期刊
ELECTROCHIMICA ACTA
卷 182, 期 -, 页码 900-907出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.10.006
关键词
Carboxymethyl Chitosan; Water soluble binder; Adhesion strength; LiFePO4; lithium-ion battery
资金
- Special Support Program of Guangdong Province for High-Level Talents [2014TX01N014]
- Guangdong Provincial Project for Science Technology [2013B091300017/2014A050503050]
- Guangzhou Municipal Project for Science Technology [201423/2014Y2-00219]
- Fund for Science & Technology Innovation Team of Zhoushan (Zhejiang, China)
Cyanoethylated carboxymethyl chitosan (CN-CCTS) has been synthesized through a straightforward cyanoethylation reaction by reacting CCTS with acrylonitrile in NaOH aqueous solution. CN-CCTS shows improved adhesion strength of 0.047 N/cm as compared with 0.013 N/cm for CCTS after introducing cyanoethyl group in the chemical structure of CCTS. The electrochemical performances of LiFePO4 electrode with CN-CCTS binder have been investigated and compared with those using water soluble sodium carboxymethyl cellulose (CMC) and non-aqueous polyvinylidene difluoride (PVDF) binder. LiFePO4 electrode with CN-CCTS exhibits better cycling stability and rate capability, retaining 56.3% capacity of C/5 at 5C rate as compared with 48.4% and 32.8% for CMC and PVDF, respectively. Cyclic voltammetry and electrochemical impedance spectroscopy measurement reveal that LiFePO4 electrode with CN-CCTS has a more favorable electrochemical kinetics than that with CMC and PVDF, thus better rate capability. (C) 2015 Elsevier Ltd. All rights reserved.
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