4.6 Article

Electrochemical Synthesis of PbO2, Pb3O4 and PbO Films on a Transparent Conducting Substrate

期刊

ELECTROCHIMICA ACTA
卷 156, 期 -, 页码 283-288

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.01.019

关键词

PbO2; Pb3O4; PbO; Thin Film

资金

  1. Royal Society [UF100105]
  2. EPSRC
  3. Royal Society [UF100105] Funding Source: Royal Society

向作者/读者索取更多资源

Through electroplating and thermal decomposition by annealing at various temperatures in an oxygen environment, films of PbO2, Pb3O4 and PbO have been synthesised on transparent conducting substrates of indium tin oxide coated glass. Of these films, Pb3O4, alpha-PbO and beta-PbO have a phase pure crystal structure. These films are formed as either nano-scale particles or complete films depending on the electroplating conditions. The complete films demonstrate excellent surface coverage with a thickness of the order of a few microns. The films have been characterised through a combination of x-ray diffraction, scanning electron microscopyand surface profilometry. (C) 2015 Elsevier Ltd. All rights reserved.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Chemistry, Multidisciplinary

Origin of Open-Circuit Voltage Enhancements in Planar Perovskite Solar Cells Induced by Addition of Bulky Organic Cations

Chieh-Ting Lin, Jinho Lee, Jinhyun Kim, Thomas J. Macdonald, Jonathan Ngiam, Bob Xu, Matyas Daboczi, Weidong Xu, Sebastian Pont, Byoungwook Park, Hongkyu Kang, Ji-Seon Kim, David J. Payne, Kwanghee Lee, James R. Durrant, Martyn A. McLachlan

ADVANCED FUNCTIONAL MATERIALS (2020)

Article Chemistry, Physical

Probing structural changes upon carbon monoxide coordination to single metal adatoms

P. T. P. Ryan, M. Meier, Z. Jakub, J. Balajka, J. Hulva, D. J. Payne, T. -L. Lee, C. Franchini, F. Allegretti, G. S. Parkinson, D. A. Duncan

JOURNAL OF CHEMICAL PHYSICS (2020)

Article Multidisciplinary Sciences

Surface enhanced Raman scattering artificial nose for high dimensionality fingerprinting

Nayoung Kim, Michael R. Thomas, Mads S. Bergholt, Isaac J. Pence, Hyejeong Seong, Patrick Charchar, Nevena Todorova, Anika Nagelkerke, Alexis Belessiotis-Richards, David J. Payne, Amy Gelmi, Irene Yarovsky, Molly M. Stevens

NATURE COMMUNICATIONS (2020)

Article Materials Science, Multidisciplinary

Direct insight into the band structure of SrNbO3

Chiara Bigi, Pasquale Orgiani, Jagoda Slawinska, Jun Fujii, John T. Irvine, Silvia Picozzi, Giancarlo Panaccione, Ivana Vobornik, Giorgio Rossi, David Payne, Francesco Borgatti

PHYSICAL REVIEW MATERIALS (2020)

Article Nanoscience & Nanotechnology

Exsolution of Catalytically Active Iridium Nanoparticles from Strontium Titanate

Eleonora Cali, Gwilherm Kerherve, Faris Naufal, Kalliopi Kousi, Dragos Neagu, Evangelos I. Papaioannou, Melonie P. Thomas, Beth S. Guiton, Ian S. Metcalfe, John T. S. Irvine, David J. Payne

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Materials Science, Ceramics

Antimony substituted lanthanum orthoniobate proton conductor - Structure and electronic properties

Aleksandra Mielewczyk-Gryn, Sebastian Wachowski, Agnieszka Witkowska, Kacper Dzierzgowski, Wojciech Skubida, Konrad Swierczek, Anna Regoutz, David J. Payne, Stephen Hull, Hangfeng Zhang, Isaac Abrahams, Maria Gazda

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2020)

Article Nanoscience & Nanotechnology

Quantum Confinement and Thickness-Dependent Electron Transport in Solution-Processed In2O3Transistors

Ivan Isakov, Hendrik Faber, Alexander D. Mottram, Satyajit Das, Max Grell, Anna Regoutz, Rebecca Kilmurray, Martyn A. McLachlan, David J. Payne, Thomas D. Anthopoulos

ADVANCED ELECTRONIC MATERIALS (2020)

Article Chemistry, Physical

Linking in situ charge accumulation to electronic structure in doped SrTiO3 reveals design principles for hydrogen-evolving photocatalysts

Benjamin Moss, Qian Wang, Keith T. Butler, Ricardo Grau-Crespo, Shababa Selim, Anna Regoutz, Takashi Hisatomi, Robert Godin, David J. Payne, Andreas Kafizas, Kazunari Domen, Ludmilla Steier, James R. Durrant

Summary: This study reveals the unique properties of La,Rh:SrTiO3 photocatalyst sheets by combining in situ spectroelectrochemical measurements with density functional theory. It demonstrates that the electronic structure reorganization induced by Rh reduction controls the electron lifetime, while La co-doping fixes Rh in the 3+ state to improve the lifetime of photogenerated electrons even at positive potentials. This understanding provides new insights into the design principles for water-splitting devices based on bandgap-engineered metal oxides.

NATURE MATERIALS (2021)

Article Materials Science, Multidisciplinary

Identification of hidden orbital contributions in the La0.65Sr0.35MnO3 valence band

F. Offi, K. Yamauchi, S. Picozzi, V Lollobrigida, A. Verna, C. Schlueter, T-L Lee, A. Regoutz, D. J. Payne, A. Petrov, G. Vinai, G. M. Pierantozzi, T. Pincelli, G. Panaccione, F. Borgatti

Summary: The hybridization of electronic states and orbital symmetry in transition metal oxides plays a key role in their electronic and magnetic properties. Analysis of elemental and orbital distributions in the valence band of La0.65Sr0.35MnO3 (LSMO) reveals significant contributions from La 5p, Mn 4s, and O 2s orbitals, previously considered negligible, which are essential for a correct description of LSMO and transition metal oxides in general.

PHYSICAL REVIEW MATERIALS (2021)

Article Chemistry, Physical

Low temperature methane conversion with perovskite-supportedexo/endo-particles

Kalliopi Kousi, Dragos Neagu, Leonidas Bekris, Eleonora Cali, Gwilherm Kerherve, Evangelos Papaioannou, David J. Payne, Ian S. Metcalfe

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Multidisciplinary

Validation of the inverted adsorption structure for free-base tetraphenyl porphyrin on Cu(111)

P. T. P. Ryan, P. L. Lalaguna, F. Haag, M. M. Braim, P. Ding, D. J. Payne, J. Barth, T-L Lee, D. P. Woodruff, F. Allegretti, D. A. Duncan

CHEMICAL COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Adsorbate-induced structural evolution changes the mechanism of CO oxidation on a Rh/Fe3O4(001) model catalyst

Zdenek Jakub, Jan Hulva, Paul T. P. Ryan, David A. A. Duncan, David J. J. Payne, Roland Bliem, Manuel Ulreich, Patrick Hofegger, Florian Kraushofer, Matthias Meier, Michael Schmid, Ulrike Diebold, Gareth S. S. Parkinson

NANOSCALE (2020)

Article Chemistry, Physical

Electron spectroscopy of ionic liquids: experimental identification of atomic orbital contributions to valence electronic structure

Richard M. Fogarty, Robert G. Palgrave, Richard A. Bourne, Karsten Handrup, Ignacio J. Villar-Garcia, David J. Payne, Patricia A. Hunt, Kevin R. J. Lovelock

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

Review Chemistry, Physical

Developments in electrochemical processes for recycling lead-acid batteries

Sze-yin Tan, David J. Payne, Jason P. Hallett, Geoffrey H. Kelsall

CURRENT OPINION IN ELECTROCHEMISTRY (2019)

Meeting Abstract Chemistry, Multidisciplinary

Vacuum deposition of biferrocene thin films: growth strategies for stability and tuneable magnetism

Roland Leber, Lucy Wilson, Peter Robaschik, Michael Inkpen, David Payne, Nicholas Long, Tim Albrecht, Cyrus Hirjibehedin, Sandrine Heutz

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Electrochemistry

Recent advances in Bio-mass by electrochemically strategies generated hydrogen gas production: Environmentally sustainable technologies innovation

Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro

Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

ACGNet: An interpretable attention crystal graph neural network for accurate oxidation potential prediction

Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao

Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Enhanced electrochemical performance of CuO/NiO/rGO for oxygen evolution reaction

P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha

Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Carbon nanofibers implanted porous catalytic metal oxide design as efficient bifunctional electrode host material for lithium-sulfur battery

Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li

Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Spray coating of carbon nanoparticles as an effective and scalable method to enhance the performance of stainless steel anode in microbial electrochemical systems

Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo

Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical properties of Li-rich ternary cathode material Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase

Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu

Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Post-mortem analysis of the Li-ion battery with charge/discharge deterioration in high- and low-temperature environments

Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda

Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A Co3O4-x/Co nanocomposite with synergistically enhanced electrochemical activity for reduction of nitrite to ammonia

Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen

Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Facile fabrication of NaOH nanorods on pencil graphite electrode for simultaneous electrochemical detection of natural antioxidants by deep eutectic solvent

Berna Dalkiran, Havva Bekirog

Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A three-dimensional fibrous tungsten-oxide/carbon composite derived from natural cellulose substance as an anodic material for lithium-ion batteries

Sijun Ren, Jianguo Huang

Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Stabilizing the dissolution kinetics by interstitial Zn cations in CoMoO4 for oxygen evolution reaction at high potential

Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian

Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Molecular insights on optimizing nanoporous carbon-based supercapacitors with various electrolytes

Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings

Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Interaction between bilirubin oxidase and Au nanoparticles distributed over dimpled titanium foil towards oxygen reduction reaction

Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou

Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical supercapacitor and water splitting electrocatalysis applications of self-grown amorphous Ni(OH)2 nanosponge-balls

Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane

Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Versatile mixed ionic-electronic conducting binders for high-power, high-energy batteries

Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado

Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.

ELECTROCHIMICA ACTA (2024)