期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 37, 期 7, 页码 630-636出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.201500679
关键词
block copolymers; cobaltocenium; electrochemistry; ferrocenes; ring-opening metathesis polymerization
Diblock metallopolymer polyelectrolytes containing the two redox-robust cationic sandwich units [CoCp'Cp](+) and [FeCp'(eta(6)-C6Me6)](+) (Cp = eta(5)-C5H5; Cp' = eta(5)-C5H4-) as hexafluorophosphate ([PF6](-)) salts are synthesized by ring-opening metathesis polymerization using Grubbs' third generation catalyst. Their electrochemical properties show full chemical and electrochemical reversibilities allowing fine determination of the copolymer molecular weight using Bard-Anson's electrochemical method by cyclic voltammetry.
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