4.7 Article

Electrochemical fabrication of NZVI/TiO2 nano-tube arrays photoelectrode and its enhanced visible light photocatalytic performance and mechanism for degradation of 4-chlorphenol

期刊

SEPARATION AND PURIFICATION TECHNOLOGY
卷 182, 期 -, 页码 144-150

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/j.seppur.2017.03.047

关键词

NZVI/TiO2 nano-tube arrays; Photoelectrode; Visible light photocatalysis; 4-Chlorphenol

资金

  1. National Natural Science Foundation of China [51508254]
  2. Nature Science Foundation of Gansu Province of China [1506RJZA216]
  3. Fundamental Research Funds for the Central Universities [lzujbky-2015-137]
  4. Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure [SKL201509SIC]
  5. Open fund by Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials [KFK1502]
  6. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  7. Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources, Qinghai Institute of Salt Lake, Chinese Academy of Sciences

向作者/读者索取更多资源

In this study, nano-scale zero-valent iron (NZVI) decorated TiO2 nano-tube arrays (NZVI/TiO2 NTAs) photoelectrode was fabricated through anodization process, followed by galvanostatic electrodeposition strategy. Afterwards, physicochemical properties of the resulting NZVI/TiO2 NTAs samples were systematically studied by SEM, XRD, XPS, IJV vis DRS and photoelectrochemical (PECH) measurements. Results indicated that NZVI/TiO2 NTAs photoelectrode exhibited greatly enhanced visible light absorbance and high photogenerated charge separation efficiency. However, after photocatalytic (PC) reaction, NVZI particles were converted to alpha-Fe2O3 species, which would further improve the visible light absorbance and PC efficiency, which was confirmed by the further enhanced visible light PC performance for decomposition of 4-chlorphenol (4-CP) and generation of.OH radicals. Furthermore, the enhanced visible light mechanism of NZVI/TiO2 NTAs photoelectrode was detailed discussed. This study provides a versatile strategy to fabricate high-efficient catalysts which could be used in the high-toxic and refractory micro-pollutants elimination in water body. (C) 2017 Elsevier B.V. All rights reserved.

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