2-Formylarylsulfonate from Aryne: A Sequential Reaction Strategy for Direct Synthesis of ortho -Hydroxyl-Protected Aryl Aldehydes

Reaction of Arynes with Vinyl Sulfoxides: Highly Stereospecific Synthesis of ortho-Sulfinylaryl Vinyl Ethers

(2017) Yuanming Li et al.   ORGANIC LETTERS

Synthesis of o-Methyl Trifluoromethyl Sulfide Substituted Benzophenones via 1,2-Difunctionalization of Aryne by Insertion into the C–C Bond

(2017) Milind M. Ahire et al.   ORGANIC LETTERS

Coumarin to Isocoumarin: One-Pot Synthesis of 3-Substituted Isocoumarins from 4-Hydroxycoumarins and Benzyne Precursors

(2017) Kashmiri Neog et al.   ORGANIC LETTERS

Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides

(2017) Xiaojin Li et al.   ORGANIC LETTERS

Palladium-Catalyzed Formylation of Arylzinc Reagents with S-Phenyl Thioformate

(2017) Ryosuke Haraguchi et al.   ORGANIC LETTERS

Electron-Poor, Fluoro-Containing Arylboronic Acids as Efficient Coupling Partners for Bis(1,5-cyclooctadiene)nickel(0)/Tricyclohexylphosphine-Catalyzed Cross-Coupling Reactions of Aryl Arenesulfonates

(2016) Wen-Bo Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

Sulfonium Ylides by (3+2) Cycloaddition of Arynes with Vinyl Sulfides: Stereoselective Synthesis of Highly Substituted Alkenes

(2016) Yuanming Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Corroles and Their Heteroanalogs

(2016) Rafał Orłowski et al.   CHEMICAL REVIEWS

Organobase catalysis using 1-(2-pyrimidyl)piperazine in micellar medium: an approach for better performance and reusability of organobase

(2016) Manu Vashishtha et al.   GREEN CHEMISTRY

Palladium(II)-Catalyzed C–H Bond Activation/C–C and C–O Bond Formation Reaction Cascade: Direct Synthesis of Coumestans

(2016) Kashmiri Neog et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Construction of 2-Aryliminochromenes from Arynes, N,S-Keteneacetals, and DMF

(2016) Li-Rong Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryne 1,2,3-Trifunctionalization with Aryl Allyl Sulfoxides

(2016) Yuanyuan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2-Benzylphenyl Ketones by Aryne Insertion into Unactivated C–C Bonds

(2016) Bin Rao et al.   ORGANIC LETTERS

Insertion of Arynes into P–O Bonds: One-Step Simultaneous Construction of C–P and C–O Bonds

(2016) Na Qi et al.   ORGANIC LETTERS

Arylboration of 1-Arylalkenes by Cooperative Nickel/Copper Catalysis

(2016) Kazuhiko Semba et al.   ORGANIC LETTERS

Substrate-Controlled Selectivity Switch in the Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and CO2

(2016) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Access to phthalazinones via palladium-catalyzed three-component cycloamino-carbonylation of 2-formylaryl tosylates, hydrazines and CO

(2016) Bin Liu et al.   TETRAHEDRON

Multicomponent Coupling Reaction Using Arynes: Synthesis of Xanthene Derivatives

(2015) Eito Yoshioka et al.   JOURNAL OF ORGANIC CHEMISTRY

Buchwald–Hartwig Amination of (Hetero)Aryl Tosylates Using a Well-Defined N-Heterocyclic Carbene/Palladium(II) Precatalyst

(2015) Yin Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Thioamination of Arynes via Reaction with Sulfilimines and Migratory N-Arylation

(2015) Suguru Yoshida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Arynes with Sulfoxides

(2015) Hong-Ying Li et al.   ORGANIC LETTERS

Three-Component Coupling Involving Arynes, Aromatic Tertiary Amines, and Aldehydes via Aryl–Aryl Amino Group Migration

(2015) Sachin Suresh Bhojgude et al.   ORGANIC LETTERS

Dimerization of Aryl Sulfonates by in situ Generated Nickel(0)

(2015) Muriel Durandetti et al.   SYNLETT

PhI(OAc)2-Mediated Intramolecular Oxidative Aryl-Aldehyde Csp2–Csp2 Bond Formation: Metal-Free Synthesis of Acridone Derivatives

(2014) Zisheng Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Three-Component Coupling Reaction Triggered by Insertion of Arynes into the S═O Bond of DMSO

(2014) Feng-Lei Liu et al.   ORGANIC LETTERS

Metal-Free Synthesis of ortho-CHO Diaryl Ethers by a Three-Component Sequential Coupling

(2014) Fangliang Liu et al.   ORGANIC LETTERS

[4+2] cycloaddition of intermediates generated from arynes and DMF

(2014) Eito Yoshioka et al.   TETRAHEDRON LETTERS

A Direct and Mild Formylation Method for Substituted Benzenes Utilizing Dichloromethyl Methyl Ether–Silver Trifluoromethanesulfonate

(2013) Kosuke Ohsawa et al.   JOURNAL OF ORGANIC CHEMISTRY

Insertion of Arynes into Arylphosphoryl Amide Bonds: One-Step Simultaneous Construction of C–N and C–P Bonds

(2013) Chaoren Shen et al.   ORGANIC LETTERS

Straightforward Synthesis of Dihydrobenzofurans and Benzofurans from Arynes

(2013) Eito Yoshioka et al.   ORGANIC LETTERS

Palladium-Catalyzed Aryl CH Activation and Tandemortho-Hydroxylation/Alkoxylation of 2-Aryl Benzimidazoles: Cytotoxicity and DNA-Binding Studies

(2013) Ahmed Kamal et al.   Asian Journal of Organic Chemistry

A Comprehensive History of Arynes in Natural Product Total Synthesis

(2012) Pamela M. Tadross et al.   CHEMICAL REVIEWS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic Carbene–Palladium(II)–1-Methylimidazole Complex-Catalyzed Suzuki–Miyaura Coupling of Aryl Sulfonates with Arylboronic Acids

(2012) Zhan-Yong Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryne Insertion into I–I σ-Bonds

(2012) Diego Rodríguez-Lojo et al.   ORGANIC LETTERS

Recyclable palladium(II) imino-pyridine complex immobilized on mesoporous silica as a highly active and recoverable catalyst for Suzuki–Miyaura coupling reactions in aqueous medium

(2012) Qiang Zhang et al.   TETRAHEDRON

A Multicomponent Coupling Reaction Induced by Insertion of Arynes into the CO Bond of Formamide

(2011) Eito Yoshioka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Natural products-based insecticidal agents 11. Synthesis and insecticidal activity of novel 4α-arylsulfonyloxybenzyloxy-2β-chloropodophyllotoxin derivatives against Mythimna separata Walker in vivo

(2011) Hui Xu et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Three-component coupling using arynes and DMF: straightforward access to coumarins via ortho-quinone methides

(2011) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Mild and Selective Ru-Catalyzed Formylation and Fe-Catalyzed Acylation of Free (N–H) Indoles Using Anilines as the Carbonyl Source

(2011) Wenliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequential Reaction of Arynes via Insertion into the π-Bond of Amides and Trapping Reaction with Dialkylzincs

(2010) Eito Yoshioka et al.   ORGANIC LETTERS

Uncommon Regioselectivity in the Thiacalix[4]arene Series: Gross Formylation of theConeConformer

(2009) Ondrej Kundrat et al.   JOURNAL OF ORGANIC CHEMISTRY

Insertion of Benzene Rings into the Amide Bond: One-Step Synthesis of Acridines and Acridones from Aryl Amides

(2009) Didier G. Pintori et al.   ORGANIC LETTERS