Iridium Acylnitrenoid-Initiated Biomimetic Cascade Cyclizations: Stereodefined Access to Polycyclic δ-Lactams

A Stereospecific Alkene 1,2‐Aminofunctionalization Platform for the Assembly of Complex Nitrogen‐Containing Ring Systems

(2023) Yuxiang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic snapshots of rhodium-catalyzed acylnitrene transfer reactions

(2023) Hoimin Jung et al.   SCIENCE

Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

(2022) Koji Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Synthesis of 4-Amino-5-aryltetrahydro-1H-benzo[c]azepines via Aminoarylation Reaction

(2022) Sk Md Samim Akhtar et al.   SYNLETT

Alcohols as Efficient Intermolecular Initiators for a Highly Stereoselective Polyene Cyclisation Cascade

(2022) Daniya Aynetdinova et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tuning Orbital Symmetry of Iridium Nitrenoid Enables Catalytic Diastereo- and Enantioselective Alkene Difunctionalizations

(2021) Suhyeon Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Aminating Agents in Total Synthesis

(2021) Lauren O'Neil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrene-mediated intermolecular N–N coupling for efficient synthesis of hydrazides

(2021) Hao Wang et al.   Nature Chemistry

Indium(III)-Catalyzed Stereoselective Synthesis of Tricyclic Frameworks by Cascade Cycloisomerization Reactions of Aryl 1,5-Enynes

(2021) Ramón E. Millán et al.   JOURNAL OF ORGANIC CHEMISTRY

Cationic cyclization reactions with alkyne terminating groups: a useful tool in biomimetic synthesis

(2021) Olaya García-Pedrero et al.   CHEMICAL COMMUNICATIONS

Rh2(II)-Catalyzed Intermolecular N-Aryl Aziridination of Olefins Using Nonactivated N Atom Precursors

(2021) Tianning Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric aminoarylation for the synthesis of trans-3-amino-4-aryltetrahydroquinolines: An access to aza-analogue of dihydrexidine

(2021) Sk Md Samim Akhtar et al.   TETRAHEDRON

Cobalt-Catalyzed Hydrogen-Atom Transfer Induces Bicyclizations that Tolerate Electron-Rich and Electron-Deficient Intermediate Alkenes

(2020) Darius Vrubliauskas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

(2020) Aaron Trowbridge et al.   CHEMICAL REVIEWS

Organocatalytic nitrogen transfer to unactivated olefins via transient oxaziridines

(2020) Qing-Qing Cheng et al.   Nature Catalysis

Modular Tuning of Electrophilic Reactivity of Iridium Nitrenoids for the Intermolecular Selective α-Amidation of β-Keto Esters

(2020) Minhan Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Three-Dimensionally Fascinating Diterpenoid Alkaloids and Related Diterpenes

(2020) Xiao-Yu Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic access to carbocation intermediates via nitrenoid transfer leading to allylic lactams

(2020) Seung Youn Hong et al.   Nature Catalysis

Exploiting Natural Complexity: Synthetic Terpenoid‐Alkaloids by Regioselective and Diastereoselective Hydroaminoalkylation Catalysis

(2019) Rebecca C. DiPucchio et al.   ChemCatChem

Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes

(2019) Honghui Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodefined Access to Lactams via Olefin Difunctionalization: Iridium Nitrenoids as a Motif of LUMO-Controlled Dipoles

(2019) Seung Youn Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing Secondary Coordination Sphere Interactions That Enable the Selective Amidation of Benzylic C–H Bonds

(2019) Hoimin Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances Towards Syntheses of Diterpenoid Alkaloids

(2019) Christian Dank et al.   SYNTHESIS-STUTTGART

Hydrazide-Catalyzed Polyene Cyclization: Asymmetric Organocatalytic Synthesis of cis -Decalins

(2019) Samuel J. Plamondon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery and development of azasteroids as anticancer agents

(2019) Nagaraju Birudukota et al.   STEROIDS

NXS, Morpholine, and HFIP: The Ideal Combination for Biomimetic Haliranium-Induced Polyene Cyclizations

(2018) Andreas M. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective, Lewis Base-Catalyzed Sulfenocyclization of Polyenes

(2018) Zhonglin Tao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Ir(III)-Catalyzed Stereoselective Haloamidation of Alkynes Enabled by Ligand Participation

(2018) Seung Youn Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Isomerization of N-Sulfonyl Aziridines to Allyl Amines

(2018) Albert Cabré et al.   ORGANIC LETTERS

Stereospecific Alkene Aziridination Using a Bifunctional Amino-Reagent: An Aza-Prilezhaev Reaction

(2018) Joshua J. Farndon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Parametrization of Non-covalent Interactions for Transition State Interrogation Applied to Asymmetric Catalysis

(2017) Manuel Orlandi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(II)-Catalyzed Ring Expansion of Cyclobutanol-Substituted Aryl Azides To Access Medium-Sized N-Heterocycles

(2017) Wrickban Mazumdar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inverting Steric Effects: Using “Attractive” Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer

(2017) Minxue Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling syntheses of diterpenoid alkaloids and related diterpenes by an oxidative dearomatization/Diels–Alder cycloaddition strategy

(2017) Xiao-Yu Liu et al.   NATURAL PRODUCT REPORTS

Broad scope gold(i)-catalysed polyenyne cyclisations for the formation of up to four carbon–carbon bonds

(2017) Zhouting Rong et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Steroidal 5α-Reductase Inhibitors: A Comparative 3D-QSAR Study Review

(2015) Suresh Thareja   CHEMICAL REVIEWS

Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent

(2015) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Study of Sustainability and Scalability in the Cp*Rh(III)-Catalyzed Direct C–H Amidation with 1,4,2-Dioxazol-5-ones

(2015) Yoonsu Park et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Total synthesis of steroids and heterosteroids from BISTRO

(2015) Malika Ibrahim-Ouali   STEROIDS

Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes

(2015) Elise Bernoud et al.   Catalysis Science & Technology

Ongoing Pursuit of Diterpenoid Alkaloids: A Synthetic View

(2015) Xiao-Yu Liu et al.   Asian Journal of Organic Chemistry

Endothelin-3 Expression in the Subfornical Organ Enhances the Sensitivity of Nax, the Brain Sodium-Level Sensor, to Suppress Salt Intake

(2013) Takeshi Y. Hiyama et al.   Cell Metabolism

Synthesis of steroids with nitrogen-containing substituents in ring D (Review)

(2013) S. V. Stulov et al.   Chemistry of Heterocyclic Compounds

Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes

(2013) Nikki A. Cochrane et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh2(II)-Catalyzed Selective Aminomethylene Migration from Styryl Azides

(2013) Chen Kong et al.   ORGANIC LETTERS

Rhodium(II)-Catalyzed Alkyne Amination of Homopropargylic Sulfamate Esters: Stereoselective Synthesis of Functionalized Norcaradienes by Arene Cyclopropanation

(2013) Ryan A. Brawn et al.   ORGANIC LETTERS

Pattern Hair Loss in Men

(2012) Nusrat Banka et al.   DERMATOLOGIC CLINICS

A Stereoselective Hydroamination Transform To Access Polysubstituted Indolizidines

(2012) Sergey V. Pronin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Enantioselective Polyene Cyclization

(2012) Michael A. Schafroth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic alkene cyclization reactions for the stereoselective synthesis of complex “terpenoid-like” heterocycles

(2012) Jared T. Moore et al.   Chemical Science

Terpenoid-Alkaloids: Their Biosynthetic Twist of Fate and Total Synthesis

(2011) Emily C. Cherney et al.   ISRAEL JOURNAL OF CHEMISTRY

Intramolecular Hydroamination of Aminoalkenes Catalyzed by a Cationic Zirconium Complex

(2011) Xinke Wang et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Enantioselective Polycyclization Reactions

(2010) Steven G. Sethofer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Reagents for Direct Halonium-Induced Polyene Cyclizations

(2010) Scott A. Snyder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Thiourea-Catalyzed Cationic Polycyclizations

(2010) Robert R. Knowles et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Polyene Cyclization via Organo-SOMO Catalysis

(2010) Sebastian Rendler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Compelling Computational Evidence for the Concerted Cyclization of the ABC Rings of Hopene from Protonated Squalene

(2010) Lidia Smentek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stereocontrolled Synthesis of (±)-Xenovenine via a Scandium(III)-Catalyzed Internal Aminodiene Bicyclization Terminated by a 2-(5-Ethyl-2-thienyl)ethenyl Group

(2010) Tao Jiang et al.   ORGANIC LETTERS

Carbenium ion trapping using sulfonamides: an acid-catalysed synthesis of pyrrolidines by intramolecular hydroamination

(2010) Charlotte M. Griffiths-Jones (née Haskins) et al.   TETRAHEDRON

A two-step mimic for direct, asymmetric bromonium- and chloronium-induced polyene cyclizations

(2010) Scott A. Snyder et al.   TETRAHEDRON

Bio-inspired polyene cyclization: aziridinyl polyene cyclization catalyzed by InBr3

(2009) Yu-Jun Zhao et al.   CHEMICAL COMMUNICATIONS

Acid-Catalyzed Cyclization of Terpenes Under Homogeneous and Heterogeneous Conditions as Probed Through Stereoisotopic Studies: A Concerted Process with Competing Preorganized Chair and Boat Transition States

(2009) Christos Raptis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS

Substituent Effects in the Benzene Dimer are Due to Direct Interactions of the Substituents with the Unsubstituted Benzene

(2008) Steven E. Wheeler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in azasteroids chemistry

(2008) Malika Ibrahim-Ouali et al.   STEROIDS