期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 1, 页码 33-37出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604407
关键词
C-H activation; hydrogen atom transfer; nickel; non-innocent ligands; pincer ligands
资金
- ERC [646747]
- NWO (NWO-VIDI)
- Dutch-Belgian Beamline at the European Synchrotron Radiation Facility [26-01-1080]
- European Research Council (ERC) [646747] Funding Source: European Research Council (ERC)
The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHPtBu2)(2)}] is reported. This compound exhibits reversible, ligand-centered oxidation and protonation reactions. The resulting pincer chemical non-innocence can be utilized for benzylic C-H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined.
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