期刊
ELECTROCHIMICA ACTA
卷 161, 期 -, 页码 84-94出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.02.071
关键词
Manganese oxides; Nitrogen doping; Nanocomposite; Supercapacitor
资金
- Anhui Province Key Laboratory of Environment-friendly Polymer Materials, Anhui Provincial Natural Science Foundation
- National Training Programs of Innovation and Entrepreneurship for Undergraduates [201410357010]
- National Natural Science Foundation of China [21101052]
Nitrogen-doped nanoporous carbon materials with large BET surface area (1322.5 m(2) g(-1)) and pore volume (0.87 cm(3) g(-1)) have been achieved by a synchronous carbonization/nitridation process, simply using potassium biphthalate and azodicarbonamide as carbon/nitrogen sources, respectively. The above carbon materials have been further impregnated with MnOx nanocrystallites that comes from the thermal decomposition of Mn(NO3)(2). Taking the carbon-2:1-Mn sample as an excellent example, it also has large BET surface area (1160.1 m(2) g(-1)) and pore volume (0.77 cm(3) g(-1)) and exhibits high nitrogen/ manganese contents of 4.13%, and 3.30%, respectively. The carbon-2: 1-Mn sample delivers excellent capacitances of 564.5 and 496.8 F g(-1) at the current density of 0.5 and 1.0 A g(-1), respectively, as well as superior cycling stability of 96.10% even after charging/discharging for 5000 times. The present method of incorporating cheap MnOx substance into carbon matrix is efficient and also easy for large scale production of carbon nanocomposites, especially possessing large BET surface area and high pore volume. (C) 2015 Elsevier Ltd. All rights reserved.
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