Catalytic Electrophilic CH Silylation of Pyridines Enabled by Temporary Dearomatization

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Silylation of Aryl C–H Bonds

(2015) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Direct silylation reactions of inert C-H bonds via transition metal catalysis

(2015) Yunhui Yang et al.   Science China-Chemistry

Mechanism of the cooperative Si–H bond activation at Ru–S bonds

(2015) Timo Stahl et al.   Chemical Science

Direct Catalytic Access to N-Silylated Enamines from Enolizable Imines and Hydrosilanes by Base-Free Dehydrogenative SiN Coupling

(2014) Julia Hermeke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Boron-Catalyzed Silylative Reduction of Quinolines: Selective sp3 C–Si Bond Formation

(2014) Narasimhulu Gandhamsetty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Rhodium-Catalyzed Silylation of Arene C–H Bonds

(2014) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Disilaferracycle Dicarbonyl Complex Containing Weakly Coordinated η2-(H-Si) Ligands: Application to C–H Functionalization of Indoles and Arenes

(2014) Yusuke Sunada et al.   ORGANOMETALLICS

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Catalytic 1,4-Selective Hydrosilylation of Pyridines and Benzannulated Congeners

(2013) C. David F. Königs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base

(2013) C. David F. Königs et al.   CHEMICAL COMMUNICATIONS

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

(2013) Gyeongshin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C(sp3)–F Bond Activation of CF3-Substituted Anilines with Catalytically Generated Silicon Cations: Spectroscopic Evidence for a Hydride-Bridged Ru–S Dimer in the Catalytic Cycle

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fused Heteroaromatic Dihydrosiloles: Synthesis and Double-Fold Modification

(2013) Alexey Kuznetsov et al.   ORGANIC LETTERS

Facile Catalytic Hydrosilylation of Pyridines

(2011) Dmitry V. Gutsulyak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

(2011) Hendrik F. T. Klare et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

(2011) Kazuyuki Oshima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Silylation of Aromatic Carbon-Hydrogen Bonds in 2-Arylpyridines with Disilane

(2008) Mamoru Tobisu et al.   Chemistry-An Asian Journal

Reactions at the Ru-S Bonds of Coordinatively Unsaturated Ruthenium Complexes with Tethered 2,6-Dimesitylphenyl Thiolate

(2008) Yasuhiro Ohki et al.   Chemistry-An Asian Journal

New Cationic and Zwitterionic Cp*M(κ2-P,S) Complexes (M = Rh, Ir): Divergent Reactivity Pathways Arising from Alternative Modes of Ancillary Ligand Participation in Substrate Activation

(2008) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY