Alkali Metal Carbatrane Compounds [TismPriBenz]M: Synthesis and Structural Characterization of a Complete Series of Monomeric Alkali Metal Alkyl Compounds

Synthesis and Structural Characterization of Thallium and Cadmium Carbatrane Compounds, [TismPriBenz]Tl and [TismPriBenz]CdMe

(2022) Matthew Hammond et al.   POLYHEDRON

Dicarbanion Compounds: The Bridge between Organometallic Reagents and Mononuclear Heterocycles

(2022) Zhengqi Chai et al.   Organometallics

Incorporating Trimethylaluminium into the Structures of Alkali Metal (Li, Na, K, Cs) dihydropyridines

(2022) Shay P. Docherty et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Alkali-Metal-Ion-Centered Sandwich Structures of 4-Bromophenyl[tris(pentafluorophenyl)]borates and Their Synthetic Utility

(2021) Kento Iwai et al.   ORGANOMETALLICS

Hydrosilyation of CO2 using a silatrane hydride: structural characterization of a silyl formate compound

(2021) Serge Ruccolo et al.   Canadian Journal of Chemistry

Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation of Alkenes

(2021) Robert E. Mulvey et al.   ChemCatChem

Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex

(2021) Jingzhen Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Terminal Cadmium Hydride Compound, [κ3-TismPriBenz]CdH

(2021) Matthew Hammond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

THF‐solvated Heavy Alkali Metal Benzyl Compounds (Na, Rb, Cs): Defined Deprotonation Reagents for Alkali Metal Mediation Chemistry

(2021) Lukas Brieger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Benchmarking Cation−π Interactions: Assessment of Density Functional Theory and Möller–Plesset Second-Order Perturbation Theory Calculations with Optimized Basis Sets (mp2mod) for Complexes of Benzene, Phenol, and Catechol with Na+, K+, Rb+, and Cs+

(2020) Alessandro Ferretti et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Synthesis and Structural Characterization of Bis(2-pyridylthio)(p-tolylthio)methyl Zinc Complexes and the Catalytic Hydrosilylation of CO2

(2020) Wesley Sattler et al.   POLYHEDRON

Alkali Metal Mediation: Diversity of Applications in Main Group Organometallic Chemistry

(2020) Robert E. Mulvey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insight into the Bonding and Aggregation of Alkyllithiums by Experimental Charge Density Studies and Energy Decomposition Analyses

(2020) Annika Münch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of [TismPriBenz]MgMe towards Secondary Amines and Terminal Alkynes: Catalytic Dehydrocoupling with Hydrosilanes to Afford Si–N and Si–C Bonds

(2019) Michael Rauch et al.   INORGANICA CHIMICA ACTA

Ligand Effect in Alkali Metal‐Catalyzed Transfer Hydrogenation of Ketones Iryna D. Alshakova, Hayden C. Foy, Travis Dudding, and Georgii I. Nikonov*[a]

(2019) Georgii Nikonov et al.   CHEMISTRY-A EUROPEAN JOURNAL

Titanium(IV) Cations with Trigonal Monopyramidal Geometry: Unusual Lewis Acids Supported by a Triaryl Triamidoamine Ligand

(2019) Priyabrata Ghana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stabilization of Heteroleptic Heavier Alkaline Earth Metal Complexes with an Encapsulating Dipyrromethene Ligand

(2019) Gerd Ballmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Representation of Three-Center–Two-Electron Bonds in Covalent Molecules with Bridging Hydrogen Atoms

(2019) Gerard Parkin   JOURNAL OF CHEMICAL EDUCATION

Selective Conversion of Carbon Dioxide to Formaldehyde via a Bis(silyl)acetal: Incorporation of Isotopically Labeled C1 Moieties Derived from Carbon Dioxide into Organic Molecules

(2019) Michael Rauch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Impact of the Alkali Metal Ion on the Crystal Structure and (Mechano)luminescence of Terbium(III) Tetrakis(β-diketonates)

(2019) Yulia S. Kudyakova et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Insertion of CS2 into the Mg–H bond: synthesis and structural characterization of the magnesium dithioformate complex, [TismPriBenz]Mg(κ2-S2CH)

(2018) Michael Rauch et al.   DALTON TRANSACTIONS

Straightforward synthesis of rubidium bis(trimethylsilyl)amide and complexes of the alkali metal bis(trimethylsilyl)amides with weakly coordinating 2,2,5,5-tetramethyltetrahydrofuran

(2018) Sven Krieck et al.   DALTON TRANSACTIONS

Alkali-Metal Alkyl Complexes with the Tridentate Benzhydryl Ligand [2,2′-(4-MeC6H4NMe2)2CH]−

(2018) Dmitry O. Khristolyubov et al.   ORGANOMETALLICS

Synthesis and Structural Characterization of Tris(isopropylbenzimidazol-2-ylthio)methyl Zinc Complexes, [TitmPriBenz]ZnX: Modulation of Transannular Zn–C Interactions

(2018) Serge Ruccolo et al.   ORGANOMETALLICS

200 Years of Lithium and 100 Years of Organolithium Chemistry

(2018) Ulrich Wietelmann et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Synthesis, Structure, and Reactivity of a Terminal Magnesium Hydride Compound with a Carbatrane Motif, [TismPriBenz]MgH: A Multifunctional Catalyst for Hydrosilylation and Hydroboration

(2017) Michael Rauch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zinc and Magnesium Catalysts for the Hydrosilylation of Carbon Dioxide

(2017) Michael Rauch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach

(2017) H. Li et al.   Chemical Science

Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [TismPriBenz]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field

(2017) Serge Ruccolo et al.   Chemical Science

Structural Studies of Cesium, Lithium/Cesium, and Sodium/Cesium Bis(trimethylsilyl)amide (HMDS) Complexes

(2016) Ana I. Ojeda-Amador et al.   INORGANIC CHEMISTRY

Modulation of Zn–C Bond Lengths Induced by Ligand Architecture in Zinc Carbatrane Compounds

(2016) Serge Ruccolo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Cambridge Structural Database

(2016) Colin R. Groom et al.   Acta Crystallographica Section B-Structural Science Crystal Engineering and Materials

Carbene Complexes Based on Dilithium Methandiides

(2015) Viktoria H. Gessner et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Tris(pyrazolyl)methanides of the Alkaline Earth Metals: Influence of the Substitution Pattern on Stability and Degradation

(2015) Christoph Müller et al.   INORGANIC CHEMISTRY

Hydrosilylation of Aldehydes and Ketones Catalyzed by a Terminal Zinc Hydride Complex, [κ3-Tptm]ZnH

(2015) Wesley Sattler et al.   ORGANOMETALLICS

Crystal structure refinement withSHELXL

(2015) George M. Sheldrick   Acta Crystallographica Section C-Structural Chemistry

Functionalization of P4Using a Lewis Acid Stabilized Bicyclo[1.1.0]tetraphosphabutane Anion

(2014) Jaap E. Borger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Extremely Bulky Tris(pyrazolyl)methanide: A Tridentate Ligand for the Synthesis of Heteroleptic Magnesium(II) and Ytterbium(II) Alkyl, Hydride, and Iodide Complexes

(2014) Ralte Lalrempuia et al.   Chemistry-An Asian Journal

Synthesis and structural characterization of tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium halide complexes, {[TmMeBenz]Cd(μ-Cl)}2and [TmMeBenz]CdI: a rare example of cadmium in a trigonal bipyramidal sulfur-rich coordination environment

(2014) Joshua H. Palmer et al.   DALTON TRANSACTIONS

Ruthenium Hydrides Containing the Superhindered Polydentate Polyphosphine Ligand P(CH2CH2PtBu2)3

(2014) Ryan Gilbert-Wilson et al.   INORGANIC CHEMISTRY

Application of the Covalent Bond Classification Method for the Teaching of Inorganic Chemistry

(2014) Malcolm L. H. Green et al.   JOURNAL OF CHEMICAL EDUCATION

Coinage Metal Complexes of Tris(pyrazolyl)methanide-Based Redox-Active Metalloligands

(2014) Sandra González-Gallardo et al.   ORGANOMETALLICS

Reduction of bicarbonate and carbonate to formate in molecular zinc complexes

(2014) Wesley Sattler et al.   Catalysis Science & Technology

Organometallic intermediate-based organic synthesis: organo-di-lithio reagents and beyond

(2014) Wen-Xiong Zhang et al.   Organic Chemistry Frontiers

Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms

(2013) Hans J. Reich   CHEMICAL REVIEWS

Jaguar: A high-performance quantum chemistry software program with strengths in life and materials sciences

(2013) Art D. Bochevarov et al.   INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY

A Zwitterionic Carbanion Frustrated by Boranes – Dihydrogen Cleavage with Weak Lewis Acids via an “Inverse” Frustrated Lewis Pair Approach

(2013) Hui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Terminal Organozinc Fluoride Compound: Hydrogen Bonding, Halogen Bonding, and Donor–Acceptor Interactions

(2013) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural characterization of tris(pyrazolyl)hydroborato and tris(2-pyridylthio)methyl lithium compounds: Lithium in uncommon trigonal pyramidal and trigonal monopyramidal coordination environments

(2013) Neena Chakrabarti et al.   POLYHEDRON

The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds

(2012) Jennifer C. Green et al.   CHEMICAL COMMUNICATIONS

Cation−π Interaction: Its Role and Relevance in Chemistry, Biology, and Material Science

(2012) A. Subha Mahadevi et al.   CHEMICAL REVIEWS

Adding Rubidium and Cesium to the Homologous Series of Alkali Metal Compounds of (Trimethylsilyl)methanides and 2,2,6,6-Tetramethylpiperidides

(2012) William Clegg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Zinc Catalysts for On-Demand Hydrogen Generation and Carbon Dioxide Functionalization

(2012) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigations on the Steric Accessibility of the Carbanionic Moiety in Zwitterionic Magnesium Tris(pyrazolyl)methanide Complexes. Synthesis and Characterisation of Bi- and Tri­metallic Complexes

(2012) Jens Meyer et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Structural characterization of zinc bicarbonate compounds relevant to the mechanism of action of carbonic anhydrase

(2012) Wesley Sattler et al.   Chemical Science

Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2]

(2011) Daniel Kratzert et al.   CHEMICAL COMMUNICATIONS

Synthesis and Structures of [(Trimethylsilyl)methyl]sodium and -potassium with Bi- and Tridentate N-Donor Ligands

(2011) William Clegg et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

s-Block Organometallics: Analysis of Ion-Association and Noncovalent Interactions on Structure and Function in Benzyl-Based Compounds

(2011) Ana Torvisco et al.   INORGANIC CHEMISTRY

Synthesis, Structure, and Reactivity of a Mononuclear Organozinc Hydride Complex: Facile Insertion of CO2into a Zn–H Bond and CO2-Promoted Displacement of Siloxide Ligands

(2011) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group 1 Bis(iminophosphorano)methanides, Part 2:N-Aryl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2(R = 2,4,6-trimethylphenyl or 2,6-diisopropylphenyl)

(2011) Ashley J. Wooles et al.   ORGANOMETALLICS

Group 1 Bis(iminophosphorano)methanides, Part 1:N-Alkyl and Silyl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2(R = Adamantyl and Trimethylsilyl)

(2011) Ashley J. Wooles et al.   ORGANOMETALLICS

The Structure of the “Third-Generation” Tris(pyrazolyl)borate Caesium Salt p-BrC6H4TpCs

(2011) Johannes Zagermann et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

1,4-Dilithio-1,3-dienes: Reaction and Synthetic Applications

(2010) Zhenfeng Xi   ACCOUNTS OF CHEMICAL RESEARCH

Ionic radii for Group 1 and Group 2 halide, hydride, fluoride, oxide, sulfide, selenide and telluride crystals

(2010) Peter F. Lang et al.   DALTON TRANSACTIONS

Trigonal Bi- and Monopyramidal Cobalt(II) Complexes of a Novel Guanidine-Based Tripodal Ligand

(2010) Cassandra E. Searls et al.   INORGANIC CHEMISTRY

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

(2010) Gregory R. Fulmer et al.   ORGANOMETALLICS

Methandiide Complexes (R2CM2) of the Heavier Alkali Metals (M=Potassium, Rubidium, Cesium): Reaching the Limit?

(2009) Lars Orzechowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organometallic Compounds of the Heavier s-Block Elements-What Next?

(2009) J. David Smith   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Syntheses, Structures and Electronic Properties of Zwitterionic Iron(II) and Cobalt(II) Complexes Featuring Ambidentate Tris(pyrazolyl)methanide Ligands

(2009) Istemi Kuzu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Structure Formation Principles and Reactivity of Organolithium Compounds

(2009) Viktoria H. Gessner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co

(2009) Bennett P. Greenwood et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multidentate ligand systems featuring dual functionality

(2008) Istemi Kuzu et al.   DALTON TRANSACTIONS

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

Molybdenum and Tungsten Structural Differences are Dependent onndz2/(n+ 1)s Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox =tBu3SiO)

(2008) David S. Kuiper et al.   INORGANIC CHEMISTRY

Structure/Reactivity Studies on an α-Lithiated Benzylsilane: Chemical Interpretation of Experimental Charge Density

(2008) Holger Ott et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[(thf)Li2{H2CS(NtBu)2}]2: Synthesis, Polymorphism, and Experimental Charge Density to Elucidate the Bonding Properties of a Lithium Sulfur Ylide

(2008) Stephan Deuerlein et al.   ORGANOMETALLICS