4.6 Article

Production of biochars from Ca impregnated ramie biomass (Boehmeria nivea (L.) Gaud.) and their phosphate removal potential

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RSC ADVANCES
卷 6, 期 7, 页码 5871-5880

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra22142k

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资金

  1. National Natural Science Foundation of China [41271332, 51521006]
  2. Hunan Provincial Innovation Foundation For Postgraduate [CX2015B090, CX2015B092]

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This work explored the efficiency and mechanisms of phosphate (P) removal by Ca-impregnated biochar prepared from CaCl2-pretreated ramie stem (Ca-RSB) and ramie bark (Ca-RBB). The properties of Ca-modified biochar were analyzed using elemental analysis, scanning electron microscopy (SEM), BET specific surface analysis, energy-dispersive X-ray analysis (EDS), Fourier transform infrared (FTIR) and a zeta potential meter. The results of characterization suggested that the Ca-RSB had a much higher H/C ratio, total pore volume, BET surface area and more functional groups compared with pristine biochar (RSB). In addition, a higher yield of Ca-RSB (50.8%) than RSB (28.0%) was also observed. Comparison experiments suggested that Ca-RSB showed higher adsorption capacity than Ca-RBB and the adsorption amount of Ca-RSB was more than two-folds that of RSB. Adsorption experimental data fitted well with pseudo-second order kinetics and the Langmuir isotherm. The intra-particle diffusion and Boyd's film-diffusion models revealed that the rate-controlled step was controlled by film-diffusion initially and then followed by intra-particle diffusion. Electrostatic attraction served as the main force to adsorb phosphates at a lower pH, and the precipitation and surface deposition took over at higher pH. The results of this study indicated that Ca-RSB is a potential effective and low-cost adsorbent for phosphate removal from wastewater.

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