4.6 Article

Construction of Porous Hierarchical Manganese Dioxide on Exfoliated Titanium Dioxide Nanosheets as a Novel Electrode for Supercapacitors

期刊

ELECTROCHIMICA ACTA
卷 178, 期 -, 页码 758-766

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.08.073

关键词

Manganese dioxide; Titanium dioxide; Hierarchical structure; Exfoliation; Supercapacitors

资金

  1. National Natural Science Foundation of China [51402065]
  2. Heilongjiang Province Natural Science Funds for Distinguished Young Scholar
  3. Special Innovation Talents of Harbin Science and Technology for Distinguished Young Scholar [2014RFYXJ005]
  4. Fundamental Research Funds of the Central University (HEUCFZ)
  5. Natural Science Foundation of Heilongjiang Province [B201404]
  6. Program of International S&T Cooperation special project [2015DFR50050]
  7. Special Innovation Talents of Harbin Science and Technology [2013RFQXJ145]
  8. fund for Transformation of Scientific and Technological Achievements of Harbin [2013DB4BG011]

向作者/读者索取更多资源

A facile composite of tremella-on-sheet manganese dioxide (MnO2)/titanium dioxide (TiO2) has been fabricated successfully as the electrode material for supercapacitors. The results of scanning electron microscopy and transmission electron microscopy reveal that hierarchical tremella-like MnO2 grows onto the exfoliated two-dimensional (2D) TiO2 nanosheets. The uniquely structured composite covers a large specific surface area with typical mesoporous characteristics for achieving high pseudocapacitance performance. The composite exhibits higher specific capacitance (286.69 F g(-1) at a current of 1 A g(-1)) and has 81.1% retained specific capacitance after 1000 cycles in three-electrode system. The high performance of the electrode is attributed to a unique structure, 3D hierarchical morphology, particular conductive substrate, and low contact resistance. (C) 2015 Elsevier Ltd. All rights reserved.

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