期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 10, 期 6, 页码 1295-1298出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201500201
关键词
cluster compounds; core-shell structures; electrocatalytic activity; luminescence; nanoparticles; silver cluster
资金
- NSFC [21201110, 21227001]
- China Postdoctoral Science Foundation [2013T60663]
Atomically precise polyoxometalate-Ag2S core-shell nanoparticles were generated in a top-down approach under solvothermal conditions and structurally confirmed by X-ray single-crystal diffraction as an interesting core-shell structure comprising an in situ generated Mo6O228- polyoxometalate core and a mango-like Ag58S38 shell. This result demonstrates the possibility to integrate polyoxometalate and Ag2S nanoparticles into a core-shell heteronanostructure with precisely controlled atomical compositions of both core and shell.
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