I) Complexes Generated by the Carbocupration of Tetrafluoroethylene: Construction of a Tetrafluoroethylene-Bridging Structure

(2014) Hiroki Saijo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide

(2014) Xinjin Li et al.   ORGANIC LETTERS

Direct Synthesis of Pentafluoroethyl Copper from Pentafluoropropionate as an Economical C2F5 Source: Application to Pentafluoroethylation of Arylboronic Acids and Aryl Bromides

(2014) Hiroki Serizawa et al.   ORGANIC LETTERS

Base-Free Hiyama Coupling Reaction via a Group 10 Metal Fluoride Intermediate Generated by C–F Bond Activation

(2014) Hiroki Saijo et al.   ORGANOMETALLICS

Dinuclear μ-fluoro cations of copper, silver and gold

(2014) Chelsea M. Wyss et al.   POLYHEDRON

Preparation of Trifluorovinyl Compounds by Lithium Salt-promoted Monoalkylation of Tetrafluoroethene

(2013) Masato Ohashi et al.   CHEMISTRY LETTERS

Direct Synthesis of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones: Application to Trifluoromethylation

(2013) Hiroki Serizawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cupration of C2F5H: Isolation, Structure, and Synthetic Applications of [K(DMF)2][(t-BuO)Cu(C2F5)]. Highly Efficient Pentafluoroethylation of Unactivated Aryl Bromides

(2013) Anton Lishchynskyi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Methoxycarbonyltetrafluoroethylation of Arenes

(2013) Andreas Hafner et al.   ORGANIC LETTERS

Carbon–Fluorine Bond Activation of Tetrafluoroethylene on Palladium(0) and Nickel(0): Heat or Lewis Acidic Additive Promoted Oxidative Addition

(2013) Masato Ohashi et al.   ORGANOMETALLICS

Efficient SN2 Fluorination of Primary and Secondary Alkyl Bromides by Copper(I) Fluoride Complexes

(2013) Yanpin Liu et al.   ORGANOMETALLICS

Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations

(2013) Guosheng Liu et al.   SYNTHESIS-STUTTGART

Silver-Assisted Difunctionalization of Terminal Alkynes: Highly Regio- and Stereoselective Synthesis of Bromofluoroalkenes

(2012) Yibiao Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Developments on the Trifluoromethylation of (Hetero)Arenes

(2012) Xiao-Feng Wu et al.   Chemistry-An Asian Journal

Palladium-Catalyzed Base-Free Suzuki-Miyaura Coupling Reactions of Fluorinated Alkenes and Arenes via a Palladium Fluoride Key Intermediate

(2012) Masato Ohashi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Hydrophobically Assisted Separation-Friendly Mitsunobu Reaction

(2012) Xin-Shan Ye et al.   SYNLETT

Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides

(2012) Thomas Schareina et al.   TOPICS IN CATALYSIS

A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF]

(2011) Nichole D. Litvinas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides

(2011) Hiroyuki Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Coupling Reactions of Tetrafluoroethylene with Arylzinc Compounds

(2011) Masato Ohashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cupration of Fluoroform

(2011) Alessandro Zanardi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

(2011) Ilya Popov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Trifluoromethylation of aryl and heteroaryl halides

(2011) Sudipta Roy et al.   TETRAHEDRON

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes

(2010) Shuifa Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic trifluoromethylation catalytic in copper

(2009) Masahiro Oishi et al.   CHEMICAL COMMUNICATIONS

Regio- and Stereoselective Synthesis of Fluoroalkenes by Directed Au(I) Catalysis

(2009) Benjamin C. Gorske et al.   ORGANIC LETTERS

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3Complexes

(2008) Galyna G. Dubinina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure of Bis(trifluoromethyl)cuprate and Its Role in Trifluoromethylation Reactions

(2008) Galyna G. Dubinina et al.   ORGANOMETALLICS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS