期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 133, 期 10, 页码 3256-3259出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja109911p
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资金
- MEXT [21245028, 21750102]
- NAGASE Science and Technology Foundation
- Japan Petroleum Institute
- Grants-in-Aid for Scientific Research [21750102] Funding Source: KAKEN
Organofluorine compounds are widely used in all aspects of the chemical industry. Although tetrafluoroethylene (TFE) is an example of an economical bulk organofluorine feedstock, the use of TFE is mostly limited to the production of poly(tetrafluoroethylene) and copolymers with other alkenes. Furthermore, no catalytic transformation of TFE that involves carbon-fluorine bond activation has been reported to date. We herein report the first example of a palladium-catalyzed coupling reaction of TFE with arylzinc reagents in the presence of lithium iodide, giving alpha,beta,beta-trifluorostyrene derivatives in excellent yields.
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