Catalytic Asymmetric Inverse-Electron-Demand Oxa-Diels-Alder Reaction of In Situ Generatedortho-Quinone Methides with 3-Methyl-2-Vinylindoles

Chiral Brønsted acid-catalyzed Friedel–Crafts alkylation of electron-rich arenes with in situ-generated ortho-quinone methides: highly enantioselective synthesis of diarylindolylmethanes and triarylmethanes

(2015) Satyajit Saha et al.   CHEMICAL COMMUNICATIONS

Directing Group Assisted Nucleophilic Substitution of Propargylic Alcohols via o-Quinone Methide Intermediates: Brønsted Acid Catalyzed, Highly Enantio- and Diastereoselective Synthesis of 7-Alkynyl-12a-acetamido-Substituted Benzoxanthenes

(2015) Satyajit Saha et al.   ORGANIC LETTERS

Enantio- and Diastereoselective Access to Distant Stereocenters Embedded within Tetrahydroxanthenes: Utilizingortho-Quinone Methides as Reactive Intermediates in Asymmetric Brønsted Acid Catalysis

(2014) Chien-Chi Hsiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Asymmetric Arylative Dearomatization of 2,3-Disubstituted Indoles Enabled by Tandem Reactions

(2014) Yu-Chen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Catalyzed, Conjugate Addition of β-Dicarbonyls to In Situ Generatedortho-Quinone Methides-Enantioselective Synthesis of 4-Aryl-4H-Chromenes

(2014) Osama El-Sepelgy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Formation of All-Carbon Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group

(2014) Wanxiang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic enantioselective and (Z)-selective allylation of 3-indolylmethanol via hydrogen-bond activation

(2014) Yan Liu et al.   CHEMICAL COMMUNICATIONS

Highly diastereo- and enantioselective construction of a spiro[cyclopenta[b]indole-1,3′-oxindole] scaffold via catalytic asymmetric formal [3+2] cycloadditions

(2014) Wei Tan et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Brønsted Acid-Catalyzed, Highly Enantioselective Addition of Enamides to In Situ-Generatedortho-Quinone Methides: A Domino Approach to Complex Acetamidotetrahydroxanthenes

(2014) Satyajit Saha et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Asymmetric Synthesis of 1,1-Diarylethanes by Transfer Hydrogenation

(2014) Zhaobin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed [1,5]-Hydride Shift onto Unactivated Alkynes To Trigger an Intermolecular Diels–Alder Reaction

(2014) Xiang Wu et al.   ORGANIC LETTERS

Complex Bioactive Alkaloid-Type Polycycles through Efficient Catalytic Asymmetric Multicomponent Aza-Diels-Alder Reaction of Indoles with Oxetane as Directing Group

(2013) Zhilong Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Aza-Diels-Alder Reaction of 1-Azadienes with Enecarbamates Catalyzed by Chiral Phosphoric Acids

(2013) Long He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed [4+3] Annulation of Enals ando-Quinone Methides: Highly Enantioselective Synthesis of Benzo-ε-Lactones

(2013) Hui Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arylamine-Catalyzed Enamine Formation: Cooperative Catalysis with Arylamines and Acids

(2013) Yongming Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trienamines Derived from Interrupted Cyclic 2,5-Dienones: Remote δ,ε-CC Bond Activation for Asymmetric Inverse-Electron-Demand Aza-Diels-Alder Reaction

(2013) Xin Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Developments in Catalytic Asymmetric Inverse-Electron-Demand Diels–Alder Reaction

(2013) Xianxing Jiang et al.   CHEMICAL REVIEWS

A Novel MonoterpeneStilbene Adduct with a 4,4-Dimethyl-2,3-diphenylchromane Skeleton fromArtocarpus xanthocarpus

(2013) Horng-Huey Ko et al.   CHEMISTRY & BIODIVERSITY

A Dual Lewis Base Activation Strategy for Enantioselective Carbene-Catalyzed Annulations

(2013) Javier Izquierdo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Cascade Annulation Based on Enantioselective Oxa-Diels–Alder Cycloaddition of in Situ Generated Isochromenyliums by Cooperative Binary Catalysis of Pd(OAc)2 and (S)-Trip

(2013) Shu-Yan Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Gold Complex-Catalyzed Hetero-Diels–Alder Reaction of Diazenes: Highly Enantioselective and General for Dienes

(2013) Bin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hetero Diels–Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: application to the formal synthesis of myristinin B/C

(2013) Santosh J. Gharpure et al.   RSC Advances

Aminocatalytic Asymmetric Diels–Alder Reactions via HOMO Activation

(2012) Jun-Long Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dienamine-Mediated Inverse-Electron-Demand Hetero-Diels-Alder Reaction by Using an Enantioselective H-Bond-Directing Strategy

(2012) Łukasz Albrecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bifunctional Organocatalytic Strategy for Inverse-Electron-Demand Diels-Alder Reactions: Highly Efficient In Situ Substrate Generation and Activation to Construct Azaspirocyclic Skeletons

(2012) Xianxing Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dihydropyridones: Catalytic Asymmetric Synthesis, N- to C-Sulfonyl Transfer, and Derivatizations

(2012) Carmen Simal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles

(2012) Géraldine Masson et al.   CHEMICAL SOCIETY REVIEWS

Chiral Phosphoric Acid-Catalyzed Enantioselective Three-Component Povarov Reaction Using Cyclic Enethioureas as Dienophiles: Stereocontrolled Access to Enantioenriched Hexahydropyrroloquinolines

(2012) Guillaume Dagousset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Inverse-Electron-Demand Hetero-Diels-Alder Reaction for the Construction of Bicyclic Skeletons with Multiple Stereocenters by Using a Bifunctional Organocatalytic Strategy: An Efficient Approach to Chiral Macrolides

(2012) Xianxing Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

ortho-Quinone Methides in Natural Product Synthesis

(2012) Nicky J. Willis et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Hetero Diels–Alder Approach to the Synthesis of Chromans (3,4-Dihydrobenzopyrans) Using Oxonium Ion Chemistry: The Oxa-Povarov Reaction

(2012) Rivka R. R. Taylor et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Addition of Boronates to o-Quinone Methides Catalyzed by Chiral Biphenols

(2012) Yi Luan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hybrid Metal/Organo Relay Catalysis Enables Enynes To Be Latent Dienes for Asymmetric Diels–Alder Reaction

(2012) Zhi-Yong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted-Acid-Catalyzed Asymmetric Multicomponent Reactions for the Facile Synthesis of Highly Enantioenriched Structurally Diverse Nitrogenous Heterocycles

(2011) Jie Yu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Organocatalytic Cyclization and Cycloaddition Reactions

(2011) Albert Moyano et al.   CHEMICAL REVIEWS

Asymmetric Binary-Acid Catalysis with InBr3 in the Inverse-Electron-Demanding Hetero-Diels-Alder Reaction of Mono- and Bis-Substituted Cyclopentadienes: Remote Fluoro-Effect on Stereocontrol

(2011) Jian Lv et al.   CHEMISTRY-A EUROPEAN JOURNAL

Applications ofortho-Quinone Methide Intermediates in Catalysis and Asymmetric Synthesis

(2011) Tejas P. Pathak et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Organic Contact Ion Pairs in Metal-Free Catalytic Asymmetric Allylic Substitutions

(2011) Magnus Rueping et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Inverse-Electron-Demand (IED) [4+2] Cycloaddition of Salicylaldimines: Preparation of Optically Active 4-Aminobenzopyran Derivatives

(2010) Luca Bernardi et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Three-Component Inverse Electron-Demand Aza-Diels-Alder Reaction: Efficient Synthesis of Ring-Fused Tetrahydroquinolines

(2010) Mingsheng Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Mannich-Ketalization Reaction: Highly Enantioselective Synthesis of Aminobenzopyrans

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Preliminary Biological Studies of 3-Substituted Indoles Accessed by a Palladium-Catalyzed Enantioselective Alkene Difunctionalization Reaction

(2010) Tejas P. Pathak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Relay Catalysis in the Three-Component Reaction for Direct Construction of Structurally Complex Heterocycles

(2010) Chao Wang et al.   ORGANIC LETTERS

Asymmetric Cooperative Catalysis of Strong Bronsted Acid-Promoted Reactions Using Chiral Ureas

(2010) H. Xu et al.   SCIENCE

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Enantioselective Synthesis of DihydrocoumarinsviaN-Heterocyclic Carbene-Catalyzed Cycloaddition of Ketenes ando-Quinone Methides

(2009) Hui Lv et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis and biological evaluation of 2,3,4-triarylbenzopyran derivatives as SERM and therapeutic agent for breast cancer

(2009) Shailesh Kumar et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Organocatalytic asymmetric Povarov reactions with 2- and 3-vinylindoles

(2009) Giulia Bergonzini et al.   CHEMICAL COMMUNICATIONS

Unexpected Inversions in Asymmetric Reactions: Reactions with Chiral Metal Complexes, Chiral Organocatalysts, and Heterogeneous Chiral Catalysts

(2009) Mihály Bartók   CHEMICAL REVIEWS

Chiral Brønsted Acid-Catalyzed Enantioselective Three-Component Povarov Reaction

(2009) Hua Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN,N′-Dioxide/In(OTf)3 Catalyst for the Asymmetric Hetero-Diels–Alder Reaction Between Danishefsky's Dienes and Aldehydes: Application in the Total Synthesis of Triketide

(2008) Zhipeng Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

Asymmetric Carbonyl-Ene Reaction Catalyzed by ChiralN,N′-Dioxide-Nickel(II) Complex: Remarkably Broad Substrate Scope

(2008) Ke Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Cycloadditions ofo-Quinone Methides Employing Chiral Ammonium Fluoride Precatalysts

(2008) Ethan Alden-Danforth et al.   ORGANIC LETTERS