Reversible water activation driven by contraction and expansion of a 12-vertex-closo-12-vertex-nido biscarborane cluster

Carborane Substituents Promote Direct Electrophilic Insertion over Reduction-Metalation Reactions

(2016) Wing Y. Man et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unique properties of C,C′-linked nido-biscarborane tetraanions. Synthesis, structure and bonding of ruthenium monocarbollide via unprecedented cage carbon extrusion

(2016) Da Zhao et al.   CHEMICAL COMMUNICATIONS

Synthesis of the First Example of the 12-Vertex-closo /12-Vertex-nido Biscarborane Cluster by a Metal-Free B−H Activation at a Phosphorus(III) Center

(2016) Yuen Onn Wong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Probing the reactivity of pentaphenylborole with N–H, O–H, P–H, and S–H bonds

(2016) Sam Yruegas et al.   DALTON TRANSACTIONS

Unprecedented flexibility of the 1,1′-bis(o-carborane) ligand: catalytically-active species stabilised by B-agostic B–H⇀Ru interactions

(2016) Laura E. Riley et al.   DALTON TRANSACTIONS

Facile synthesis of closo-nido bis(carborane) and its highly regioselective halogenation

(2016) Grigoriy S. Kazakov et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene

(2016) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center

(2016) Bennett J. Eleazer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants

(2016) Marco S. Messina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Luminescent metal complexes featuring photophysically innocent boron cluster ligands

(2016) Kent O. Kirlikovali et al.   Chemical Science

Ambiphilic boron in 1,4,2,5-diazadiborinine

(2016) Baolin Wang et al.   Nature Communications

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Icosahedral metallacarborane/carborane species derived from 1,1′-bis(o-carborane)

(2015) Gobika Thiripuranathar et al.   DALTON TRANSACTIONS

Carboranes in the chemist's toolbox

(2015) Russell N. Grimes   DALTON TRANSACTIONS

Synthesis of a Hybrid m-Terphenyl/o-Carborane Building Block: Applications in Phosphine Ligand Design

(2015) Christopher A. Lugo et al.   INORGANIC CHEMISTRY

Synthesis, characterization and radiolabeling of carborane-functionalized tetrazines for use in inverse electron demand Diels–Alder ligation reactions

(2015) Afaf R. Genady et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Pseudo -aromatic bis- o -carborane iridium and rhodium complexes

(2015) Zi-Jian Yao et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Resisting B–H oxidative addition: The divergent reactivity of the o -carborane and carba- closo -dodecaborate ligand substituents

(2015) Jess Estrada et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Metal-free catalytic C-H bond activation and borylation of heteroarenes

(2015) M.-A. Legare et al.   SCIENCE

Frustrated Lewis Pairs: From Concept to Catalysis

(2014) Douglas W. Stephan   ACCOUNTS OF CHEMICAL RESEARCH

Reactivity of Diruthenium and Dirhodium Analogues of Pentaborane(9): Agostic versus Boratrane Complexes

(2014) R. S. Anju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π Aromaticity and Three-Dimensional Aromaticity: Two sides of the Same Coin?

(2014) Jordi Poater et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fusing N-Heterocyclic Carbenes with Carborane Anions

(2014) Ahmad El-Hellani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane

(2014) Nicole Harmgarth et al.   CHEMICAL COMMUNICATIONS

Preparation and evaluation of carborane-derived inhibitors of prostate specific membrane antigen (PSMA)

(2014) Mohamed E. El-Zaria et al.   DALTON TRANSACTIONS

Reversible Intermolecular E–H Oxidative Addition to a Geometrically Deformed and Structurally Dynamic Phosphorous Triamide

(2014) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane

(2013) Joseph A. Ioppolo et al.   CHEMICAL COMMUNICATIONS

Structure and Bonding of a Zwitterionic Iridium Complex Supported by a Phosphine with the Parent Carba-closo-dodecaborate CB11H11– Ligand Substituent

(2013) Ahmad El-Hellani et al.   ORGANOMETALLICS

New ligand platforms featuring boron-rich clusters as organomimetic substituents

(2013) Alexander M. Spokoyny   PURE AND APPLIED CHEMISTRY

Metallacarboranes and their interactions: theoretical insights and their applicability

(2012) Pau Farràs et al.   CHEMICAL SOCIETY REVIEWS

Reaction of o-carboranes with sterically demanding N-heterocyclic carbene: synthesis and structural characterization of 1 : 1 adducts

(2012) Fangrui Zheng et al.   DALTON TRANSACTIONS

Carbaboranes as Pharmacophores: Properties, Synthesis, and Application Strategies

(2011) Matthias Scholz et al.   CHEMICAL REVIEWS

Synthesis and Reactivity of 4,5-[1,2-Dicarba-closo-dodecaborano(12)]-1,3-diselenacyclopentane: Opening of the Icosahedron to Give a Zwitterionic Intermediate and Conversion into 7,8-Dicarba-nido-undecaborate(1−)

(2011) Bernd Wrackmeyer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Relaxed but Highly Compact Diansa Metallacyclophanes

(2011) Pau Farràs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room-Temperature CC Bond Cleavage of an Arene by a Metallacarborane

(2010) David Ellis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The first supraicosahedral bis(heteroborane)

(2010) David Ellis et al.   CHEMICAL COMMUNICATIONS

Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes

(2010) Charlotte E. Willans et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Properties of Carborane-AppendedC3-Symmetrical Extended π Systems

(2010) Barada Prasanna Dash et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Reaction of a 14-Vertex Carborane with Nucleophiles: Formation ofnido-C2B12,nido-C2B11,andcloso-CB11Carborane Anions

(2009) Jian Zhang et al.   INORGANIC CHEMISTRY

Identification of an intermediate in the deboronation of ortho-carborane: an adduct of ortho-carborane with two nucleophiles on one boron atom

(2008) Yoshiyuki Taoda et al.   CHEMICAL COMMUNICATIONS

A simple entry into nido-C2B10 clusters: HCl promoted cleavage of the C–C bond in ortho-carboranyl diphosphines

(2008) Jonathan P. H. Charmant et al.   DALTON TRANSACTIONS

Influence of the solvent and R groups on the structure of (carboranyl)R2PI2 compounds in solution. Crystal structure of the first iodophosphonium salt incorporating the anion [7,8-nido-C2B9H10]−

(2008) Rosario Núñez et al.   DALTON TRANSACTIONS