Reactivity of Dinitrogen Bound to Mid- and Late-Transition-Metal Centers

Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine

(2014) Takamasa Miyazaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Isolated Nitridyl Radical-Bridged {Rh(N.)Rh} Complex

(2014) Yann Gloaguen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photolytic N2Splitting: A Road to Sustainable NH3Production?

(2014) Christophe Rebreyend et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dinitrogen Reduction at the Molybdenum Center Promoted by a Bulky Tetradentate Phosphine Ligand

(2014) Qian Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Challenges in reduction of dinitrogen by proton and electron transfer

(2014) Cornelis J. M. van der Ham et al.   CHEMICAL SOCIETY REVIEWS

How Does Nishibayashi’s Molybdenum Complex Catalyze Dinitrogen Reduction to Ammonia?

(2014) Yong-Hui Tian et al.   INORGANIC CHEMISTRY

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

(2014) Shogo Kuriyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A 106-Fold Enhancement in N2-Binding Affinity of an Fe2(μ-H)2 Core upon Reduction to a Mixed-Valence FeIIFeI State

(2014) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium

(2014) Isabel Klopsch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Protonation Studies of a Tungsten Dinitrogen Complex Supported by a Diphosphine Ligand Containing a Pendant Amine

(2014) Charles J. Weiss et al.   ORGANOMETALLICS

Synthesis and Protonation Studies of Molybdenum(0) Bis(di­nitrogen) Complexes Supported by Diphosphine Ligands ­Containing Pendant Amines

(2014) Liezel A. Labios et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Mechanisms for the Formation of NH3, N2H4, and N2H2in the Protonation Reaction of Fe(DMeOPrPE)2N2{DMeOPrPE = 1,2-bis[bis(methoxypropyl)phosphino]ethane}

(2014) David R. Tyler   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Synthesis and Reactivity of Molybdenum-Dinitrogen Complexes Bearing PNN-Type Pincer Ligand

(2014) Kazuya Arashiba et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

New Approaches to Functionalizing Metal-Coordinated N2

(2013) José G. Andino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Design and Preparation of Molybdenum-Dinitrogen Complexes with Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands

(2013) Takamasa Miyazaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Developing more sustainable processes for ammonia synthesis

(2013) Yoshiaki Tanabe et al.   COORDINATION CHEMISTRY REVIEWS

Dinitrogen Activation at Iron and Cobalt Metallalumatranes

(2013) P. Alex Rudd et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Dinitrogen Reduction by a Chromium(0) Complex Supported by a 16-Membered Phosphorus Macrocycle

(2013) Michael T. Mock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium

(2013) Markus G. Scheibel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron

(2013) K. Cory MacLeod et al.   Nature Chemistry

Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation

(2012) Travis M. Figg et al.   INORGANIC CHEMISTRY

Photooxidation of coordinated dinitrogen. Photolysis of the ClO2 adduct of [(NH3)5Os(μ-N2)Os(NH3)5]5+

(2012) Arnd Vogler et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Photolysis of aqueous [Os(NH3)5(N2)]2+: Dismutation of coordinated dinitrogen

(2012) Horst Kunkely et al.   INORGANICA CHIMICA ACTA

Closed-shell and open-shell square-planar iridium nitrido complexes

(2012) Markus G. Scheibel et al.   Nature Chemistry

Synthesis and Catalytic Activity of Molybdenum–Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

(2012) Eriko Kinoshita et al.   ORGANOMETALLICS

Synthesis and Protonation of Molybdenum– and Tungsten–Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

(2012) Kazuya Arashiba et al.   ORGANOMETALLICS

Photolysis of Aqueous [Os(NH3)5(N2)]2+. Photoreduction of Coordinated Dinitrogen to Hydrazine as a Model for a New Type of Artificial Photosynthesis?

(2012) Horst Kunkely et al.   ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

(2011) Marc-Etienne Moret et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(iv) nitride

(2011) Travis J. Hebden et al.   CHEMICAL COMMUNICATIONS

Coordination of a Complete Series of N2 Reduction Intermediates (N2H2, N2H4, and NH3) to an Iron Phosphine Scaffold

(2011) Justin L. Crossland et al.   INORGANIC CHEMISTRY

N2Functionalization at Iron Metallaboratranes

(2011) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

(2011) Hiromasa Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand

(2011) Bjorn Askevold et al.   Nature Chemistry

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

Photolysis of Aqueous [(NH3)5Os(μ-N2)Os(NH3)5]5+: Cleavage of Dinitrogen by an Intramolecular Photoredox Reaction

(2010) Horst Kunkely et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

(2010) Nilay Hazari   CHEMICAL SOCIETY REVIEWS

Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity

(2010) Justin L. Crossland et al.   COORDINATION CHEMISTRY REVIEWS

Metal–dioxygen and metal–dinitrogen complexes: where are the electrons?

(2010) Patrick L. Holland   DALTON TRANSACTIONS

Protonation of the Dinitrogen-Reduction Catalyst [HIPTN3N]MoIIIInvestigated by ENDOR Spectroscopy

(2010) R. Adam Kinney et al.   INORGANIC CHEMISTRY

Synthesis of [(DPPNCH2CH2)3N]3−Molybdenum Complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and Studies Relevant to Catalytic Reduction of Dinitrogen

(2010) Michael R. Reithofer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen Fixation and Hydrogen Metabolism in Cyanobacteria

(2010) H. Bothe et al.   MICROBIOLOGY AND MOLECULAR BIOLOGY REVIEWS

Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron

(2010) Yunho Lee et al.   Nature Chemistry

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

A Stable Six-Coordinate Intermediate in Ammonia-Dinitrogen Exchange at Schrock's Molybdenum Catalyst

(2009) Stephan Schenk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intermediates in the reduction of N2 to NH3: synthesis of iron η2 hydrazido(1−) and diazene complexes

(2009) Justin L. Crossland et al.   DALTON TRANSACTIONS

Theoretical Studies of N2Reduction to Ammonia in Fe(dmpe)2N2

(2009) Robert B. Yelle et al.   INORGANIC CHEMISTRY

Synthesis and Protonolysis of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ruthenocenyldiphosphines

(2009) Masahiro Yuki et al.   ORGANOMETALLICS

Preparation and Protonation of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands

(2009) Masahiro Yuki et al.   ORGANOMETALLICS

Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment

(2008) Richard R. Schrock   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First-Principles Investigation of the Schrock Mechanism of Dinitrogen Reduction Employing the Full HIPTN3N Ligand

(2008) Stephan Schenk et al.   INORGANIC CHEMISTRY

Shining Light on Dinitrogen Cleavage: Structural Features, Redox Chemistry, and Photochemistry of the Key Intermediate Bridging Dinitrogen Complex

(2008) John J. Curley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How a century of ammonia synthesis changed the world

(2008) Jan Willem Erisman et al.   Nature Geoscience

Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis

(2008) Masahiro Yuki et al.   ORGANOMETALLICS