期刊
ELECTROCHIMICA ACTA
卷 176, 期 -, 页码 718-726出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.07.051
关键词
Electroplating; nickel; deep eutectic solvents; speciation
资金
- Ministry of higher education and scientific research in Kurdistan, Iraq, HCDP program
- TSB (UK) under the RECONIF project [BA011K]
- EU under Framework 7
Metal electrodeposition using ionic liquid electrolytes and deep eutectic solvents is now well known but to our knowledge for electrolytic deposition of metals such as nickel no direct comparison has thus far been drawn between deposition using aqueous solutions and DES under otherwise identical conditions. In the current study it is shown that nickel deposition can be carried out with similar deposition rates in aqueous and ionic media despite the significant differences in viscosity and conductivity. It is, however, shown that in ionic media the morphology of the deposits is markedly different from that achieved using a Watts nickel bath and that one aspect of these differences manifests itself in significant increase in the coating hardness. It is proposed that the observed morphology differences occur due to the variations of nickel speciation in each electrolyte environment. (C) 2015 Elsevier Ltd. All rights reserved.
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