Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

Highly Enantio- and Diastereoselective Synthesis of γ-Amino Alcohols from α,β-Unsaturated Imines through a One-Pot β-Boration/Reduction/Oxidation Sequence

(2011) Cristina Solé et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Conjugate Silyl Additions to α,β-Unsaturated Aldehydes Catalyzed by Combination of Transition Metal and Chiral Amine Catalysts

(2011) Ismail Ibrahem et al.   ADVANCED SYNTHESIS & CATALYSIS

The selective addition of water to CC bonds; enzymes are the best chemists

(2011) Jianfeng Jin et al.   CHEMICAL COMMUNICATIONS

Organocatalytic versus Iron-Assisted β-Boration of Electron-Deficient Olefins

(2011) Amadeu Bonet et al.   Chemistry-An Asian Journal

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines

(2011) Devendra J. Vyas et al.   ORGANIC LETTERS

Asymmetric Conjugate Silyl Transfer in Iterative Catalytic Sequences: Synthesis of the C7-C16 Fragment of (+)-Neopeltolide

(2010) Eduard Hartmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Conjugate Borylation

(2010) Julia A. Schiffner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides

(2010) Devendra J. Vyas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric β-Boration of α,β-Unsaturated Carbonyl Derivatives

(2010) Luca Mantilli et al.   ChemCatChem

Isoquinoline-based chiral monodentate N-heterocyclic carbenes

(2010) Dimitri Hirsch-Weil et al.   CHEMICAL COMMUNICATIONS

MhyADH catalysed Michael addition of water and in situ oxidation

(2010) Jianfeng Jin et al.   CHEMICAL COMMUNICATIONS

The direct catalytic asymmetric aldol reaction

(2010) Barry M. Trost et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalysed Domino Silylative Aldol Reaction Leading to Stereocontrolled Chiral Quaternary Carbons

(2010) Alexandre Welle et al.   CHEMISTRY-A EUROPEAN JOURNAL

Boron Conjugate Additions on Electron Deficient Olefins Towards Selective 1,3- Difunctionalization

(2010) Amadeu Bonet et al.   CURRENT ORGANIC CHEMISTRY

Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides

(2010) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Conjugate Additions of Alcohols

(2010) Eric M. Phillips et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters

(2010) Jack Chang Hung Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective syn hydration of enones in water using a DNA-based catalyst

(2010) Arnold J. Boersma et al.   Nature Chemistry

SmI2-Mediated Radical Cyclizations Directed by a C−Si Bond

(2010) Hassan Y. Harb et al.   ORGANIC LETTERS

Copper(I)−Secondary Diamine Complex-Catalyzed Enantioselective Conjugate Boration of Linear β,β-Disubstituted Enones

(2010) I-Hon Chen et al.   ORGANIC LETTERS

Organocatalytic Preparation of Simple β-Hydroxy and β-Amino Esters: Low Catalyst Loadings and Gram-Scale Synthesis

(2010) Hao Jiang et al.   ORGANIC LETTERS

A Chiral 6-MemberedN-Heterocyclic Carbene Copper(I) Complex That Induces High Stereoselectivity

(2010) Jin Kyoon Park et al.   ORGANIC LETTERS

Efficient and stereoselective synthesis of threo-β-hydroxy-l-glutamic acid via a tandem (Z)-olefination-conjugate addition

(2010) Hyeonjeong Kim et al.   TETRAHEDRON-ASYMMETRY

Copper-Catalyzed Conjugate Addition of Diboron Reagents to α,β-Unsaturated Amides: Highly Reactive Copper-1,2- Bis(diphenylphosphino)benzene Catalyst System

(2009) Heesung Chea et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

(2009) Xinhui Feng et al.   CHEMICAL COMMUNICATIONS

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

(2009) Takushi Shiomi et al.   CHEMICAL COMMUNICATIONS

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Enantioselective β-Boration of Acyclic Enones

(2009) Hak-Suk Sim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!

(2009) Andreas Weickgenannt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric induction on β-boration of α,β-unsaturated compounds: an inexpensive approach

(2009) Vanesa Lillo et al.   DALTON TRANSACTIONS

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the β-position

(2009) Vanesa Lillo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Axially chiral P-N ligands for the copper catalyzed β-borylation of α,β-unsaturated esters

(2009) William J. Fleming et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The synthesis of single enantiomers of mycobacterial ketomycolic acids containing cis-cyclopropanes

(2009) Gani Koza et al.   TETRAHEDRON

Rhodium(I)-catalyzed enantioselective 1,4-addition of nucleophilic silicon

(2009) Christian Walter et al.   TETRAHEDRON

Catalytic Asymmetric Hydroperoxidation of α,β-Unsaturated Ketones: An Approach to Enantiopure Peroxyhemiketals, Epoxides, and Aldols

(2008) Corinna M. Reisinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of an α,β-Unsaturated Ketone to Form a γ-Siloxyallylborane

(2008) Takashi Kajiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage

(2008) Christian Walter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

The oxa-Michael reaction: from recent developments to applications in natural product synthesis

(2008) Carl F. Nising et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Enantioselective Peroxidation of α,β-Unsaturated Ketones

(2008) Xiaojie Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Oxy-Michael Additions to β,γ-Unsaturated α-Keto Esters:  Rapid Enantioselective Synthesis of 3-Hydroxybutenolides

(2008) Xin Xiong et al.   ORGANIC LETTERS

DFT Studies on the Borylation of α,β-Unsaturated Carbonyl Compounds Catalyzed by Phosphine Copper(I) Boryl Complexes and Observations on the Interconversions between O- and C-Bound Enolates of Cu, B, and Si

(2008) Li Dang et al.   ORGANOMETALLICS

Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

(2008) Vanesa Lillo et al.   ORGANOMETALLICS

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective, Organocatalytic Oxy-Michael Addition to γ/δ-Hydroxy-α,β-enones:  Boronate-Amine Complexes as Chiral Hydroxide Synthons

(2007) De Run Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY