Synthesis of 1,2-Diamines from Vinyl Sulfonium Salts and Arylamines

Alkynyl Sulfonium Salts Can Be Employed as Chalcogen‐Bonding Catalysts and Generate Alkynyl Radicals under Blue‐Light Irradiation

(2022) Yu Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diverse C–P Cross-Couplings of Arylsulfonium Salts with Diarylphosphines via Selective C–S Bond Cleavage

(2021) Yun Ye et al.   ORGANIC LETTERS

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3•, and CF3– Reactivity

(2021) Hao Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Diamination of Unactivated Alkenes With Electron-Rich Amino Sources

(2021) Yang Li et al.   ORGANIC LETTERS

Cobalt-Catalyzed Divergent Aminofluorination and Diamination of Styrenes with N-Fluorosulfonamides

(2021) Peng Guo et al.   ORGANIC LETTERS

Enabling the Use of Alkyl Thianthrenium Salts in Cross‐Coupling Reactions by Copper Catalysis

(2021) Cheng Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C–H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence

(2021) Beatrice Lansbergen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vinyl Thianthrenium Tetrafluoroborate: A Practical and Versatile Vinylating Reagent Made from Ethylene

(2021) Fabio Juliá et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aziridine synthesis by coupling amines and alkenes via an electrogenerated dication

(2021) Dylan E. Holst et al.   NATURE

Palladium-Catalyzed Fluoroalkylation via C(sp3)–S Bond Cleavage of Vinylsulfonium Salts

(2021) Yuan He et al.   ORGANIC LETTERS

Transition-Metal-Free, Formal C–H Germylation of Arenes and Styrenes via Dibenzothiophenium Salts

(2021) Aymane Selmani et al.   ORGANIC LETTERS

Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation

(2021) Cheng Chen et al.   Nature Communications

Electrochemical Synthesis of Allylic Amines from Terminal Alkenes and Secondary Amines

(2021) Diana J. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tritiation of aryl thianthrenium salts with a molecular palladium catalyst

(2021) Da Zhao et al.   NATURE

Alkylation Reactions with Alkylsulfonium Salts

(2021) Cheng-Pan Zhang et al.   SYNTHESIS-STUTTGART

Metal-free allylic C–H nitrogenation, oxygenation, and carbonation of alkenes by thianthrenation

(2021) Ming-Shang Liu et al.   Chemical Science

Photoinduced Olefin Diamination with Alkylamines

(2020) Sebastian Govaerts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vinyl Sulfonium Salts as the Radical Acceptor for Metal-Free Decarboxylative Alkenylation

(2020) Yu-Lan Zhang et al.   ORGANIC LETTERS

Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalization Reaction

(2020) Szabolcs Makai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts

(2019) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl Sulfonium Salts for Site-Selective Late-Stage Trifluoromethylation

(2019) Fei Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C−H Oxygenation via Aryl Sulfonium Salts

(2019) Ruocheng Sang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral Borylation of Aryl Sulfonium Salts via C–S Activation Enabled by Light

(2019) Chen Huang et al.   ORGANIC LETTERS

Practical and stereoselective electrocatalytic 1,2-diamination of alkenes

(2019) Chen-Yan Cai et al.   Nature Communications

An Interrupted Pummerer/Nickel-Catalysed Cross-Coupling Sequence

(2018) Miles H. Aukland et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Chemo- and Regioselective Vinylation of N-Heteroarenes with Vinylsulfonium Salts

(2018) Mingwei Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Diamination of Styrenes

(2017) Kilian Muñiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic copper-TEMPO catalysis of intermolecular vicinal diamination of styrenes

(2017) Shiue-Shien Weng et al.   TETRAHEDRON LETTERS

Palladium-Assisted “Aromatic Metamorphosis” of Dibenzothiophenes into Triphenylenes

(2015) Dhananjayan Vasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins

(2015) Yong-An Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Inter-/Intermolecular Alkene Diamination of Hydroxy Styrenes with Electron-Rich Amines

(2015) Michael W. Danneman et al.   ORGANIC LETTERS

Catalytic Diamination of Olefins via N–N Bond Activation

(2014) Yingguang Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Vicinal Diamination of Alkenes under Rh-Catalysis

(2014) David E. Olson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Aminoazidation of Alkenes

(2014) Bo Zhang et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Aminocyanation and Diamination of Alkenes

(2013) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methods for direct alkene diamination, new & old

(2012) Sam De Jong et al.   TETRAHEDRON

Enantioselective Metal-Free Diamination of Styrenes

(2011) Caren Röben et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Intermolecular Palladium-Catalyzed Diamination of Unactivated Alkenes

(2010) Álvaro Iglesias et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient and general synthesis of oxazino[4,3-a]indoles by cascade addition-cyclization reactions of (1H-indol-2-yl)methanols and vinyl sulfonium salts

(2010) Jing An et al.   CHEMICAL COMMUNICATIONS

Diamine ligands in copper-catalyzed reactions

(2010) David S. Surry et al.   Chemical Science

Metal-catalysed 1,2-diamination reactions

(2009) Francesca Cardona et al.   Nature Chemistry