4.7 Article

Visible-solar-light-driven photo-reduction and removal of cadmium ion with Eosin Y-sensitized TiO2 in aqueous solution of triethanolamine

期刊

SEPARATION AND PURIFICATION TECHNOLOGY
卷 174, 期 -, 页码 109-115

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2016.10.011

关键词

Dye-sensitization; Photocatalysis; Photo-reduction; Cd (II); TiO2; Visible-solar light; Eosin Y

资金

  1. Natural Sciences and Engineering Research Council (NSERC) of Canada

向作者/读者索取更多资源

Cadmium is toxic to humans, animals, and plants, and show persistence because of its non-degradability. Photo-reduction of cadmium ion (Cd (II)) was studied with Eosin Y-sensitized TiO2 photocatalyst for the reduction/removal of Cd (II) in an aqueous medium under visible-solar light. Triethanolamine (TEOA) was used as a sacrificial electron donor. The band-gap of Eosin Y-sensitized TiO(2)photocatalyst was reduced by similar to 1 eV, and visible light activity was observed for Cd (II) photo-reduction. Parametric studies were performed for visible-solar light intensity, solution pH, and initial concentrations of metal ion, dye, photo catalyst, and an electron donor. Complete photo-reduction of Cd (II) was achieved in 3 h at a pH of 7.0 and a light intensity of 100 mW cm(-2). The photo-reduction rata of Cd (II) in TEOA solution followed Langmuir-Hinshelwood rate equation. The highest apparent quantum yield (similar to 0.3%) for Cd (II) photo-reduction was observed at the lower visible light intensity with illuminated Eosin Y-sensitized TiO2. (C) 2016 Elsevier B.V. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Physical

Removal of As(V) using low cost adsorbents: aerocrete and vermiculite modified with iron oxy-hydroxide

Mrinmoyee Mondal, Ajay K. Ray

ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY (2020)

Article Engineering, Environmental

Direct UV photolysis of pharmaceutical compounds: Determination of pH-dependent quantum yield and full-scale performance

Pankaj Chowdhury, Siva R. Sarathy, Sreejon Das, Juan Li, Ajay K. Ray, Madhumita B. Ray

CHEMICAL ENGINEERING JOURNAL (2020)

Article Engineering, Chemical

Multi-objective optimization of sequential simulated moving bed for the purification of xylo-oligosaccharides

Yan Li, Jin Xu, Weifang Yu, Ajay K. Ray

CHEMICAL ENGINEERING SCIENCE (2020)

Article Engineering, Environmental

Inactivation of Murine Norovirus and Fecal Coliforms by Ferrate(VI) in Secondary Effluent Wastewater

Kyriakos Manoli, Roberta Maffettone, Virender K. Sharma, Domenico Santoro, Ajay K. Ray, Karla D. Passalacqua, Kelly E. Carnahan, Christiane E. Wobus, Siva Sarathy

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2020)

Article Chemistry, Physical

Photocatalytic Activity of Aeroxide TiO2Sensitized by Natural Dye Extracted from Mangosteen Peel

Malini Ghosh, Pankaj Chowdhury, Ajay K. Ray

CATALYSTS (2020)

Article Chemistry, Physical

Morphology-Controlled Synthesis of ZnO Nanostructures for Caffeine Degradation and Escherichia coli Inactivation in Water

Shaila Thakur, Sudarsan Neogi, Ajay K. Ray

Summary: The morphology of nanoparticles strongly influences their photocatalytic and antibacterial activities. Different shapes of ZnO nanoparticles can be obtained by varying the type of solvent used, affecting the generation of reactive oxygen species and metal ions, which ultimately determines their effectiveness. ZnO nanospheres showed the highest activity in degrading caffeine and killing E. coli among the tested nanostructures.

CATALYSTS (2021)

Article Engineering, Chemical

Multi-Objective Optimizations of Non-Isothermal Simulated Moving Bed Reactor: Parametric Analyses

Jian Wang, Wenwei Chen, Yan Li, Jin Xu, Weifang Yu, Ajay K. Ray

Summary: The study investigates the performance of SMBR in reversible reactions and finds that both kinetics and adsorptive separation are important factors. Non-isothermal operation can significantly improve unit throughput under certain conditions, while feed concentration and reaction enthalpy have minor effects on the optimal solutions. Decision variables based on flow rate ratios and internal concentration profiles can explain the trends of Pareto optimal solution.

PROCESSES (2021)

Article Environmental Sciences

Statistical study of Khibiny Alkaline Massif (Kola Peninsula) groundwater quality with respect to elevated aluminum concentrations

Daria Popugaeva, Konstantin Kreyman, Ajay K. Ray

Summary: Current study addresses the issue of elevated aluminum concentrations deteriorating groundwater quality in the Khibiny Alkaline Massif. By applying chemometric methods to a dataset spanning from 1999 to 2018, the study quantitatively describes groundwater quality, identifies patterns of variability, and potential sources of aluminum contamination. Results show significant associations between aluminum and pH, Cl-, NO3-, SO42-, as well as developed mathematical models elucidating variability in aluminum concentration and dataset variance. The study highlights the importance of this approach for enhancing groundwater quality monitoring and control in the Arctic region and other areas facing similar issues.

ENVIRONMENTAL TECHNOLOGY (2022)

Article Engineering, Chemical

Detailed modeling of solids separation by microsieving in a rotating belt filter: Explicit effect of particle size, mesh size, and polymer dose

Furqan Ahmad Khan, Pankaj Chowdhury, Francesca Giaccherini, Anthony Gerald Straatman, Domenico Santoro

Summary: The study presented a detailed microsieving filtration model and demonstrated its effectiveness in capturing observed trends in filtration processes, with the relative error in performance scale up reduced through further calibration against pilot data. The calibrated model provided guidance for future pilot studies, emphasizing the importance of continuous pilot data collection and sampling frequency for accurate estimation of model parameters.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Chemistry, Analytical

Multi-Objective Optimisation of Biodiesel Synthesis in Simulated Moving Bed Reactor

Nillohit Mitra Ray, Ajay K. Ray

Summary: A multi-objective optimization study was conducted in a simulated moving bed reactor (SMBR) for biodiesel synthesis, leading to significant improvements in yield and purity. The mathematical model used in the study was modified and experimentally verified for multiple-column SMBR system, showing promise for optimizing both existing setups and designs.

SEPARATIONS (2021)

Article Engineering, Chemical

Photocatalytic Degradation of Diazo Dye over Suspended and Immobilized TiO2 Catalyst in Swirl Flow Reactor: Kinetic Modeling

Waleed Jadaa, Anand Prakash, Ajay K. Ray

Summary: The degradation kinetics of Direct Blue 15 using TiO2 catalyst was studied, showing effective degradation of the dye and fitting with a pseudo first-order kinetics model, as well as being describable by the Langmuir-Hinshelwood (L-H) model. The P25 catalyst deposited on Pyrex glass demonstrated high efficiency and reusability, with analysis on the impact of dye concentration and light intensity on kinetics validation.

PROCESSES (2021)

Article Engineering, Environmental

Physico-chemical characteristics and biodegradability of primary effluent and particulate matter removed by microscreens

Sanaz Alizadeh, Pankaj Chowdhury, Vahid Ghodsi, Francesca Giaccherini, Siva Sarathy, Domenico Santoro, Yves Comeau

Summary: In this study, the physical, chemical, and biological characteristics of liquid and solid streams generated by different filter configurations were compared. The results showed that the RBF, DF, and PC all had different removal efficiencies for total suspended solids. The liquid fractions also underwent significant compositional changes, while the biodegradability of the liquid fractions remained constant. The recovered solids from RBF had higher TS concentration and VS content compared to DF and PC treatments. The biodegradability rate of DF and PC sludge was higher than that of solids recovered by RBF.

WATER ENVIRONMENT RESEARCH (2023)

Review Engineering, Chemical

Research Progress on the Typical Variants of Simulated Moving Bed: From the Established Processes to the Advanced Technologies

Xiaotong Zhang, Juming Liu, Ajay K. K. Ray, Yan Li

Summary: Simulated moving bed (SMB) chromatography is an efficient adsorption-based separation technology, widely used in various industrial sectors, particularly in biochemical and pharmaceutical industries. SMB offers advantages such as high product purity and yield, large feed treatment capacity, and simple process control, making it suitable for difficult multi-component separation or complicated purification processes. Improvements and optimization are needed to enhance SMB performance and deal with more complex separation tasks.

PROCESSES (2023)

Review Green & Sustainable Science & Technology

Water Pollution and Agriculture Pesticide

Samira Mosalaei Rad, Ajay K. Ray, Shahzad Barghi

Summary: The agricultural industry uses a large amount of water for irrigation, but excessive use of pesticides has led to the issue of wastewater contamination, which is a global problem. Pesticides not only have negative impacts on human health, the ecosystem, and the aquatic environment, but also react with water and soil to form substances with different properties. Although there are biodegradable pesticides, their use is limited and natural degradation is time-consuming. The development of environmentally friendly pesticides and new technologies to reduce water contamination is becoming increasingly important.

CLEAN TECHNOLOGIES (2022)

Article Engineering, Chemical

A tough double-network ion gel membrane based on poly (ionic liquid) for efficient carbon capture

Yunfei Yu, Xue Yang, Chenchen Zhang, Jie Chen, Wei Lin, Jianqiang Meng

Summary: This study reports an environmentally friendly and simple approach for preparing double-network (DN) ion gel membranes with high strength and excellent gas separation performance. By optimizing crosslinking density, mass ratio, and the type and content of free ionic liquid, the mechanical and gas separation properties of the DN membrane are improved.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

An innovative dual-strengthening pretreatment to improve Li and Co leaching in spent lithium-ion batteries: Pyrolysis combined with mechanical grinding

Si-qi Jiang, Qiang Gao, Xi-guang Li, Chao-zhu Deng, Jun Qiu, Xiang-nan Zhu

Summary: A dual-strengthening pretreatment method is proposed to remove PVDF more efficiently and enhance the leaching of LiCoO2. Experimental results show that dual-strengthening pretreatment can effectively remove PVDF and significantly improve the leaching efficiency compared to single pretreatment methods.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Rapid fabrication of composite membranes based on conjugated microporous polymers: Microstructural design for performance optimization

Zengchi Hu, Xiaoyu Wang, Xiaohui Zhang, Xue Li, Jiangbin Xia

Summary: The rapid fabrication of high-performance composite membranes based on CMPs using simple and low-cost methods is challenging. In this study, three CMPs-based composite membranes were rapidly fabricated with adjustable size using unidirectional diffusion synthesis. The microstructural design enhanced the rejection rates of the membranes and they showed strong hydrolytic resistance, thermal stability, and acid-base resistance. Electrostatic adsorption and the adjustable microstructures significantly varied the repellence of the membranes to different charged molecules.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Dual nature brilliant adsorbent engineering by converting an Al-based MOF to defect rich quasi-MOF

Farzaneh Rouhani, Matineh Ayedi, Nasser Safari

Summary: Introducing defects into porous metal-organic frameworks is important for improving their adsorption performance. Quasi-MOFs, an underutilized variant of large-scale, fundamentally deficient MOFs, have been found to have substantial amounts of unsaturated metal sites to offset the drawbacks of MOFs. In this study, a quasi-MOF was produced using a water-stable MOF and demonstrated significantly improved phosphate adsorption capability due to the presence of defect sites.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Liquid-liquid extraction of sinapic acid from a mustard seed by-product using a hollow fiber membrane contactor

Valentin Reungoat, Morad Chadni, Louis M. M. Mouterde, Fanny Brunissen, Florent Allais, Helene Ducatel, Irina Ioannou

Summary: This study focuses on the recovery of sinapic acid using liquid-liquid extraction assisted by a hollow fiber membrane contactor from an aqueous feed obtained through the hydrolysis of mustard bran. The screening of solvents of different chemical nature showed that all tested solvents had an extraction efficiency of more than 80% for pH < 5. Four solvents were selected for use in the hollow fiber membrane contactor, and the volatile solvents showed higher mass transfer coefficients compared to non-volatile solvents. The extraction efficiency was intensified by increasing the initial concentration of sinapic acid and the feed-to-solvent ratio. CPME was found to have optimal recovery efficiency at a phase ratio of 8:1, yielding 0.9 g of sinapic acid per liter of CPME used.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Hydrophobic deep eutectic solvents for the direct leaching of nickel laterite ores: Selectivity and reusability investigations

Takahiro Sakamoto, Takafumi Hanada, Hayate Sato, Mayu Kamisono, Masahiro Goto

Summary: The emergence of the battery society has led to a high demand for battery metals, resulting in a strain on their supply. This study introduces a novel technique using a hydrophobic deep eutectic solvent (DES) for leaching and recovering battery metals from low-grade nickel laterite ores. The DES enables selective leaching and recovery of the metals, offering a promising pathway for the extraction of critical battery metals.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Quantification of overcompensated cations in layer-by-layer membrane by Orange yellow II

Rongrong He, Jiarui Chen, Chunyao Zhang, Dan Lu, Lin Zhang, Tao He

Summary: Researcher has developed a method to quantify the charge density in nanofiltration (NF) membrane separation layer and applied it in NF membranes that can separate Mg2+ and Li+. The results showed that overcompensated amine groups played a major role, and there was a linear relationship between charge density and coating bi-layers or PAH layers.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Insight of multifunctional Cu-alginate hydrogel membrane for precise molecule/ion separation applications

Zhijian Zhang, Min Chen, Zhe Lin, Zhichao Yang, Yafeng Du, Zhihui Chen, Zhenhao Yang, Kongyin Zhao, Ligang Lin

Summary: Membrane technology plays an important role in molecular/ion separation processes, but faces challenges such as membrane fouling. This study introduces a new ion-crosslinking method to fabricate copper alginate hydrogel membranes with improved mechanical strength and antimicrobial capabilities. The membranes exhibit excellent separation performance and enhanced long-term molecule/ion separation through improved anti-swelling properties. Molecular dynamics simulations and life cycle analysis highlight the pore structure and environmental friendliness of the hydrogel membranes. These findings provide valuable insights for developing sustainable hydrogel membranes with stable performance and high separation efficiency.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Activation of persulfate by magnetic Mg/Mn-layered double oxide-doped biochar composite for ciprofloxacin removal and bacterial inactivation

Dongmei Liu, Aiying Guo, Yanling Qi, Zhixin Ji, Hongjuan Li, Zhiwei Zhang, Xinyue Zhang, Kunze Wu, Aijun Cai

Summary: In this study, a stable magnetic Mg/Mn-layered double oxide-doped biochar composite (MgMnLDO-MBC) was prepared and successfully used for the removal of antibiotics and bacteria from wastewater. The composite exhibited enhanced surface areas, adsorption sites, and free radicals, leading to improved catalytic activity. The effects of different factors on the removal efficiency were evaluated, and the composite showed good reusability.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Rapid peroxymonosulfate activation by self-assembly of layered fluorine-free MXene with nanofibrous Co3O4: Antibiotic degradation and electron transfer mechanism

Feng Wang, Zhaoyong Bian, Yaru Zhang, Wenchao Yu, Qiang Zhang, Hui Wang

Summary: In this study, a nanofibrous layered structure of Ff-Ti3C2Tx-Co3O4 was prepared by self-assembling nanofibrous Co3O4 with lamellar fluorine-free MXene (Ff-Ti3C2Tx). The Ff-Ti3C2Tx-Co3O4 exhibited excellent catalytic activity for degradation, resistant to ionic interference, and maintained high removal efficiency of sulfamethoxazole (SMX) in municipal wastewater. The rapid SMX degradation involved fast electron transfer in redox cycles with PMS and the generation of 1O2 via PMS ->center dot O2  -> 1O2. This work provides new insights into antibiotic degradation mechanisms and electron transfer based on PMS activation.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Differently charged polyacrylamides (PAMs) significantly affect adsorption affinity and associated floc growth behaviors during ballasted flocculation: Performance and mechanism

Weipeng He, Jiacheng Luo, Yujie Wu, Tianhao Luo, Chen Tang

Summary: This study comparatively evaluated the role of cationic, anionic, and nonionic polyacrylamides (PAMs) in ballasted flocculation of clay suspensions under different aluminum sulfate (AS) coagulant dosages. The selection of PAMs and AS dosage had a significant influence on the size and shear resistance of ballasted floc aggregates.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Polymeric membrane with nanohybrids of Cu nanocomposites and metalloporphyrin-based nanosheets for enzyme-like catalytic degradation of Congo Red

Lixian Wang, Lizhi Zhao, Didi Si, Zhixin Li, Huiqin An, Hui Ye, Qingping Xin, Hong Li, Yuzhong Zhang

Summary: Metalloporphyrin-based nanozymes integrated with poly (vinylidene fluoride) membrane show high catalytic activity and reusability for the decolorization of Congo Red dye in continuous flow process.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Facile synthesis of ball milling and magnetization co-modified sludge-derived biochar for efficient adsorbing environmental concentration sulfamethoxazole from various waters: Performance and mechanism

Yongfei Ma, Chenyu Zeng, Yongzhen Ding, Jiayi Tang, Ondrej Masek, Zhikang Deng, Rui Mu, Zulin Zhang

Summary: In this study, sludge-derived biochar (SBC) was functionalized with various iron salts to enhance its adsorption ability for sulfamethoxazole (SMX) and magnetic collection performance. Ball milling was further employed to treat the optimal iron salt functionalized SBC (MSBC), resulting in ball milled SBC (BMSBC) with improved adsorption performance for SMX. The dominant driving mechanism for SMX adsorption onto BMSBC was confirmed to be multiple physicochemical forces, including 7C-7C conjugation, pore filling, H-bonding, Fe-O complexation, and electrostatic interactions. BMSBC exhibited favorable adsorption ability for SMX in actual waters and could be easily collected within 1 min due to its magnetic sensitivity.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Facile fabrication of non-fluorine polymer brush/loop surfaces for oil/water separation and self-cleaning applications

Jinglin Tan, Xiaohui Mao, Wenjihao Hu, Hongbo Zeng

Summary: This study investigates the influence of PDMS chain architectures on surface properties and reveals that PDMS coatings with looped structures exhibit superior hydrophobicity, self-cleaning, and water sliding compared to coatings with linear structures. Additionally, both looped and linear PDMS coated stainless steel mesh/polyester fibers show efficient separation of oil/water mixture.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Engineering, Chemical

Fabrication of sandwich-structured capacitor containing core@shell polystyrene@graphene oxide microspheres for switchable removal of dyes from water by dielectrophoresis force

Wei-Liang Chen, Chih-Chia Cheng, Chien-Hsing Lu, Jem-Kun Chen

Summary: This study designs a novel sandwich-structured capacitor that reduces the absorption time of pollutants using dielectrophoresis force. By coating graphene oxide on polystyrene microspheres as adsorbents and encapsulating them within the capacitor, the adsorption rate is significantly enhanced. Additionally, frequency manipulation allows for the recycling of adsorbents and concentration of dyes, minimizing secondary pollution.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)