期刊
SYNLETT
卷 27, 期 6, 页码 941-945出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0035-1560548
关键词
asymmetric synthesis; chirality; sulfoxides; indoles; total synthesis
资金
- JSPS KAKENHI [25860014]
- Grants-in-Aid for Scientific Research [25860014] Funding Source: KAKEN
The first example of an enantioselective intermolecular interrupted Pummerer reaction has been developed by the utilization of a C-2-symmetric chiral sulfoxide. The reaction was used for the enantioselective synthesis of C3a-substituted pyrroloindolines in a one-pot procedure starting from tryptamine. The synthetic utility of the reaction was further demonstrated by its application to the highly concise total synthesis of (+)-psychotriasine.
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