Direct Access to Indoles by IrIII -Catalyzed C-H Functionalization of Acetanilides with Diazo Compounds

Iridium- and Rhodium-Catalyzed Carbocyclization between 2-Phenylimidazo[1,2-a]pyridine and α-Diazo Esters

(2016) Yunyun Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Multiple Roles of the Pyrimidyl Group in the Rhodium-Catalyzed Regioselective Synthesis and Functionalization of Indole-3-carboxylic Acid Esters

(2016) Hui Jiang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Synthesis of Indole Derivatives From Pyrimidyl-Substituted Anilines and Diazo Compounds

(2016) Ke Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium(II)-Catalyzed C−H Activation of Imidamides and Divergent Couplings with Diazo Compounds: Substrate-Controlled Synthesis of Indoles and 3H-Indoles

(2016) Yunyun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Lewis Acid/Cp*CoIIICatalyzed C−H Bond Activation for the Synthesis of Isoquinolin-3-ones

(2016) Ju Hyun Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

IrIII-Catalyzed One-Pot Cascade Synthesis of Pentacyclic-Fused Carbazoles from Indoles and Diazoes

(2016) Shuai-Shuai Li et al.   Chemistry-An Asian Journal

Iridium(III)-Catalyzed Regioselective Carbenoid Insertion C-H Alkylation by α-Diazotized Meldrum's Acid

(2016) Honggui Lv et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium(iii)-catalyzed regioselective C7-sulfonamidation of indoles

(2016) Zengqiang Song et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides

(2016) Youyoung Kim et al.   ORGANIC LETTERS

Amidines for Versatile Cobalt(III)-Catalyzed Synthesis of Isoquinolines through C–H Functionalization with Diazo Compounds

(2016) Jie Li et al.   ORGANIC LETTERS

Ir(III)-Catalyzed Carbenoid Functionalization of Benzamides: Synthesis of N-Methoxyisoquinolinediones and N-Methoxyisoquinolinones

(2016) Ravindra S. Phatake et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–C/C–N Coupling of Imidates with α-Diazo Imidamide: Synthesis of Isoquinoline-Fused Indoles

(2016) He Wang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Synthesis of N-Unprotected Indoles from Imidamides and Diazo Ketoesters via C–H Activation and C–C/C–N Bond Cleavage

(2016) Zisong Qi et al.   ORGANIC LETTERS

Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles

(2016) Qingquan Lu et al.   ACS Catalysis

Ir(iii)-catalyzed synthesis of isoquinolines from benzimidates and α-diazocarbonyl compounds

(2016) Xiaobo Yang et al.   RSC Advances

Iridium(iii)- and rhodium(iii)-catalyzed coupling of anilines with α-diazoesters via chelation-assisted C–H activation

(2016) Guo-Dong Tang et al.   Organic Chemistry Frontiers

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination

(2015) Kwangmin Shin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Regioselective C7-Functionalization of N -Pivaloylindoles

(2015) Lanting Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral Rhodium-Catalyzed CH Functionalization of ArylamineN-Oxides with Diazo Compounds: Primary C(sp3)H/C(sp2)H Activation and Oxygen-Atom Transfer

(2015) Bing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [4+1] Cyclative Capture Approach to 3H-Indole-N-oxides at Room Temperature by Rhodium(III)-Catalyzed CH Activation

(2015) Yaxi Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt(III)-Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

(2015) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective synthesis of multisubstituted isoquinolones and pyridones via Rh(iii)-catalyzed annulation reactions

(2015) Liangliang Shi et al.   CHEMICAL COMMUNICATIONS

C–H bond functionalization based on metal carbene migratory insertion

(2015) Fangdong Hu et al.   CHEMICAL COMMUNICATIONS

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2015) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Cp*Rh(iii) and Cp*Ir(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

(2015) Shang-Shi Zhang et al.   CHEMICAL COMMUNICATIONS

Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis

(2015) Neeraj Kumar Mishra et al.   CHEMICAL COMMUNICATIONS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanocrystalline magnesium oxide-stabilized palladium(0): an efficient and reusable catalyst for synthesis of N-(2-pyridyl)indoles

(2015) Police Vishnuvardhan Reddy et al.   NEW JOURNAL OF CHEMISTRY

Synthesis of indoles and polycyclic amides via ruthenium(ii)-catalyzed C–H activation and annulation

(2015) Hui Lin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(III)-Catalyzed Direct Coupling of Azobenzenes with α-Diazo Esters: Facile Synthesis of Cinnolin-3(2H)-ones

(2015) Satyasheel Sharma et al.   ORGANIC LETTERS

Synthesis of Cinnolin-3(2H)-one Derivatives from Rh-Catalyzed Reaction of Azobenzenes with Diazotized Meldrum’s Acid

(2015) Jeong-Yu Son et al.   ORGANIC LETTERS

Ir(III)-Catalyzed Synthesis of Isoquinoline N-Oxides from Aryloxime and α-Diazocarbonyl Compounds

(2015) Ravindra S. Phatake et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–H Cyclization of Arylnitrones with Diazo Compounds: Access to N-Hydroxyindolines

(2015) Ramesh B. Dateer et al.   ORGANIC LETTERS

Rh(III)-Catalyzed [4 + 2] Annulation of Indoles with Diazo Compounds: Access to Pyrimido[1,6-a]indole-1(2H)-ones

(2015) Xun Chen et al.   ORGANIC LETTERS

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Oxidative Annulation of Anilides with Internal Alkynes Using an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Catalyst Under Ambient Conditions

(2014) Yuki Hoshino et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of Isoindolones by Chiral Cyclopentadienyl-Rhodium(III)-Catalyzed CH Functionalizations

(2014) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh(iii)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water

(2014) Yujie Liang et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes

(2014) Ying-Feng Han et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(III)- and Iridium(III)-Catalyzed C7 Alkylation of Indolines with Diazo Compounds

(2014) Wen Ai  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intramolecular Redox-Neutral Annulation of Tethered Alkynes: Formal Total Synthesis of (±)-Goniomitine

(2014) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ir(III)-Catalyzed Aromatic C–H Bond Functionalization via Metal Carbene Migratory Insertion

(2014) Ying Xia et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams

(2014) Hon-Wah Lam et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Isoquinoline skeleton synthesis via chelation-assisted C−H activation

(2014) Ruoyu He et al.   TETRAHEDRON LETTERS

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

(2014) Min Zhang et al.   Organic Chemistry Frontiers

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium(III)-CatalyzedorthoAlkenylation ofN-Phenoxyacetamides withN-Tosylhydrazones or Diazoesters through CH Activation

(2013) Fangdong Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed alkyne annulation by anilines: versatile indole synthesis by C–H/N–H functionalization

(2013) Weifeng Song et al.   CHEMICAL COMMUNICATIONS

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds

(2013) Zhuangzhi Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient and Versatile Synthesis of Indoles from Enamines and Imines by Cross-Dehydrogenative Coupling

(2012) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Ruthenium(II) Catalysts for Oxidative C–H/N–H Bond Functionalizations of Anilines with Removable Directing Group: Synthesis of Indoles in Water

(2012) Lutz Ackermann et al.   ORGANIC LETTERS

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis ofN-(2-Pyridyl)indoles via Pd(II)-Catalyzed Oxidative Coupling

(2011) Jinlei Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Preparation of indoles via iron catalyzed direct oxidative coupling

(2010) Zheng-Hui Guan et al.   CHEMICAL COMMUNICATIONS

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed CC Bond Formation through CH Functionalization: Synthesis of Multisubstituted Indoles fromN-Aryl Enaminones

(2009) Roberta Bernini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Promoted Hydrohydrazination of Terminal Alkynes: An Efficient Domino Synthesis of Indoles

(2008) Karolin Alex et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Cyclization ofN-Aryl Enamines: From Anilines to Indoles

(2008) Sebastian Würtz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Indoles via Domino Reaction ofN-Aryl Amides and Ethyl Diazoacetate

(2008) Sun-Liang Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elaboration of 2-(Trifluoromethyl)indoles via a Cascade Coupling/Condensation/Deacylation Process

(2008) Yu Chen et al.   ORGANIC LETTERS

Palladium-Catalyzed Aryl Amination–Heck Cyclization Cascade: A One-Flask Approach to 3-Substituted Indoles

(2007) Thomas Jensen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Multicomponent Synthesis of Indoles from 2-Iodobenzoic Acid

(2007) Olivier Leogane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION