Transition metal catalysis—a unique road map in the stereoselective synthesis of 1,3-polyols

Enantioselective Modular Total Synthesis of Macrolides Sch725674 and C-4-epi-Sch725674

(2016) Brijesh M. Sharma et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Platinum Catalysis Revisited—Unraveling Principles of Catalytic Olefin Hydrosilylation

(2016) Teresa K. Meister et al.   ACS Catalysis

Copper-Catalyzed Oxy-Alkenylation of Homoallylic Alcohols to Generate Functionalsyn-1,3-Diol Derivatives

(2015) Dean Holt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Synthesis of Protected 1,3-Diols by Catalytic Diol Relocation

(2015) Justin A. Goodwin et al.   ORGANIC LETTERS

Catalytic Enantioselective CH Functionalization of Alcohols by Redox-Triggered Carbonyl Addition: Borrowing Hydrogen, Returning Carbon

(2014) John M. Ketcham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (+)-Discodermolide by Catalytic Stereoselective Borylation Reactions

(2014) Zhiyong Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic and Computational Evaluation of Regiodivergent Epoxide Opening for Diol and Polyol Synthesis

(2014) Andreas Gansäuer et al.   Chemistry-An Asian Journal

Lewis Acid Catalyzed Synthesis of Cyclic Carbonates, Precursors of 1,2- and 1,3-Diols

(2014) Johan Cornil et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C–H Bonds for the Synthesis of 1,3-Diols

(2014) Bijie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Desymmetrization Approach to the Enantiopuresyn/anti-1,5-DiolsviaHydrolytic Kinetic Resolution (HKR) of Functionalizedmeso-Bis-Epoxides: Further Elaboration tosyn/syn-1,3,5-Triols and Application to the Formal Synthesis of Cryptocarya Diacetate

(2013) Pradeep Kumar et al.   ADVANCED SYNTHESIS & CATALYSIS

Structures and Interligand Interaction Pattern of Phosphoramidite Pd Complexes by NMR Spectroscopy: Modulations in Extended Interaction Surfaces as Stereoselection Mode of a Privileged Class of Ligands

(2013) Evelyn Hartmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Air-Stable Bifunctional Allylation Reagents for the Asymmetric Synthesis of Differentiatedsyn- andanti-1,3-Diols

(2013) Jae Seung Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Streamlined Catalytic Asymmetric Synthesis of Atorvastatin

(2013) Yuji Kawato  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of a Cn-Cn+6Building Block Common to Important Polyol,Polyene Antibiotics from a Divinylcarbinol by a Desymmetrizing Sharpless Epoxidation

(2013) Luc Nachbauer et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stereocontrolled Synthesis of 1,3-Diols from Enones: Cooperative Lewis Base-Mediated Intramolecular Carbonyl Hydrosilylations

(2013) Casey Medina et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Basis for High Stereoselectivity and Broad Substrate Scope in the (salen)Co(III)-Catalyzed Hydrolytic Kinetic Resolution

(2013) David D. Ford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Catalytic Functionalization of Primary C–H Bonds Using a Silylation Strategy

(2013) Abhishek Parija et al.   ORGANIC LETTERS

Bimetallic catalysis in the highly enantioselective ring–opening reactions of aziridines

(2013) Bin Wu et al.   Chemical Science

Proline Catalyzed α-Aminoxylation Reaction in the Synthesis of Biologically Active Compounds

(2012) Pradeep Kumar et al.   ACCOUNTS OF CHEMICAL RESEARCH

Concise Synthesis of Acetal-Protectedsyn1,3-Diols by a Tandem Hemiacetal Formation/Tsuji-Trost Reaction

(2012) Liang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Construction of syn-1,3-Dioxanes via a Bismuth-Mediated Two-Component Hemiacetal/Oxa-Conjugate Addition Reaction

(2012) P. Andrew Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Recent advances and applications of iridium-catalysed asymmetric allylic substitution

(2012) Paolo Tosatti et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereoselective Synthesis of 1,3-anti Diols by an Ipc-Mediated Domino Aldol-Coupling/Reduction Sequence

(2012) Michael Dieckmann et al.   ORGANIC LETTERS

Two-Directional Desymmetrization by Double 1,4-Addition of Silicon and Boron Nucleophiles

(2012) Eduard Hartmann et al.   ORGANIC LETTERS

Tandem hydroboration/reduction of trisubstituted β,γ-unsaturated esters for the asymmetric synthesis of chiral 1,3-diols

(2012) Paul S. Fordred et al.   TETRAHEDRON LETTERS

Formal synthesis of tetrahydrolipstatin and tetrahydroesterastin

(2012) Divya Tripathi et al.   TETRAHEDRON-ASYMMETRY

Rapid Total Syntheses Utilizing “Supersilyl” Chemistry

(2011) Brian J. Albert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Direct Catalytic Enantio- and Diastereoselective Aldol Reaction of Thioamides

(2011) Mitsutaka Iwata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Borylative Ketone-Diene Coupling

(2011) Hee Yeon Cho et al.   ORGANIC LETTERS

A simplified catalytic system for direct catalytic asymmetric aldol reaction of thioamides; application to an enantioselective synthesis of atorvastatin

(2011) Yuji Kawato et al.   TETRAHEDRON

Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide

(2010) Eduard Hartmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphoramidites: Privileged Ligands in Asymmetric Catalysis

(2010) Johannes F. Teichert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Diastereocontrolled Total Synthesis of (+)-Strictifolione

(2010) Pradeep Kumar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stereocontrolled Synthesis of 1,3,5-Triols by an Iteration of Asymmetric Dihydroxylation and Deoxygenation

(2010) Patrick Walleser et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (+)-Roxaticin via C−C Bond Forming Transfer Hydrogenation: A Departure from Stoichiometric Chiral Reagents, Auxiliaries, and Premetalated Nucleophiles in Polyketide Construction

(2010) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Cobalt Oxazoline Palladacycle (COP)-Catalyzed Asymmetric Synthesis of Allylic Esters

(2010) Jeffrey S. Cannon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones via Soft Lewis Acid/Hard Brønsted Base/Hard Lewis Base Catalysis

(2010) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereocontrol in Rhenium-Catalyzed Transposition of Allylic Alcohols

(2010) Aaron T. Herrmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Radical Cyclization via Regiodivergent Epoxide Opening

(2010) Andreas Gansäuer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Myxobacterial secondary metabolites: bioactivities and modes-of-action

(2010) Kira J. Weissman et al.   NATURAL PRODUCT REPORTS

Direct Conversion of β-Hydroxyketones to Cyclic Disiloxanes

(2010) Gregory W. O’Neil et al.   ORGANIC LETTERS

Regiodivergent epoxide opening (REO) via electron transfer: control elements

(2010) Andreas Gansäuer et al.   TETRAHEDRON-ASYMMETRY

Sequential and Modular Synthesis of Chiral 1,3-Diols with Two Stereogenic Centers: Access to All Four Stereoisomers by Combination of Organo- and Biocatalysis

(2009) Katrin Baer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,n-Glycols as Dialdehyde Equivalents in Iridium-Catalyzed Enantioselective Carbonyl Allylation and Iterative Two-Directional Assembly of 1,3-Polyols

(2009) Yu Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Asymmetric Mannich-Type Reaction of Thioamides

(2009) Yuta Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Hydroxylation Using a Heterocyclic Catalyst and Aqueous H2O2

(2009) Nichole D. Litvinas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis ofanti-1,3-Diols through RuCl3/PPh3-Mediated Hydrogenation of β-Hydroxy Ketones: An Alternative to Organoboron Reagents

(2009) Christophe Roche et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Jacobsen’s Catalyst for Hydrolytic Kinetic Resolution: Structure Elucidation of Paramagnetic Co(III) Salen Complexes in Solution via Combined NMR and Quantum Chemical Studies

(2009) Sebastian Kemper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Aldol Reactions of Thioamides: Toward a Stereocontrolled Synthesis of 1,3-Polyols

(2009) Mitsutaka Iwata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Transition-State Structures for Nickel-Catalyzed Reductive Alkyne−Aldehyde Coupling Reactions

(2009) P. R. McCarren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Polyrhacitides A and B by Use of an Iterative Strategy for the Stereoselective Synthesis of 1,3-Polyol Arrays

(2009) Helge Menz et al.   ORGANIC LETTERS

Stereoselective Synthesis ofsyn,syn- andsyn,anti-1,3,5-Triols via Intramolecular Hydrosilylation of Substituted Pent-3-en-1,5-diols

(2009) Fangzheng Li et al.   ORGANIC LETTERS

Elongation of 1,3-Polyols via Iterative Catalyst-Directed Carbonyl Allylation from the Alcohol Oxidation Level

(2009) Abbas Hassan et al.   ORGANIC LETTERS

Regioselective Iron-Catalyzed Decarboxylative Allylic Etherification

(2009) Rushi Trivedi et al.   ORGANIC LETTERS

Regiodivergent Ring Opening of Chiral Aziridines

(2009) B. Wu et al.   SCIENCE

Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon

(2009) Christian Walter et al.   TETRAHEDRON

A two-step synthesis of allylic syn 1,3-diols via an intramolecular oxa-Michael reaction followed by a modified Julia olefination

(2009) Raphaël Oriez et al.   TETRAHEDRON LETTERS

Catalytic Carbonyl Addition through Transfer Hydrogenation: A Departure from Preformed Organometallic Reagents

(2008) John F. Bower et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage

(2008) Christian Walter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of C–C Bonds via Ruthenium-catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level

(2008) Fumitoshi Shibahara et al.   CHEMISTRY LETTERS

Enantioselective Iridium-Catalyzed Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Transfer Hydrogenative Coupling of Allyl Acetate: Departure from Chirally Modified Allyl Metal Reagents in Carbonyl Addition

(2008) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,3-Diol Synthesis via Controlled, Radical-Mediated C−H Functionalization

(2008) Ke Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iterative Cr-Mediated Catalytic Asymmetric Allylation To Synthesizesyn/syn- andanti/anti-1,3,5-Triols

(2008) Zhiyu Zhang et al.   ORGANIC LETTERS

Ruthenium-SYNPHOS-Catalyzed Asymmetric Hydrogenations: an Entry to Highly Stereoselective Synthesis of the C15−C30 Subunit of Dolabelide A

(2008) Christophe Roche et al.   ORGANIC LETTERS

DFT Studies on the Borylation of α,β-Unsaturated Carbonyl Compounds Catalyzed by Phosphine Copper(I) Boryl Complexes and Observations on the Interconversions between O- and C-Bound Enolates of Cu, B, and Si

(2008) Li Dang et al.   ORGANOMETALLICS

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION