Accessing chiral sulfones bearing quaternary carbon stereocenters via photoinduced radical sulfur dioxide insertion and Truce–Smiles rearrangement

Catalytic Asymmetric Construction of Axially and Centrally Chiral Heterobiaryls by Minisci Reaction

(2022) Dong Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric, visible light-mediated radical sulfinyl-Smiles rearrangement to access all-carbon quaternary stereocentres

(2021) Cédric Hervieu et al.   Nature Chemistry

Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization

(2021) Shi Cao et al.   Nature Communications

Sodium Dithionite‐Mediated Decarboxylative Sulfonylation: Facile Access to Tertiary Sulfones

(2020) Yaping Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes

(2020) Xi-Tao Li et al.   Chem

Highly Efficient Enantioselective Synthesis of Chiral Sulfones by Rh-Catalyzed Asymmetric Hydrogenation

(2019) Qiaozhi Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts

(2019) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes

(2019) Niankai Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of 1,4-Dicarbonyl Compounds from Aldehydes by Hydrogen Atom Transfer Photocatalysis and Chiral Lewis Acid Catalysis

(2019) Yulong Kuang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multicomponent Reductive Cross-Coupling of an Inorganic Sulfur Dioxide Surrogate: Straightforward Construction of Diversely Functionalized Sulfones

(2019) Yingying Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light mediated aryl migration by homolytic C-N cleavage of aryl amines

(2018) Dirk Alpers et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote C−H functionalization using radical translocating arylating groups

(2018) Florian W. Friese et al.   Nature Communications

Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

(2018) Guanyinsheng Qiu et al.   Organic Chemistry Frontiers

Direct Photocatalytic Synthesis of Medium-Sized Lactams through C-C Bond Cleavage

(2018) Na Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Highly Enantioselective Hydrogenation of β-Acetylamino Vinylsulfones: Access to Chiral β-Amido Sulfones

(2018) Jiao Long et al.   ORGANIC LETTERS

Efficient Docking-Migration Strategy for Selective Radical Difluoromethylation of Alkenes

(2018) Jiajia Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Arylsulfonylation and Cyclizative Carbonation of N-(Arylsulfonyl)acrylamides Involving Desulfonative Arrangement toward Sulfonated Oxindoles

(2017) Hepan Wang et al.   ORGANIC LETTERS

Combining the catalytic enantioselective reaction of visible-light-generated radicals with a by-product utilization system

(2017) Xiaoqiang Huang et al.   Chemical Science

A remote C–C bond cleavage–enabled skeletal reorganization: Access to medium-/large-sized cyclic alkenes

(2017) Lei Li et al.   Science Advances

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3-Sulfonated Coumarins

(2016) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical aryl migration enables diversity-oriented synthesis of structurally diverse medium/macro- or bridged-rings

(2016) Lei Li et al.   Nature Communications

A Visible-Light-Mediated Radical Smiles Rearrangement and its Application to the Synthesis of a Difluoro-Substituted Spirocyclic ORL-1 Antagonist

(2015) James J. Douglas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fixation of sulfur dioxide into small molecules

(2015) Gang Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry

(2015) Edward J. Emmett et al.   Asian Journal of Organic Chemistry

Arylphosphonylation and Arylazidation of Activated Alkenes

(2014) Wangqing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2and Hydrazines

(2014) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Enantioselective Approach to the Preparation of Chiral Sulfones by Ir-Catalyzed Asymmetric Hydrogenation

(2014) Byron K. Peters et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed One-Pot Trifluoromethylation/Aryl Migration/Desulfonylation and C(sp2)–N Bond Formation of Conjugated Tosyl Amides

(2013) Wangqing Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First domino radical cyclisation/Smiles rearrangement combination

(2012) Marc Pudlo et al.   CHEMICAL COMMUNICATIONS

Cyclic Sulfones as Novel P3-Caps for Hepatitis C Virus NS3/4A (HCV NS3/4A) Protease Inhibitors: Synthesis and Evaluation of Inhibitors with Improved Potency and Pharmacokinetic Profiles

(2010) Francisco Velázquez et al.   JOURNAL OF MEDICINAL CHEMISTRY

A truce on the Smiles rearrangement: revisiting an old reaction—the Truce–Smiles rearrangement

(2008) Timothy J. Snape   CHEMICAL SOCIETY REVIEWS