Small molecules (CO2, iPrNCO, and iPrNCNiPr) activation by the metallomimetics (μ‐Hydrido) diborane anion: A DFT investigation on mechanism and chemoselectivity controlling

B–B vs. B–H Bond Activation in a (μ‐Hydrido)diborane(4) Anion upon Cycloaddition with CO 2 , Isocyanates, or Carbodiimides

(2021) Timo Trageser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future

(2020) Michele Soleilhavoup et al.   Chem

Towards the catalytic activation of inert small molecules by main-group ambiphiles

(2020) Rian D. Dewhurst et al.   Communications Chemistry

Implementation of Cooperative Designs in Polarized Transition Metal Systems—Significance for Bond Activation and Catalysis

(2020) Basujit Chatterjee et al.   ACS Catalysis

Metallomimetic Chemistry of Boron

(2019) Marc-André Légaré et al.   CHEMICAL REVIEWS

CO2 Binding and Splitting by Boron-Boron Multiple Bonds

(2018) Andreas Stoy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHCs in Main Group Chemistry

(2018) Vitaly Nesterov et al.   CHEMICAL REVIEWS

A redox-active diborane platform performs C(sp3)–H activation and nucleophilic substitution reactions

(2018) Thomas Kaese et al.   Chemical Science

Main-Group Metallomimetics: Transition Metal-like Photolytic CO Substitution at Boron

(2017) Holger Braunschweig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Examining the relationship between coordination mode and reactivity of dinitrogen

(2017) Richard J. Burford et al.   Nature Reviews Chemistry

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Compounds with Low-Valent p-Block Elements for Small Molecule Activation and Catalysis

(2015) Sandeep Yadav et al.   ChemCatChem

Intermolecular N–H Oxidative Addition of Ammonia, Alkylamines, and Arylamines to a Planar σ3-Phosphorus Compound via an Entropy-Controlled Electrophilic Mechanism

(2014) Sean M. McCarthy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

(2014) Douglas W. Stephan et al.   Chemical Science

Natural bond orbital analysis: A critical overview of relationships to alternative bonding perspectives

(2012) Frank Weinhold   JOURNAL OF COMPUTATIONAL CHEMISTRY

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Transition-metal-catalyzed C–C bond formation through the fixation of carbon dioxide

(2011) Kun Huang et al.   CHEMICAL SOCIETY REVIEWS

A thorough benchmark of density functional methods for general main group thermochemistry, kinetics, and noncovalent interactions

(2011) Lars Goerigk et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

(2009) Y. Peng et al.   SCIENCE