Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [TismPriBenz]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field

Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach

(2017) H. Li et al.   Chemical Science

From Widely Accepted Concepts in Coordination Chemistry to Inverted Ligand Fields

(2016) Roald Hoffmann et al.   CHEMICAL REVIEWS

Synthesis and reactions of a zirconium naphthalene complex bearing a tetraanionic C-capped triaryloxide ligand

(2016) Yusuke Nakanishi et al.   DALTON TRANSACTIONS

Boron-Centered Scorpionate-Type NHC-Based Ligands and Their Metal Complexes

(2016) Carlo Santini et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Formation of NH,NR N-Heterocyclic Carbene Complexes through Mercuration of Mono-N-substituted Benzimidazoles

(2016) Ming-Hung Yu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Modulation of Zn–C Bond Lengths Induced by Ligand Architecture in Zinc Carbatrane Compounds

(2016) Serge Ruccolo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spectroscopic Evidence for a 3d10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4]1–

(2016) Richard C. Walroth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

BDI ∗ MgX(L) where X = n Bu and O t Bu and L = THF, py and DMAP. The rates of kinetic exchange of L where BDI ∗ = CH{C( t Bu)N-2,6- i Pr 2 C 6 H 3 } 2

(2016) Vagulejan Balasanthiran et al.   POLYHEDRON

Tris(pyrazolyl)methanides of the Alkaline Earth Metals: Influence of the Substitution Pattern on Stability and Degradation

(2015) Christoph Müller et al.   INORGANIC CHEMISTRY

Synthesis and Structural Studies of Nickel(0) Tetracarbene Complexes with the Introduction of a New Four-Coordinate Geometric Index, τδ

(2015) Mark H. Reineke et al.   INORGANIC CHEMISTRY

Coordination-Induced Spin-State Change in Manganese(V) Complexes: The Electronic Structure of Manganese(V) Nitrides

(2015) Henning Kropp et al.   INORGANIC CHEMISTRY

Hydrosilylation of Aldehydes and Ketones Catalyzed by a Terminal Zinc Hydride Complex, [κ3-Tptm]ZnH

(2015) Wesley Sattler et al.   ORGANOMETALLICS

Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications

(2014) Stéphane Bellemin-Laponnaz et al.   CHEMICAL REVIEWS

An Extremely Bulky Tris(pyrazolyl)methanide: A Tridentate Ligand for the Synthesis of Heteroleptic Magnesium(II) and Ytterbium(II) Alkyl, Hydride, and Iodide Complexes

(2014) Ralte Lalrempuia et al.   Chemistry-An Asian Journal

Molecular structures of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato and tris(2-mercapto-1-adamantylimidazolyl)hydroborato sodium complexes: analysis of [TmR] ligand coordination modes and conformations

(2014) Ava Kreider-Mueller et al.   DALTON TRANSACTIONS

Pentacoordination for pincer and related terdentate coordination compounds: Revisiting structural properties and trends for d 8 transition metal systems

(2014) Dean M. Roddick et al.   INORGANICA CHIMICA ACTA

Application of the Covalent Bond Classification Method for the Teaching of Inorganic Chemistry

(2014) Malcolm L. H. Green et al.   JOURNAL OF CHEMICAL EDUCATION

Tautomerization of Pyridine and 2-Substituted Pyridines to Pyridylidene Ligands by the Iridium(I)–Diene Complex TpMe2Ir(η4-CH2═C(Me)C(Me)═CH2)

(2014) Florencia Vattier et al.   ORGANOMETALLICS

Coinage Metal Complexes of Tris(pyrazolyl)methanide-Based Redox-Active Metalloligands

(2014) Sandra González-Gallardo et al.   ORGANOMETALLICS

Probing the Reactivity of Redox-Active 2-Aminophenolates on Iron Complexes of a Carbanionic N3C Donor Ligand

(2014) Sridhar Banerjee et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Transmethylation of a four-coordinate nickel(i) monocarbonyl species with methyl iodide

(2014) Changho Yoo et al.   Chemical Science

Reduction of bicarbonate and carbonate to formate in molecular zinc complexes

(2014) Wesley Sattler et al.   Catalysis Science & Technology

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety

(2013) Hajime Kameo et al.   Chemistry-An Asian Journal

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound

(2013) Ahmed Al-Harbi et al.   DALTON TRANSACTIONS

Reactivity Consequences of Substituent-Dependent Preaggregation Motifs ofn- andtert-Butyllithium towards 1,3,5-Triazacyclohexanes

(2013) Matthias Hülsmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Zwitterionic Carbanion Frustrated by Boranes – Dihydrogen Cleavage with Weak Lewis Acids via an “Inverse” Frustrated Lewis Pair Approach

(2013) Hui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Polar Copper–Boron One-Electron σ-Bond

(2013) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Terminal Organozinc Fluoride Compound: Hydrogen Bonding, Halogen Bonding, and Donor–Acceptor Interactions

(2013) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural characterization of tris(pyrazolyl)hydroborato and tris(2-pyridylthio)methyl lithium compounds: Lithium in uncommon trigonal pyramidal and trigonal monopyramidal coordination environments

(2013) Neena Chakrabarti et al.   POLYHEDRON

Fe-N2/CO complexes that model a possible role for the interstitial C atom of FeMo-cofactor (FeMoco)

(2013) J. Rittle et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Dioxygen Reactivity of Biomimetic Iron-Catecholate and Iron-o-Aminophenolate Complexes of a Tris(2-pyridylthio)methanido Ligand: Aromatic CC Bond Cleavage of Catecholate versuso-Iminobenzosemiquinonate Radical Formation

(2012) Partha Halder et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Structure, and Reactivity of a Dimeric Zinc(I) Compound Stabilized by a Sterically Demanding Diiminophosphinate Ligand

(2012) Andreas Stasch   CHEMISTRY-A EUROPEAN JOURNAL

Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety

(2012) Salvador Conejero et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly active zinc alkyl cations for the controlled and immortal ring-opening polymerization of ε-caprolactone

(2012) Charles Romain et al.   DALTON TRANSACTIONS

Tris(carbene)borate Ligands Featuring Imidazole-2-ylidene, Benzimidazol-2-ylidene, and 1,3,4-Triazol-2-ylidene Donors. Evaluation of Donor Properties in Four-Coordinate {NiNO}10 Complexes

(2012) Salvador B. Muñoz et al.   INORGANIC CHEMISTRY

2-Substituted 8-(2-benzhydrylarylimino)-5,6,7-trihydroquinoline-N,N′ nickel dichlorides: Synthesis, characterization and catalytic behavior towards ethylene

(2012) Xiaohua Hou et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Zinc Catalysts for On-Demand Hydrogen Generation and Carbon Dioxide Functionalization

(2012) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigations on the Steric Accessibility of the Carbanionic Moiety in Zwitterionic Magnesium Tris(pyrazolyl)methanide Complexes. Synthesis and Characterisation of Bi- and Tri­metallic Complexes

(2012) Jens Meyer et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Structural characterization of zinc bicarbonate compounds relevant to the mechanism of action of carbonic anhydrase

(2012) Wesley Sattler et al.   Chemical Science

Substituent Effects of Pyridine-amine Nickel Catalyst Precursors on Ethylene Polymerization

(2012) Shaobo Zai et al.   ACS Catalysis

Preparation and Structural Features of Cu(I)Cu(II) Coordination Polymers Obtained by Using Tripodal Complexes as Bridging Ligands

(2011) Yuki Yoshida et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2]

(2011) Daniel Kratzert et al.   CHEMICAL COMMUNICATIONS

Redox-Controlled, Reversible Rearrangement of a Tris(2-pyridylthio)methyl Ligand on Nickel to an Isomer with an “N,S-Confused” 2-Pyridylthiolate Arm

(2011) Naoto Kuwamura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Imidazole to NHC Rearrangements at Molybdenum Centers: An Experimental and Theoretical Study

(2011) Marcel Brill et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and reactivity of niobium complexes having a tripodal triaryloxide ligand in bidentate, tridentate, and tetradentate coordination modes

(2011) Fumio Akagi et al.   DALTON TRANSACTIONS

The coordination chemistry of unsymmetric N-capped tripodal NO3 ligands with iron(III), oxo-vanadium(V) and dioxo-molybdenum(VI) metal centres

(2011) Lok H. Tong et al.   INORGANICA CHIMICA ACTA

Synthesis, Structure, and Reactivity of a Mononuclear Organozinc Hydride Complex: Facile Insertion of CO2into a Zn–H Bond and CO2-Promoted Displacement of Siloxide Ligands

(2011) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Osmium NHC Complexes from Alcohol-Functionalized Imidazoles and Imidazolium Salts

(2011) Beatriz Eguillor et al.   ORGANOMETALLICS

From Bis(N-Alkylimidazole) to Bis(NH-NHC) in Rhenium Carbonyl Complexes

(2010) Miguel A. Huertos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

σ-Acceptor, Z-type ligands for transition metals

(2010) Abderrahmane Amgoune et al.   CHEMICAL COMMUNICATIONS

Electron-Precise Coordination Modes of Boron-Centered Ligands

(2010) Holger Braunschweig et al.   CHEMICAL REVIEWS

Effect of the Nature of the Substituent in N-Alkylimidazole Ligands on the Outcome of Deprotonation: Ring Opening versus the Formation of N-Heterocyclic Carbene Complexes

(2010) Miguel A. Huertos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene–carbanion equilibrium for tris(2-pyridylthio)methanido Fe(ii) complexes

(2010) Naoto Kuwamura et al.   DALTON TRANSACTIONS

Effects of the silicon core structures on the hole mobility of star-shaped oligothiophenes

(2010) Joji Ohshita et al.   DALTON TRANSACTIONS

Transition metals as Lewis bases: “Z-type” boron ligands and metal-to-boron dative bonding

(2010) Holger Braunschweig et al.   DALTON TRANSACTIONS

Trigonal Bi- and Monopyramidal Cobalt(II) Complexes of a Novel Guanidine-Based Tripodal Ligand

(2010) Cassandra E. Searls et al.   INORGANIC CHEMISTRY

Rearrangement of the Tris(2-pyridylthio)methanido Ligand in an Iron(II) Complex Containing an Fe−C Bond

(2010) Partha Halder et al.   INORGANIC CHEMISTRY

“Compressed” Icelike Structures between Molecular Films Comparable with Ice Phase III

(2009) Yuki Yoshida et al.   CHEMISTRY LETTERS

Syntheses, Structures and Electronic Properties of Zwitterionic Iron(II) and Cobalt(II) Complexes Featuring Ambidentate Tris(pyrazolyl)methanide Ligands

(2009) Istemi Kuzu et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Bonding Quandary-or-A Demonstration of the Fact That Scientists Are Not Born With Logic

(2009) Santiago Alvarez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computational Study of theC- andN-Bound Tautomers of [Ru(Cl)(H)(CO)-(PPh3)2(IiPrMe2)] (IiPrMe2= 3-Isopropyl-4,5-dimethylimidazol-2-ylidene)

(2009) L. Jonas L. Häller et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Toward charge-neutral ‘soft scorpionates’: Coordination chemistry and Lewis acid promoted isomerization of tris(1-organo-imidazol-2-ylthio)methanes

(2009) Chengeto Gwengo et al.   INORGANICA CHIMICA ACTA

1,2-Borotropic shifts and B–N bond cleavage reactions in molybdenum hydrotris(3-isopropylpyrazolyl)borate chemistry: Mixed-valence MoVIMo2V and pyrazole-rich oxo-MoIV complexes

(2009) Jonathan M. White et al.   INORGANICA CHIMICA ACTA

Dynamic Behavior of Intramolecularly Base-Stabilized Phosphatetrylenes. Insights into the Inversion Processes of Trigonal Pyramidal Geramanium(II) and Tin(II) Centers

(2009) Keith Izod et al.   ORGANOMETALLICS

Nickel Complexes with Phosphinito-Oxazoline Ligands: Temperature-Controlled Formation of Mono- or Dinuclear Complexes and Catalytic Oligomerization of Ethylene and Propylene

(2009) Patricia Chavez et al.   ORGANOMETALLICS

Oxidation states, atomic charges and orbital populations in transition metal complexes

(2009) Gabriel Aullón et al.   THEORETICAL CHEMISTRY ACCOUNTS

Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn–C bond and DFT calculation of its one-electron oxidized species

(2008) Ken’ichi Kitano et al.   CHEMICAL COMMUNICATIONS

Isopropyllithium diamine adducts: from a non symmetric aggregate to monomeric i-PrLi·(1R,2R)-N,N,N′,N′-tetraethylcyclohexane-1,2-diamine

(2008) Carsten Strohmann et al.   CHEMICAL COMMUNICATIONS

STRONGLY DONATING SCORPIONATE LIGANDS

(2008) Jeremy M. Smith   COMMENTS ON INORGANIC CHEMISTRY

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

Tripodal Tetraamine Ligands Containing Three Pyridine Units: Theother Polypyridyl Ligands

(2008) Allan G. Blackman   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Coordination Chemistry of Neutral (Ln)-Z Amphoteric and Ambiphilic Ligands

(2008) Frédéric-Georges Fontaine et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Molybdenum and Tungsten Structural Differences are Dependent onndz2/(n+ 1)s Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox =tBu3SiO)

(2008) David S. Kuiper et al.   INORGANIC CHEMISTRY

Synthesis and characterization of [chloro{2(1H)-pyridinethione-S}{tris(pyridin-2-ylthiolato)methyl-C,N,N′,N″]}nickel(II)], [Ni(TPTM)(SPyH)Cl]

(2008) Flaviana T. Vieira et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

FromN-Alkylimidazole Ligands at a Rhenium Center: Ring Opening or Formation of NHC Complexes

(2008) Miguel A. Huertos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization

(2008) Rong Gao et al.   ORGANOMETALLICS