Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen

3d Metal Complexes in T-shaped Geometry as a Gateway to Metalloradical Reactivity

(2022) Jonas C. Ott et al.   ACCOUNTS OF CHEMICAL RESEARCH

Visible-Light-Enhanced Cobalt-Catalyzed Hydrogenation: Switchable Catalysis Enabled by Divergence between Thermal and Photochemical Pathways

(2021) Lauren N. Mendelsohn et al.   ACS Catalysis

High‐Spin Imido Cobalt Complexes with Imidyl Radical Character

(2021) Alexander Reckziegel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photo‐Initiated Cobalt‐Catalyzed Radical Olefin Hydrogenation

(2021) Sier Sang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Role of Coordination Geometry on the Magnetic Relaxation Dynamics of Isomeric Five-Coordinate Low-Spin Co(II) Complexes

(2021) Lena Spillecke et al.   INORGANIC CHEMISTRY

Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere

(2021) Kate A. Jesse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Active Superbulky Alkaline Earth Metal Amide Catalysts for Hydrogenation of Challenging Alkenes and Aromatic Rings

(2020) Sjoerd Harder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Boron Activating Effect Enables Cobalt-Catalyzed Asymmetric Hydrogenation of Sterically Hindered Alkenes

(2020) Peter Viereck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence

(2020) Andrew J. McNeece et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Square Planar Cobalt(II) Hydride versus T-Shaped Cobalt(I): Structural Characterization and Dihydrogen Activation with PNP–Cobalt Pincer Complexes

(2019) Lukas S. Merz et al.   INORGANIC CHEMISTRY

Radical Rebound Hydroxylation Versus H-Atom Transfer in Non-Heme Iron(III)-Hydroxo Complexes: Reactivity and Structural Differentiation

(2019) Michael J. Drummond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications

(2019) Rebeca Arevalo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygen Reduction by Homogeneous Molecular Catalysts and Electrocatalysts

(2018) Michael L. Pegis et al.   CHEMICAL REVIEWS

Ligand-Based Storage of Protons and Electrons in Dihydrazonopyrrole Complexes of Nickel

(2018) Mu-Chieh Chang et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Azoaromatic Ligand as Four Electron Four Proton Reservoir: Catalytic Dehydrogenation of Alcohols by Its Zinc(II) Complex

(2018) Rajib Pramanick et al.   INORGANIC CHEMISTRY

Hydrogen-Atom Noninnocence of a Tridentate [SNS] Pincer Ligand

(2018) Kyle E. Rosenkoetter et al.   INORGANIC CHEMISTRY

Mechanistic insight into cobalt-catalyzed stereodivergent semihydrogenation of alkynes: The story of selectivity control

(2018) Xiaotian Qi et al.   JOURNAL OF CATALYSIS

Cobalt-Catalyzed Regioselective Olefin Isomerization Under Kinetic Control

(2018) Xufang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Superoxide dismutase activity enabled by a redox-active ligand rather than metal

(2018) Meghan B. Ward et al.   Nature Chemistry

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

(2018) Lukas Alig et al.   CHEMICAL REVIEWS

Hydride Transfer Reactions Catalyzed by Cobalt Complexes

(2018) Wenying Ai et al.   CHEMICAL REVIEWS

Electrochemical Reduction of N2 to NH3 at Low Potential by a Molecular Aluminum Complex

(2018) Tobias J. Sherbow et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Assisted Metal-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Ni(II) Complex

(2018) Rahul Jain et al.   INORGANIC CHEMISTRY

Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups

(2018) Khashayar Rajabimoghadam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of Low-Spin Cobalt(II) Imido Complexes [(Me3P)3Co(NAr)]

(2017) Yang Liu et al.   INORGANIC CHEMISTRY

Control of Ligand pKa Values Tunes the Electrocatalytic Dihydrogen Evolution Mechanism in a Redox-Active Aluminum(III) Complex

(2017) Tobias J. Sherbow et al.   INORGANIC CHEMISTRY

Redox-Active Bis(phenolate) N-Heterocyclic Carbene [OCO] Pincer Ligands Support Cobalt Electron Transfer Series Spanning Four Oxidation States

(2017) Caleb F. Harris et al.   INORGANIC CHEMISTRY

Ammonia Activation, H2 Evolution and Nitride Formation from a Molybdenum Complex with a Chemically and Redox Noninnocent Ligand

(2017) Grant W. Margulieux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia Synthesis from a Pincer Ruthenium Nitride via Metal–Ligand Cooperative Proton-Coupled Electron Transfer

(2017) Brian M. Lindley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

(2017) Alexander Dauth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Sequential Hydroboration/Hydrogenation of Internal Alkynes

(2017) Jun Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis

(2017) Huiling Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemical Non-Innocence of an Aliphatic PNP Pincer Ligand

(2016) Felix Schneck et al.   CHEMISTRY-A EUROPEAN JOURNAL

Square-Planar Cobalt(III) Pincer Complex

(2016) Paraskevi O. Lagaditis et al.   INORGANIC CHEMISTRY

Cobalt-Catalyzed Enantioselective Hydrogenation of Minimally Functionalized Alkenes: Isotopic Labeling Provides Insight into the Origin of Stereoselectivity and Alkene Insertion Preferences

(2016) Max R. Friedfeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Cobalt-Catalyzed Transfer Hydrogenation of Alkynes: Stereodivergent Synthesis of Z- and E-Alkenes

(2016) Shaomin Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Homogeneous Hydrogenation of Alkenes under Mild Conditions by a Stepwise, Bifunctional Mechanism

(2016) Ruibo Xu et al.   ACS Catalysis

Molecular Designs for Controlling the Local Environments around Metal Ions

(2015) Sarah A. Cook et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iron- and Cobalt-Catalyzed Alkene Hydrogenation: Catalysis with Both Redox-Active and Strong Field Ligands

(2015) Paul J. Chirik   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

(2015) Thomas Zell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Electrocatalytic Hydrogen Production by an Aluminum(III) Complex: Ligand-Based Proton and Electron Transfer

(2015) Emily J. Thompson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lessons from Nature: A Bio-Inspired Approach to Molecular Design

(2015) Sarah A. Cook et al.   BIOCHEMISTRY

Combination of Redox-Active Ligand and Lewis Acid for Dioxygen Reduction with π-Bound Molybdenum−Quinonoid Complexes

(2015) Justin T. Henthorn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions

(2015) Monalisa Goswami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Mechanistic Study of the Hydrogenation and Dehydrogenation Reactions Catalyzed by Cobalt Pincer Complexes

(2015) Yuanyuan Jing et al.   ORGANOMETALLICS

Coordination polymers and molecular structures among complexes of mercury(II) halides with selected 1-benzoylthioureas

(2015) Andrzej Okuniewski et al.   POLYHEDRON

Four-Coordinate Cobalt Pincer Complexes: Electronic Structure Studies and Ligand Modification by Homolytic and Heterolytic Pathways

(2014) Scott P. Semproni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

(2014) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

(2014) T. W. Myers et al.   Chemical Science

Cobalt-catalyzed transfer hydrogenation of CO and CN bonds

(2013) Guoqi Zhang et al.   CHEMICAL COMMUNICATIONS

Aluminum–Ligand Cooperative N–H Bond Activation and an Example of Dehydrogenative Coupling

(2013) Thomas W. Myers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes

(2013) Renyuan Pony Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Mechanisms of Cobalt-Catalyzed Hydrogenation and Dehydrogenation Reactions

(2013) Guoqi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures

(2013) Rafael E. Rodríguez-Lugo et al.   Nature Chemistry

Cobalt–Bis(imino)pyridine-Catalyzed Asymmetric Hydrogenation: Electronic Structure, Mechanism, and Stereoselectivity

(2013) Kathrin H. Hopmann   ORGANOMETALLICS

Azo NN Bond Cleavage with a Redox-Active Vanadium Compound Involving Metal-Ligand Cooperativity

(2012) Carsten Milsmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Homogeneous Cobalt-Catalyzed Hydrogenation of CC, CO, and CN Bonds

(2012) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

Enantiopure C1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation

(2012) Sebastien Monfette et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–H Activation by Rh(I) via Metal–Ligand Cooperation

(2012) Moran Feller et al.   ORGANOMETALLICS

Enhanced Reactivities toward Amines by Introducing an Imine Arm to the Pincer Ligand: Direct Coupling of Two Amines To Form an Imine Without Oxidant

(2012) Li-Peng He et al.   ORGANOMETALLICS

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Synthesis and Electronic Structure Determination ofN-Alkyl-Substituted Bis(imino)pyridine Iron Imides Exhibiting Spin Crossover Behavior

(2011) Amanda C. Bowman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Step beyond the Feltham–Enemark Notation: Spectroscopic and Correlatedab InitioComputational Support for an Antiferromagnetically Coupled M(II)–(NO)−Description of Tp*M(NO) (M = Co, Ni)

(2011) Neil C. Tomson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Square-Planar Cobalt Complexes with Monodentate N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Catalytic Application

(2011) Zhenbo Mo et al.   ORGANOMETALLICS

ReducedN-Alkyl Substituted Bis(imino)pyridine Cobalt Complexes: Molecular and Electronic Structures for Compounds Varying by Three Oxidation States

(2010) Amanda C. Bowman et al.   INORGANIC CHEMISTRY

XAS and DFT Investigation of Mononuclear Cobalt(III) Peroxo Complexes: Electronic Control of the Geometric Structure in CoO2versus NiO2Systems

(2010) Ritimukta Sarangi et al.   INORGANIC CHEMISTRY

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation

(2010) Eugene Khaskin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Molecular and Electronic Structures of Reduced Bis(imino)pyridine Cobalt Dinitrogen Complexes: Ligand versus Metal Reduction

(2010) Amanda C. Bowman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Molecular Electrocatalysts for CO2Reduction and H2Production/Oxidation

(2009) M. Rakowski Dubois et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane

(2009) Martina Käß et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of New Hybrid Hydroquinone/Cobalt Schiff Base Catalysts: Efficient Electron-Transfer Mediators in Aerobic Oxidation

(2008) Byron W. Purse et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism

(2008) Andrey I. Poddel'sky et al.   COORDINATION CHEMISTRY REVIEWS