期刊
ELECTROCHIMICA ACTA
卷 182, 期 -, 页码 165-172出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2015.09.071
关键词
Prussian blue analogue; CoOx nanocubes; Porous shell; Glucose sensor; Electrochemistry
资金
- National Natural Science Foundation of China [21165010, 21465014, 21465015]
- Natural Science Foundation of Jiangxi Province [20142BAB203101]
- Young Scientist Foundation of Jiangxi Province [20122BCB23011]
- Ministry of Education, Specialized Research Fund for the Doctoral Program of Higher Education [20133604110002]
- Ground Plan of Science and Technology Projects of Jiangxi Educational Committee [KJLD14023]
- Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University [KLFS-KF-201410, KLFS-KF-201416]
Hollow metal or metal oxide nanostructures have become one of the most promising functional materials in sensor, catalysis, energy conversion, etc. In this work, a novel hollow CoOx nanocube with porous shell was fabricated based on Prussian blue analogue (PBA)-derived method. The hollow Co(OH)(2) nanocubes were firstly formed through chemical treatment of PBA in a NaOH solution then converted into hollow CoOx nanocubes with porous shell at 40 degrees C in air. The CoOx nanostructures were characterized in detail by scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, energy dispersive spectroscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The electrocatalytic properties of the hollow CoOx nanocubes with porous shell were investigated by cyclic voltammetry and amperometry. The resulted nanostructures were used to construct a novel glucose sensor with good performance owing to the good catalytic activity and high surface area of hollow CoOx nanocubes with porous shell. The proposed method is simple, efficient, cheap and easy to mass production. (C) 2015 Elsevier Ltd. All rights reserved.
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