☆ 4.4 Article

Efficient and environmental-friendly dehydration of fructose to 5-hydroxymethyl-2-furfural in water under high pressure of CO2

TETRAHEDRON LETTERS (2016)

期刊

TETRAHEDRON LETTERS

卷 57, 期 42, 页码 4742-4745

出版社

PERGAMON-ELSEVIER SCIENCE LTD

DOI: 10.1016/j.tetlet.2016.09.036

关键词

Biomass; Dehydration reaction; Carbonic acid; Fructose; CO2

类别

Chemistry, Organic

资金

Ministry of Education, Culture, Sports, Science, and Technology in Japan KAKENHI [25810078]
Japan Society for the Promotion of Science
Grants-in-Aid for Scientific Research [25810078] Funding Source: KAKEN

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Protocol

Reagent

摘要

To develop reaction systems of chemical conversion of biomass, fructose was heated in an aqueous medium under pressurized CO2, which caused in situ generation of carbonic acid. It gave 5-hydroxymethyl-2-furfural (HMF) as a dehydration product in good yields. The maximum yield of HMF was 92% in the reaction at 90 degrees C under 7.0 MPa of CO2 for 168 h. The reaction proceeded in the absence of any other reagents such as non-volatile acids, organic solvents, inorganic, and organic salts. It means green, environmental friendly, and efficient process was achieved for production of HMF. (C) 2016 Elsevier Ltd. All rights reserved.

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