期刊
ELECTROCHIMICA ACTA
卷 174, 期 -, 页码 8-14出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.05.153
关键词
MoO2 nanoparticles; Carbon-coated; Three-dimensional graphene aerogel; Lithium-ion battery
资金
- National Basic Research Program of China [2014CB848900]
- National Natural Science Foundation of China [U1232131, 11375198]
- Fundamental Research Funds for the Central Universities [WK2310000035]
Three-dimensional (3D) nanoarchitectures can improve the performance of electrical energy storage systems. In this paper, combining an improved solvothermal method with calcination treatment, thin layer carbon-coated MoO2 nanoparticles with the size of 20-50 nm were uniformly dispersed in 3D graphene aerogel (abbreviated as MoO2@C-Gas). The hybrid materials were subsequently used as a new-structured anode for lithium-ion batteries (LIBs), yielding high reversible capacity with excellent stable cyclability. We found that the battery with MoO2@C-Gas electrode could deliver a discharge capacity of 1515 mAhg(-1) at a current density of 80 mAg(-1) in the first cycle, and remain at 1113 mAhg-1 over 60 cycles. Furthermore, with the increase of current density, it also exhibited a high rate of capability and good cycling performance. The outstanding performance of the hybrid electrode were attributed to the unique 3D aerogel morphology and the close combination between C@MoO2 and graphene layers, which could significantly improve the anode's electronic conductivity. (C) 2015 Elsevier Ltd. All rights reserved.
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