Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface

POBOP pincer complexes of nickel(II): Synthesis and B H activation of the carborane ligand upon oxidation with iodine

(2017) Bennett J. Eleazer et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Boryl/Borane Interconversion and Diversity of Binding Modes of Oxygenous Ligands in PBP Pincer Complexes of Rhodium

(2017) Wei-Chun Shih et al.   ORGANOMETALLICS

Iridium-catalysed regioselective borylation of carboranes via direct B–H activation

(2017) Ruofei Cheng et al.   Nature Communications

Rhodium(III)-Catalyzed Alkenylation-Annulation ofcloso-Dodecaborate Anions through Double B−H Activation at Room Temperature

(2016) Yuanbin Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Organometallic Chemistry of Boron-Containing Pincer Ligands based on Diazaboroles and Carboranes

(2016) Makoto Yamashita   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Functional group migrations between boron and metal centres within transition metal–borane and –boryl complexes and cleavage of H–H, E–H and E–E′ bonds

(2016) Gareth R. Owen   CHEMICAL COMMUNICATIONS

Icosahedral boron clusters: a perfect tool for the enhancement of polymer features

(2016) R. Núñez et al.   CHEMICAL SOCIETY REVIEWS

A Masked Phosphinidene Trapped in a Fluxional NCN Pincer

(2016) Jakub Hyvl et al.   CHEMISTRY-A EUROPEAN JOURNAL

An electron poor iridium pincer complex for catalytic alkane dehydrogenation

(2016) Oleksandr O. Kovalenko et al.   DALTON TRANSACTIONS

Transition Metal Catalyzed Direct Amination of the Cage B(4)–H Bond in o-Carboranes: Synthesis of Tertiary, Secondary, and Primary o-Carboranyl Amines

(2016) Hairong Lyu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center

(2016) Bennett J. Eleazer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Surface Dipole Control of Liquid Crystal Alignment

(2016) Jeffrey J. Schwartz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes

(2016) Wei-Chun Shih et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands

(2016) Jonathan C. Axtell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atomically precise organomimetic cluster nanomolecules assembled via perfluoroaryl-thiol SNAr chemistry

(2016) Elaine A. Qian et al.   Nature Chemistry

Oligoarginine peptides slow strand annealing and assist non-enzymatic RNA replication

(2016) Tony Z. Jia et al.   Nature Chemistry

Iridium Hydride Complexes with Cyclohexyl-Based Pincer Ligands: Fluxionality and Deuterium Exchange

(2016) Alexey V. Polukeev et al.   ORGANOMETALLICS

Synthesis of Pincer Hydrido Ruthenium Olefin Complexes for Catalytic Alkane Dehydrogenation

(2016) Yuxuan Zhang et al.   ORGANOMETALLICS

Changing the Charge: Electrostatic Effects in Pd-Catalyzed Cross-Coupling

(2016) Allen L. Chan et al.   ORGANOMETALLICS

Structure of a Novel Rhodium Phosphinite Compound: Agostic Interactions as a Model for an Oxidative Addition Intermediate

(2016) Sophia D. T. Cherry et al.   ORGANOMETALLICS

Synthesis and Characterization of PBP Pincer Iridium Complexes and Their Application in Alkane Transfer Dehydrogenation

(2016) Wei-Chun Shih et al.   ORGANOMETALLICS

Metal- and Ligand-Centered Reactivity of meta-Carboranyl-Backbone Pincer Complexes of Rhodium

(2016) Bennett J. Eleazer et al.   ORGANOMETALLICS

Synthesis and reactivity of osmium and ruthenium PBP–LXL boryl pincer complexes

(2016) Caitlin M.A. McQueen et al.   POLYHEDRON

Luminescent metal complexes featuring photophysically innocent boron cluster ligands

(2016) Kent O. Kirlikovali et al.   Chemical Science

Palladium catalyzed regioselective B–C(sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes

(2016) Yangjian Quan et al.   Chemical Science

Efficient and selective degradation of polyethylenes into liquid fuels and waxes under mild conditions

(2016) X. Jia et al.   Science Advances

Characterization of a Palladium Dihydrogen Complex

(2015) Samantha J. Connelly et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Dialkenylation of Cage BH Bonds in o -Carboranes through Cross-Coupling Reactions

(2015) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pincer-Type Complexes for Catalytic (De)Hydrogenation and Transfer (De)Hydrogenation Reactions: Recent Progress

(2015) Svenja Werkmeister et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboranes in the chemist's toolbox

(2015) Russell N. Grimes   DALTON TRANSACTIONS

Iridium Cyclometalates with Tethered o-Carboranes: Impact of Restricted Rotation of o-Carborane on Phosphorescence Efficiency

(2015) Young Hoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product

(2015) Akshai Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regioselective Intramolecular Coupling of o-Carborane with Aromatics via Direct Cage B–H Activation

(2015) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex

(2015) Alexey V. Polukeev et al.   Chemical Science

Boron Clusters as Highly Stable Magnesium-Battery Electrolytes

(2014) Tyler J. Carter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π Aromaticity and Three-Dimensional Aromaticity: Two sides of the Same Coin?

(2014) Jordi Poater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Catalytic Transfer Dehydrogenation of Alkanes and Heterocycles by an Iridium Pincer Complex

(2014) Wubing Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal promoted charge and hapticities of phosphines: The uniqueness of carboranylphosphines

(2014) Adrian R. Popescu et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis, Structure, and Catalytic Applications for ortho- and meta-Carboranyl Based NBN Pincer-Pd Complexes

(2014) Min Ying Tsang et al.   INORGANIC CHEMISTRY

Iridium-Mediated Regioselective B–H/C–H Activation of Carborane Cage: A Facile Synthetic Route to Metallacycles with a Carborane Backbone

(2014) Zi-Jian Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Bonding Properties of Ruthenium Complexes Possessing a Boron-Based PBP Pincer Ligand and Their Application for Catalytic Hydrogenation

(2014) Takuma Miyada et al.   ORGANOMETALLICS

Arrested B–H Activation en Route to Installation of a PBP Pincer Ligand on Ruthenium and Osmium

(2014) Anthony F. Hill et al.   ORGANOMETALLICS

Perhalogenated Carba-closo-dodecaborate Anions as Ligand Substituents: Applications in Gold Catalysis

(2013) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation

(2013) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure and Bonding of a Zwitterionic Iridium Complex Supported by a Phosphine with the Parent Carba-closo-dodecaborate CB11H11– Ligand Substituent

(2013) Ahmad El-Hellani et al.   ORGANOMETALLICS

Monosubstituted Borane Ruthenium Complexes RuH2(η2:η2-H2BR)(PR′3)2: A General Approach to the Geminal Bis(σ-B–H) Coordination Mode

(2013) Yann Gloaguen et al.   ORGANOMETALLICS

Acceptor Pincer Chemistry of Osmium: Catalytic Alkane Dehydrogenation by (CF3PCP)Os(cod)(H)

(2013) Brian C. Gruver et al.   ORGANOMETALLICS

New ligand platforms featuring boron-rich clusters as organomimetic substituents

(2013) Alexander M. Spokoyny   PURE AND APPLIED CHEMISTRY

Isolation of a PBP-Pincer Rhodium Complex Stabilized by an Intermolecular CH σ Coordination as the Fourth Ligand

(2012) Maki Hasegawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphorus(III) Cations Supported by a PNP Pincer Ligand and Sub-Stoichiometric Generation of P4from Thermolysis of a Nickel Insertion Product

(2012) David E. Herbert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbaboranes as Pharmacophores: Properties, Synthesis, and Application Strategies

(2011) Matthias Scholz et al.   CHEMICAL REVIEWS

m-Carborane-Based Chiral NBN Pincer-Metal Complexes: Synthesis, Structure, and Application in Asymmetric Catalysis

(2011) Mohamed E. El-Zaria et al.   INORGANIC CHEMISTRY

Acceptor Pincer Chemistry of Ruthenium: Catalytic Alkane Dehydrogenation by (CF3PCP)Ru(cod)(H)

(2011) Brian C. Gruver et al.   ORGANOMETALLICS

Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes†

(2010) Anthony F. Hill et al.   ORGANOMETALLICS

Syntheses of PBP Pincer Iridium Complexes: A Supporting Boryl Ligand

(2009) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes

(2009) Alexander M. Spokoyny et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metallaboratranes Derived from a Triphosphanyl–Borane: IntrinsicC3 Symmetry Supported by a Z-Type Ligand

(2008) Sébastien Bontemps et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

σ-Borane Complexes of Iridium: Synthesis and Structural Characterization

(2008) Travis J. Hebden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen-Mediated Metal−Carbon to Metal−Boron Bond Conversion in Metal−Carboranyl Complexes

(2008) Dongmei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(tBu2PCH2SiMe2)2N]RhI? Rapidly Reversible H−C(sp3) and H−C(sp2) Bond Cleavage by Rhodium(I)

(2007) Alexander Y. Verat et al.   ORGANOMETALLICS