Article
Chemistry, Physical
Tian Yao, Jialing Song, Ya Gan, Cailing Feng, Lianxin Peng
Summary: This study successfully constructed temperature-sensitive magnetic ionic liquid aqueous two-phase systems and explored their potential applications in extraction and separation. The experimental results and theoretical correlations provide valuable references for future applications.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Tian Yao, Hongmei Li, Jiawen Yang, Xiaodong Shi, Huiling Yan, Lianxin Peng
Summary: In this study, three novel chiral magnetic ionic liquids were synthesized and used to construct chiral magnetic ionic liquid aqueous two-phase systems for the extractive resolution of racemic amino acids. The phase behavior and equilibrium data were determined through experimental measurements, and satisfactory correlation performances were achieved. These results provide valuable reference for future applications in this field.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Thermodynamics
Paloma Carbonell-Hermida, Antonio Marcilla, Maria del Mar Olaya
Summary: During LLE data correlation, the behavior of models in completely miscible binary mixtures is often overlooked, leading to inconsistent results. Commercial tools like Aspen Plus may provide misleading correlations, while developing custom tools can ensure consistent parameters.
FLUID PHASE EQUILIBRIA
(2021)
Review
Biochemistry & Molecular Biology
Lirong Nie, Ziwei Zheng, Mingxia Lu, Shun Yao, Dong Guo
Summary: This article summarizes the phase behavior of IL-based ATPSs in chemical reactions and separation processes, and highlights the possible future directions.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Engineering, Chemical
Tian Yao, Hongmei Li, Yuanhang Ren, Meilin Feng, Yichen Hu, Huiling Yan, Lianxin Peng
Summary: The report introduces thermo-separating magnetic ionic liquids (MILs) for the first time, detailing the synthesis, characterization, and application of two PPG600-based thermo-separating MILs, which were used to create a novel MILATPS system. The system showed high extraction efficiencies for phenolic compounds, exceeding 90%, and demonstrated potential for industrial treatment of phenolic wastewater with efficient recovery processes.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Tian Yao, Qiang Li, Hongmei Li, Lianxin Peng, Yang Liu, Kaifeng Du
Summary: A novel chiral magnetic ionic liquid aqueous two-phase system was developed for the extractive resolution of racemic phenylalanine, achieving high optical purity in both L-phenylalanine and D-phenylalanine. This green and recyclable approach showed great potential in industry with consistently good resolution ability even in gram-scale.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Physical
Sara Mashhaditafreshi, Ali Haghtalab
Summary: Biphasic-aqueous systems have been extensively studied for their ability to simultaneously separate and purify active pharmaceutical molecules. In this study, we used a specific deep eutectic solvent to investigate the biphasic curve of the system and examined the separation of pharmaceuticals using ATPS. Our findings indicate that the pharmaceuticals preferentially partition into the top phase, which is rich in deep eutectic solvents. Additionally, we developed a thermodynamic model to describe the behavior of the aqueous two-phase system.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Alicio Wagner Vieira, Keycianne da Cruz Silva, Aparecida Barbosa Mageste, Guilherme Dias Rodrigues, Leandro Rodrigues de Lemos
Summary: This study characterized new ATPS formed by PVP10K with different salts and water, with findings showing that temperature and pH had minimal influence on the phase region, sodium sulfate was more efficient than zinc sulfate, and the partition of lycopene in ATPS was driven enthalpically.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Green & Sustainable Science & Technology
Tian Yao, Ya Gan, Qiang Li, Maoling Tan, Xiaodong Shi
Summary: This study discovered temperature-sensitive magnetic ionic liquids and successfully applied them in aqueous two-phase systems for efficient removal and recovery of dyes, showing great potential for separation-recovery processes and industrial treatment of dyed wastewater.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Chemistry, Physical
Akram Ali Nasser Mansoor Al-Haimi, Ke Wang, Xin Xu, Lianzheng Zhang, Dongmei Xu, Jun Gao, Yinglong Wang
Summary: The study utilized ionic liquid extractants to recover allyl alcohol, investigated various interactions through calculations and experiments, evaluated the performance of the extractants, and used the NRTL model to fit the data, enhancing the efficiency of allyl alcohol recovery.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Chemical
Kenia Marcatti de Sousa, Thailan Souza Pereira Lima, Ranyere Lucena de Souza, Bibiana Beatriz Nerli, Matheus M. Pereira, Cleide Mara Faria Soares, Alvaro Silva Lima
Summary: This study investigates the partitioning of antidepressants such as fluoxetine hydrochloride, paroxetine hydrochloride, and sertraline hydrochloride through the construction of phase diagrams for different biphasic systems. The driving force for phase separation is the comparison of hydrophobic/hydrophilic characteristics between the constituents, resulting in the selective isolation of pairs of these antidepressants. The recoveries were high, showing the effectiveness of the proposed systems in promoting the partitioning of antidepressants.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Yuntao Tang, Yige Zhang, Xi Chen, Xiaowen Xie, Ning Zhou, Zhifeng Dai, Yubing Xiong
Summary: Thermally induced reversible up/down migration of poly(ionic liquid)s in aqueous two-phase systems was achieved for the first time in this study. The upper and lower phases of the systems could be easily tuned using the grafting degree of modified poly(ionic liquid)s, and a reversible two-phase/single-phase transition was realized under UV irradiation.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Multidisciplinary Sciences
Javad Saien, Mansoureh Bahiraei, Farnaz Jafari
Summary: A novel hydrophobic deep eutectic solvent was evaluated for the extraction of phenol from aqueous solutions, showing excellent extraction capability with high solute distribution coefficients and separation factors. Thermodynamic models NRTL and UNIQUAC were employed to reproduce the experimental data, showing satisfactory agreement with low root mean square deviations.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Physical
Chaojie Pang, Jiage Liu, Rui Peng, Yingying Guo, Zhiyong Li, Huiyong Wang
Summary: A green, highly efficient and scalable tactic to exfoliate bulk titanium disulfide powders in aqueous ionic liquids solutions has been developed. The exfoliation yield can reach 57.6%, surpassing most values reported in literatures. This liquid phase delamination approach has great potential in manufacturing high activity electrocatalysis materials.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Chemistry, Physical
Xiaoxing Lu, Zhizhuo Lu, Rong Zhang, Lijiang Zhao, Hujun Xie
Summary: This study investigates the phase behaviors and pigment extraction performance of ionic liquid-based aqueous two-phase systems formed by piperazinium ILs and anionic surfactants, showing a preference for curcumin separation. Factors influencing extraction efficiency and distribution coefficients, as well as the separation mechanism, were evaluated.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Xuezhi Dai, Xiaolian Qiang, Tian Yao, Pengfei Chen
Summary: This study introduces the preparation and characterization of magnetic microemulsions, which show unique potential applications under external magnetic field manipulation, with high magnetic susceptibility and low viscosity, showing good rheological properties.
JOURNAL OF PHYSICAL CHEMISTRY B
(2021)
Article
Biochemical Research Methods
Tian Yao, Yuxin Liao, Shasha Li, Liangzhi Qiao, Kaifeng Du
Summary: In this study, a tentacle-type cellulose monolith immobilized with m-xylene bisphosphonate was prepared for lysozyme purification, showing high static and dynamic adsorption capacity. Furthermore, the material exhibited excellent selectivity and successfully enriched lysozyme from diluted chicken egg white.
JOURNAL OF CHROMATOGRAPHY A
(2021)
Article
Chemistry, Physical
Tian Yao, Hongmei Li, Jiawen Yang, Xiaodong Shi, Huiling Yan, Lianxin Peng
Summary: In this study, three novel chiral magnetic ionic liquids were synthesized and used to construct chiral magnetic ionic liquid aqueous two-phase systems for the extractive resolution of racemic amino acids. The phase behavior and equilibrium data were determined through experimental measurements, and satisfactory correlation performances were achieved. These results provide valuable reference for future applications in this field.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Microbiology
Peng Wu, Tian Yao, Yuanhang Ren, Jinghua Ye, Yuan Qing, Qiang Li, Mingying Gui
Summary: This study sequenced and compared the mitochondrial genomes of two Pisolithus species, revealing certain characteristics and differences. The research on Pisolithus mitochondrial genomes contributes to a better understanding of the evolutionary history of these fungal species.
FRONTIERS IN MICROBIOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Huiling Yan, Changying Liu, Jianglin Zhao, Xueling Ye, Qi Wu, Tian Yao, Lianxin Peng, Liang Zou, Gang Zhao
Summary: This study identified and investigated 38 FtNF-Y genes in Tartary buckwheat, providing insights into their gene structures, genomic mapping, phylogenetic relationships, and gene expression profiles. The study revealed functional conservation and specificity of FtNF-Y genes, as well as potential functional similarities among NF-Ys from different plant species. Expression analysis indicated diverse functions of FtNF-Y genes in different tissues and fruit development stages, offering clues for enhancing fruit quality in Tartary buckwheat.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Green & Sustainable Science & Technology
Tian Yao, Ya Gan, Qiang Li, Maoling Tan, Xiaodong Shi
Summary: This study discovered temperature-sensitive magnetic ionic liquids and successfully applied them in aqueous two-phase systems for efficient removal and recovery of dyes, showing great potential for separation-recovery processes and industrial treatment of dyed wastewater.
JOURNAL OF CLEANER PRODUCTION
(2021)
Article
Engineering, Chemical
Tian Yao, Hongmei Li, Yuanhang Ren, Meilin Feng, Yichen Hu, Huiling Yan, Lianxin Peng
Summary: The report introduces thermo-separating magnetic ionic liquids (MILs) for the first time, detailing the synthesis, characterization, and application of two PPG600-based thermo-separating MILs, which were used to create a novel MILATPS system. The system showed high extraction efficiencies for phenolic compounds, exceeding 90%, and demonstrated potential for industrial treatment of phenolic wastewater with efficient recovery processes.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Tian Yao, Qiang Li, Hongmei Li, Lianxin Peng, Yang Liu, Kaifeng Du
Summary: A novel chiral magnetic ionic liquid aqueous two-phase system was developed for the extractive resolution of racemic phenylalanine, achieving high optical purity in both L-phenylalanine and D-phenylalanine. This green and recyclable approach showed great potential in industry with consistently good resolution ability even in gram-scale.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Physical
Tian Yao, Jialing Song, Ya Gan, Cailing Feng, Lianxin Peng
Summary: This study successfully constructed temperature-sensitive magnetic ionic liquid aqueous two-phase systems and explored their potential applications in extraction and separation. The experimental results and theoretical correlations provide valuable references for future applications.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Review
Biochemical Research Methods
Tian Yao, Jialing Song, Ya Gan, Liangzhi Qiao, Kaifeng Du
Summary: This paper describes the recent developments in the applications of cellulose-based absorbents as chromatographic medium, and explains the current situation of cellulose-based chromatographic medium from the aspects of cellulose dissolution, generation of spherical particles, and improvement of adsorption properties.
JOURNAL OF CHROMATOGRAPHY A
(2022)
Article
Biochemistry & Molecular Biology
Yuanhang Ren, Xuan He, Xiyue Yan, Yanting Yang, Qiang Li, Tian Yao, Lidan Lu, Lianxin Peng, Liang Zou
Summary: This study investigated the cytotoxic effect and mechanism of toxicity of the insecticide Chlorfenapyr (CHL) on human liver cells. The results showed that CHL induced cellular toxicity by causing mitochondrial damage, reactive oxygen species accumulation, and autophagy in HepG2 cells. Additionally, DNA damage and cell cycle arrest were observed. This study suggests that CHL induces cytotoxicity associated with programmed cell death and DNA damage in HepG2 cells.
Article
Chemistry, Applied
Huiling Yan, Hongxu Chen, Jianglin Zhao, Tian Yao, Xiaochun Ding
Summary: The aim of this study was to investigate the effects of 0.5 M hydrogen peroxide (H2O2) on flavor, texture quality and reactive oxygen species (ROS) metabolism in harvested 'Hongshi' kiwifruit. Results demonstrated that H2O2 accelerated changes in flavor detected by electronic tongue (e-tongue) and electronic nose (e-nose). In addition, H2O2 treatment promoted fruit softening, as evidenced by an earlier increment in the activities of alpha-amylase, total amylase, pectin lyase, and pectin methylesterase. These results indicate that H2O2 accelerates flavor formation and softening by regulating ROS metabolism in kiwifruit.
Article
Microbiology
Yu Zhang, Chang-Wei Lei, Xuan Chen, Tian-Ge Yao, Jing-Wen Yu, Wan-Long Hu, Xuan Mao, Hong-Ning Wang
FRONTIERS IN MICROBIOLOGY
(2020)
Article
Chemistry, Applied
Tian Yao, Kaifeng Du
Article
Chemistry, Multidisciplinary
Kaifeng Du, Tian Yao
Article
Chemistry, Physical
Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad
Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio
Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie
Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin
Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei
Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov
Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev
Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena
Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang
Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu
Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete
Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden
Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang
Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Correction
Chemistry, Physical
V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy
Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
