Iridium(III)-Catalyzed Selective Sulfonamidation ofo-Carborane with Sulfonyl Azide by Carboxylic Acid-Assisted B(4)-H Bond Activation

Iridium(III)-Catalyzed Direct CH Sulfonamidation of 2-Aryl-1,2,3-triazoleN-Oxides with Sulfonyl Azides

(2016) Bingfeng Zhu et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible-Light-Promoted Photocatalytic B−C Coupling via a Boron-Centered Carboranyl Radical: Facile Synthesis of B(3)-Arylated o -Carboranes

(2016) Da Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Regioselective Hydroxylation of Cage B−H Bonds ofo-Carboranes with O2or Air

(2016) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inductive effects of 10 and 12-vertex closo-carborane anions: cluster size and charge make a difference

(2016) Jess Estrada et al.   CHEMICAL COMMUNICATIONS

Reversible water activation driven by contraction and expansion of a 12-vertex-closo-12-vertex-nido biscarborane cluster

(2016) Yuen Onn Wong et al.   CHEMICAL COMMUNICATIONS

Palladium catalyzed/silver tuned selective mono-/tetra-acetoxylation of o-carboranes via B–H activation

(2016) Ke Cao et al.   CHEMICAL COMMUNICATIONS

An Unusual Natural Product Primary Sulfonamide: Synthesis, Carbonic Anhydrase Inhibition, and Protein X-ray Structures of Psammaplin C

(2016) Prashant Mujumdar et al.   JOURNAL OF MEDICINAL CHEMISTRY

Discovery and Optimization of N-(4-(3-Aminophenyl)thiazol-2-yl)acetamide as a Novel Scaffold Active against Sensitive and Resistant Cancer Cells

(2016) Antoine Millet et al.   JOURNAL OF MEDICINAL CHEMISTRY

Biological Characterization and in Vivo Assessment of the Activity of a New Synthetic Macrocyclic Antifungal Compound

(2016) Davide Deodato et al.   JOURNAL OF MEDICINAL CHEMISTRY

B–N, B–O, and B–CN Bond Formation via Palladium-Catalyzed Cross-Coupling of B-Bromo-Carboranes

(2016) Rafal M. Dziedzic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal Catalyzed Direct Amination of the Cage B(4)–H Bond in o-Carboranes: Synthesis of Tertiary, Secondary, and Primary o-Carboranyl Amines

(2016) Hairong Lyu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study

(2016) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(iii)-catalyzed regioselective C7-sulfonamidation of indoles

(2016) Zengqiang Song et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides

(2016) Youyoung Kim et al.   ORGANIC LETTERS

Rh- and Cu-Cocatalyzed Aerobic Oxidative Approach to Quinazolines via [4 + 2] C–H Annulation with Alkyl Azides

(2016) Xiaoyang Wang et al.   ORGANIC LETTERS

Changing the Charge: Electrostatic Effects in Pd-Catalyzed Cross-Coupling

(2016) Allen L. Chan et al.   ORGANOMETALLICS

[3-N2-o-C2B10H11][BF4]: a useful synthon for multiple cage boron functionalizations of o-carborane

(2016) Da Zhao et al.   Chemical Science

Palladium catalyzed regioselective B–C(sp) coupling via direct cage B–H activation: synthesis of B(4)-alkynylated o-carboranes

(2016) Yangjian Quan et al.   Chemical Science

A Computational Mechanistic Study of Amidation of Quinoline N-Oxide: The Relative Stability of Amido Insertion Intermediates Determines the Regioselectivity

(2016) Jian-Biao Liu et al.   ACS Catalysis

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Regioselective Diarylation of o -Carboranes By Direct Cage B−H Activation

(2015) Yangjian Quan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Dialkenylation of Cage BH Bonds in o -Carboranes through Cross-Coupling Reactions

(2015) Hairong Lyu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acids as Traceless Directing Groups for the Rhodium(III)-Catalyzed Decarboxylative CH Arylation of Thiophenes

(2015) Yuanfei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium(III)-Catalyzed Benzylic Amine Directed CH Sulfonamidation of Arenes with Sulfonyl Azides

(2015) Heng Chen et al.   ChemCatChem

Palladium catalyzed selective mono-arylation of o-carboranes via B–H activation

(2015) Ke Cao et al.   CHEMICAL COMMUNICATIONS

Salicylic acids as readily available starting materials for the synthesis of meta-substituted biaryls

(2015) Junfei Luo et al.   CHEMICAL COMMUNICATIONS

Ru(ii)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp3)–H activation

(2015) Bingxian Liu et al.   CHEMICAL COMMUNICATIONS

Facial Synthesis ofo-Carborane-Substituted Alkenes and Allenes by a Regioselective Ene Reaction of 1,3-Dehydro-o-carborane

(2015) Da Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct CH Amidation of Benzoic Acids to Introducemeta- andpara-Amino Groups by Tandem Decarboxylation

(2015) Donggun Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Regioselective Direct C-H Amidation of 2,4-Diarylquinazoline with Sulfonyl Azides: An Example of Steric Hindrance Regulated Mono- and Diamidation Selectivity

(2015) Chunyan Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Design, Synthesis, and Biological Activity of Sulfonamide Analogues of Antofine and Cryptopleurine as Potent and Orally Active Antitumor Agents

(2015) Yongseok Kwon et al.   JOURNAL OF MEDICINAL CHEMISTRY

Iridium-Catalyzed Direct C–H Sulfamidation of Aryl Nitrones with Sulfonyl Azides at Room Temperature

(2015) Chao Pi et al.   JOURNAL OF ORGANIC CHEMISTRY

A steric tethering approach enables palladium-catalysed C–H activation of primary amino alcohols

(2015) Jonas Calleja et al.   Nature Chemistry

Cobalt Catalyzed C–H and N–H Bond Annulation of Sulfonamide with Terminal and Internal Alkynes

(2015) Deepti Kalsi et al.   ORGANIC LETTERS

Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation

(2015) Donghyeon Gwon et al.   TETRAHEDRON

Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules

(2015) Jiao Jiao et al.   ACS Catalysis

Palladium catalyzed regioselective mono-alkenylation of o-carboranes via Heck type coupling reaction of a cage B–H bond

(2015) Ji Wu et al.   RSC Advances

Air-Stable Carbonyl(pentamethylcyclopentadienyl)cobalt Diiodide Complex as a Precursor for Cationic (Pentamethylcyclopentadienyl)cobalt(III) Catalysis: Application for Directed C-2 Selective CH Amidation of Indoles

(2014) Bo Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Carboxylate-Directed CH Functionalization

(2014) Guangfa Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Direct CH Amidation with Weakly Coordinating Carbonyl Directing Groups under Mild Conditions

(2014) Jinwoo Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,3-Dehydro-o-Carborane: Generation and Reaction with Arenes

(2014) Da Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 1,2-amino alcohols via catalytic C–H amidation of sp3 methyl C–H bonds

(2014) Taek Kang et al.   CHEMICAL COMMUNICATIONS

Metal–metal redox synergy in selective B–H activation of ortho-carborane-9,12-dithiolate

(2014) Xiaolei Zhang et al.   CHEMICAL COMMUNICATIONS

Ruthenium-Catalyzed C7 Amidation of Indoline CH Bonds with Sulfonyl Azides

(2014) Changduo Pan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to aP-Stereogenic Center

(2014) Donghyeon Gwon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Direct C–H Amidation of Azobenzenes with Sulfonyl Azides: A Synthetic Route to Sterically Hindered ortho-Substituted Aromatic Azo Compounds

(2014) Xuefeng Jia et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium(III)-Catalyzed Direct C-7 Amination of Indolines with Organic Azides

(2014) Kwangmin Shin et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Ortho Olefination of Aryl Sulfonamide via Rhodium-Catalyzed Direct C–H Bond Activation

(2014) Weijia Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Direct ortho C–N Bond Formation of Aromatic Azo Compounds with Azides

(2014) Hao Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ru(II)-Catalyzed Selective C–H Amination of Xanthones and Chromones with Sulfonyl Azides: Synthesis and Anticancer Evaluation

(2014) Youngmi Shin et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp3)–H Functionalization

(2014) Nuancheng Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium Catalyzed Regioselective Cage Boron Alkenylation of o-Carboranes via Direct Cage B–H Activation

(2014) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Mediated Regioselective B–H/C–H Activation of Carborane Cage: A Facile Synthetic Route to Metallacycles with a Carborane Backbone

(2014) Zi-Jian Yao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of the Rhodium-Catalyzed Direct C–H Amination Reaction Using Azides as the Nitrogen Source

(2014) Sae Hume Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Mediated Three-Component Cascade Cyclization: Selective Cage B–C(sp2) Coupling of Carborane with Aromatics and Synthesis of Carborane-Fused Tricyclics

(2014) Yangjian Quan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intermolecular Amidation of sp3 C–H Bonds: Late-Stage Functionalization of an Unactivated Methyl Group

(2014) Taek Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Introduction of Heteroatoms at the C-8 Position of Quinoline N-Oxides: Remote C–H Activation Using N-Oxide as a Stepping Stone

(2014) Heejun Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot

(2014) Taekyu Ryu et al.   ORGANIC LETTERS

Copper-Catalyzed C(sp2)–H Amidation with Azides as Amino Sources

(2014) Jiangling Peng et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Direct C–H Amidation of Arenes: A Mechanistic Study

(2014) Lu−Lu Zhang et al.   ORGANOMETALLICS

Carborane-Based Carbonic Anhydrase Inhibitors

(2013) Jiří Brynda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct CH Amination of Arenes with Alkyl Azides under Rhodium Catalysis

(2013) Kwangmin Shin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ru(ii)-catalyzed intermolecular C–H amidation of weakly coordinating ketones

(2013) Qing-Zhong Zheng et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed ortho-halogenation of protected anilines

(2013) Beatriz Urones et al.   CHEMICAL COMMUNICATIONS

Ru(ii)-catalyzed intermolecular ortho-C–H amidation of aromatic ketones with sulfonyl azides

(2013) M. Bhanuchandra et al.   CHEMICAL COMMUNICATIONS

Methods to produce B–C, B–P, B–N and B–S bonds in boron clusters

(2013) David Olid et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-Catalyzed Direct CH Amidation of Arenes Including Weakly Coordinating Aromatic Ketones

(2013) Jiyu Kim et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Synthesis of Amides from Aldehydes and Azides by Chelation-Assisted CH Bond Activation

(2013) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Direct Arene C–H Bond Amidation with Sulfonyl- and Aryl Azides

(2013) Donggun Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Unprecedented Boron-Functionalized Carborane Derivatives by Facile and Selective Cobalt-Induced B–H Activation

(2013) Zhaojin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of [closo-B12(OH)11NH3]−: A New Heterobifunctional Dodecaborane Scaffold for Drug Delivery Applications

(2013) Oleg Bondarev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Selective Fluorination of o-Carboranes

(2013) Zaozao Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RhIII/CuII-Cocatalyzed Synthesis of 1H-Indazoles through C–H Amidation and N–N Bond Formation

(2013) Da-Gang Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic C–H/C–H′ Cross-Biaryl Coupling: C-Selective Arylation of Sulfonanilides with Aromatic Hydrocarbons

(2013) Motoki Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expedient C–H Amidations of Heteroaryl Arenes Catalyzed by Versatile Ruthenium(II) Catalysts

(2013) Vedhagiri S. Thirunavukkarasu et al.   ORGANIC LETTERS

Sulfoximine Directed Intermolecular o-C–H Amidation of Arenes with Sulfonyl Azides

(2013) M. Ramu Yadav et al.   ORGANIC LETTERS

Structure and Bonding of a Zwitterionic Iridium Complex Supported by a Phosphine with the Parent Carba-closo-dodecaborate CB11H11– Ligand Substituent

(2013) Ahmad El-Hellani et al.   ORGANOMETALLICS

Improved Cav2.2 Channel Inhibitors through a gem-Dimethylsulfone Bioisostere Replacement of a Labile Sulfonamide

(2013) Pengcheng P. Shao et al.   ACS Medicinal Chemistry Letters

Cp*IrIII-Catalyzed Oxidative Coupling of Benzoic Acids with Alkynes

(2013) Daniel A. Frasco et al.   ACS Catalysis

Diverse Reactivity in a Rhodium(III)-Catalyzed Oxidative Coupling ofN-Allyl Arenesulfonamides with Alkynes

(2012) Dongqi Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Sultams by Rhodium(III)-Catalyzed Directed CH Activation

(2012) Manh V. Pham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Pd-Catalyzed Decarboxylative Cross-Coupling Reaction between Aryl Carboxylic Acids: Synthesis of Biaryl Compounds

(2012) Peng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding Reactivity and Stereoselectivity in Palladium-Catalyzed Diastereoselective sp3 C–H Bond Activation: Intermediate Characterization and Computational Studies

(2012) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Promoted B–H and C–H Activation: Facile B–C Coupling of Carboranedithiolate and Cyclopentadienyl

(2012) Rui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation

(2012) Ji Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C–H bond activation

(2012) Jingjing Shi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Indolo [1,2-a]Quinoxalines via a Pd-Catalyzed Regioselective C–H Olefination/Cyclization Sequence

(2012) Liang Wang et al.   ORGANIC LETTERS

Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes

(2012) Alexander M. Spokoyny et al.   ORGANOMETALLICS

Carboxylates as sources of carbon nucleophiles and electrophiles: comparison of decarboxylative and decarbonylative pathways

(2012) Wojciech I. Dzik et al.   Chemical Science

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of quadruped-shaped polyfunctionalized o-carborane synthons

(2011) Alberto V. Puga et al.   CHEMICAL COMMUNICATIONS

Rh(III)-Catalyzed Oxidative Olefination ofN-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

(2011) Xuting Li et al.   ORGANIC LETTERS

Pd-Catalyzed Intramolecular Oxidative C–H Amination: Synthesis of Carbazoles

(2011) So Won Youn et al.   ORGANIC LETTERS

Monophosphine-o-Carborane Sulfide as a Noninnocent Ligand for C,S, S,S′, and B,S,S′ Coordination Modes of Half-Sandwich Iridium and Rhodium Complexes

(2011) Zi-Jian Yao et al.   ORGANOMETALLICS

Novel Approach to Aminocarboranes by Mild Amidation of Selected Iodo-carboranes

(2010) Yulia Sevryugina et al.   INORGANIC CHEMISTRY

Pd-catalyzed allylic amination in supercritical carbon dioxide: Synthesis of carborane-containing terpenoids

(2010) Sergey E. Lyubimov et al.   JOURNAL OF SUPERCRITICAL FLUIDS

Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetates with Aryl Halides and Triflates

(2010) Rui Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water

(2010) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

(2010) Tom G. Driver   ORGANIC & BIOMOLECULAR CHEMISTRY

Pd-Catalyzed Dearboxylative Heck Coupling with Dioxygen as the Terminal Oxidant

(2010) Zhengjiang Fu et al.   ORGANIC LETTERS

Synthesis of 3-Aryl-1,2-dicarba-closo-dodecaboranes by Suzuki-Miyaura Coupling Reaction

(2009) Yasuyuki Endo et al.   HETEROCYCLES

Pd(O2CCF3)2/Benzoquinone: A Versatile Catalyst System for the Decarboxylative Olefination of Arene Carboxylic Acids

(2009) Peng Hu et al.   ORGANIC LETTERS

Some aspects of the chemical behavior of icosahedral carboranes

(2009) V. N. Kalinin et al.   RUSSIAN CHEMICAL BULLETIN

Catalytic Amidation of 9-Iodo-m-carborane and 2-Iodo-p-carborane at a Boron Atom

(2008) Sergey N. Mukhin et al.   ORGANOMETALLICS