Rational Design of First-Row Transition Metal Complexes as the Catalysts for Oxidation of Arenes: A Homogeneous Approach

Different Geometric Requirements for Cytochrome P450-Catalyzed Aliphatic Versus Aromatic Hydroxylation Results in Chemoselective Oxidation

(2022) Tom Coleman et al.   ACS Catalysis

C–H Bond Activation by a Mononuclear Nickel(IV)-Nitrate Complex

(2022) Yubin M. Kwon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes

(2021) Eduard Masferrer‐Rius et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic oxidation of a model volatile organic compound (toluene) with tetranuclear Cu(II) complexes

(2021) Manas Sutradhar et al.   INORGANICA CHIMICA ACTA

Inspiration from Nature: Influence of Engineered Ligand Scaffolds and Auxiliary Factors on the Reactivity of Biomimetic Oxidants

(2021) Gourab Mukherjee et al.   ACS Catalysis

Benzene Hydroxylation by Bioinspired Copper(II) Complexes: Coordination Geometry versus Reactivity

(2020) Sethuraman Muthuramalingam et al.   INORGANIC CHEMISTRY

Recent progress in catalytic oxygenation of aromatic C–H groups with the environmentally benign oxidants H 2 O 2 and O 2

(2020) Roman V. Ottenbacher et al.   APPLIED ORGANOMETALLIC CHEMISTRY

On the Ability of Nickel Complexes Derived from Tripodal Aminopyridine Ligands to Catalyze Arene Hydroxylations

(2020) Eduard Masferrer-Rius et al.   CHIMIA

Crystal Structure and C–H Bond-Cleaving Reactivity of a Mononuclear CoIV–Dinitrate Complex

(2020) Yubin M. Kwon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Ethyl Phenol over Modified HZSM-5 Catalyst in a Fixed Bed Reactor

(2019) Renuka Saharan et al.   International Journal of Chemical Reactor Engineering

Synthesis, characterization and catalytic properties of dinuclear complexes of copper(II) and nickel(II): Oxidation of cyclohexane, toluene and cyclopentane

(2019) Aradhita Bhattacharjee et al.   INORGANICA CHIMICA ACTA

Structure Effects of Metal Corroles on Energy-Related Small Molecule Activation Reactions

(2019) Haitao Lei et al.   ACS Catalysis

Efficient oxidation of benzene catalyzed by Cu(II) tetrazolato complexes under mild conditions

(2019) Jyoti Kumari et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Flavonol biosynthesis by nonheme iron dioxygenases: A computational study into the structure and mechanism

(2019) Neelam Zeb et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Acid pKa Dependence in O–O Bond Heterolysis of a Nonheme FeIII–OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

(2019) Shuangning Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A High-Valent Manganese(IV)-Oxo-Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity

(2019) Deepika G. Karmalkar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroxylation of Aromatics by H 2 O 2 Catalyzed by Mononuclear Non‐heme Iron Complexes: Role of Triazole Hemilability in Substrate‐Induced Bifurcation of the H 2 O 2 Activation Mechanism

(2019) Jean‐Noël Rebilly et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkane and alkene oxidation reactions catalyzed by nickel(II) complexes: Effect of ligand factors

(2019) Muniyandi Sankaralingam et al.   COORDINATION CHEMISTRY REVIEWS

Selective Hydrogen Atom Abstraction from Dihydroflavonol by a Nonheme Iron Center Is the Key Step in the Enzymatic Flavonol Synthesis and Avoids Byproducts

(2019) Sidra Ghafoor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Aromatic C−H Oxidation with H2 O2 in the Presence of Iron Complexes of the PDP Family

(2018) Nikolay V. Tkachenko et al.   ChemCatChem

A mononuclear manganese(iii)–hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

(2018) Muniyandi Sankaralingam et al.   CHEMICAL COMMUNICATIONS

Amphoteric reactivity of metal–oxygen complexes in oxidation reactions

(2018) Muniyandi Sankaralingam et al.   COORDINATION CHEMISTRY REVIEWS

Effect of different carboxylic acids on the aromatic hydroxylation with H 2 O 2 in the presence of an iron aminopyridine complex

(2018) Nikolay V. Tkachenko et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Sc3+ (or HClO4) Activation of a Nonheme FeIII–OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

(2018) Subhasree Kal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Long-Lived Photoexcited State of a Mn(IV)-Oxo Complex Binding Scandium Ions That is Capable of Hydroxylating Benzene

(2018) Namita Sharma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Evaluation of the Reactivity of Nonheme Iron(V)–Oxo Intermediates toward Arenes

(2018) Oleg Y. Lyakin et al.   ACS Catalysis

Oxidative functionalization of aliphatic and aromatic amino acid derivatives with H2O2 catalyzed by a nonheme imine based iron complex

(2018) Barbara Ticconi et al.   RSC Advances

One-Step Synthesis of Cu–ZnO@C from a 1D Complex [Cu0.02Zn0.98(C8H3NO6)(C12H8N2)]n for Catalytic Hydroxylation of Benzene to Phenol

(2018) Guanghui Wang et al.   Crystals

Cobalt pincer complexes in catalysis

(2018) Veronica Papa et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Manganese(V)-Oxo TAML Cation Radical Complex: Synthesis, Characterization, and Reactivity Studies

(2018) Deepika G. Karmalkar et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Mononuclear Non-heme Manganese(III)–Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

(2018) Muniyandi Sankaralingam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

(2018) Arup Mukherjee et al.   ACS Catalysis

Homogeneous Catalysis by Manganese-Based Pincer Complexes

(2017) Marcel Garbe et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Oxidation of aromatic compounds by hydrogen peroxide catalyzed by mononuclear iron(III) complexes

(2017) Giselle C. Silva et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies

(2017) Laia Vilella et al.   Chemical Science

Photocatalytic oxidation of benzene to phenol using dioxygen as an oxygen source and water as an electron source in the presence of a cobalt catalyst

(2017) Ji Won Han et al.   Chemical Science

Direct hydroxylation of benzene and aromatics with H2O2 catalyzed by a self-assembled iron complex: evidence for a metal-based mechanism

(2017) Giorgio Capocasa et al.   Catalysis Science & Technology

Direct synthesis of phenol by novel [FeFe]-hydrogenase model complexes as catalysts of benzene hydroxylation with H2O2

(2017) Xia Zhang et al.   RSC Advances

A CuII -based Metal-Organic Framework as an Efficient Photocatalyst for Direct Hydroxylation of Benzene to Phenol in Aqueous Solution

(2017) Li Zhang et al.   Asian Journal of Organic Chemistry

Microwave-assisted peroxidative oxidation of toluene and 1-phenylethanol with monomeric keto and polymeric enol aroylhydrazone Cu(II) complexes

(2017) Manas Sutradhar et al.   Molecular Catalysis

Non-Heme Imine-Based Iron Complexes as Catalysts for Oxidative Processes

(2016) Giorgio Olivo et al.   ADVANCED SYNTHESIS & CATALYSIS

Improved oxidation of aromatic and aliphatic hydrocarbons using rate enhancing variants of P450Bm3 in combination with decoy molecules

(2016) Samuel D. Munday et al.   CHEMICAL COMMUNICATIONS

Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems

(2016) Wei Zhang et al.   CHEMICAL REVIEWS

Catalytic Hydroxylation of Benzene to Phenol by Dioxygen with an NADH Analogue

(2016) Kensaku Hirose et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Advances of Manganese Catalysis for Organic Synthesis

(2016) Jonathan R. Carney et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

VOPO4·2H2O encapsulated in graphene oxide as a heterogeneous catalyst for selective hydroxylation of benzene to phenol

(2016) Parijat Borah et al.   GREEN CHEMISTRY

A dinuclear iron(II) complex bearing multidentate pyridinyl ligand: Synthesis, characterization and its catalysis on the hydroxylation of aromatic compounds

(2016) Erxing Gu et al.   INORGANICA CHIMICA ACTA

Participation of Electron Transfer Process in Rate-Limiting Step of Aromatic Hydroxylation Reactions by Compound I Models of Heme Enzymes

(2016) Maaya Asaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Manganese(V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion

(2016) Seungwoo Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning the Reactivity of Terminal Nickel(III)–Oxygen Adducts for C–H Bond Activation

(2016) Paolo Pirovano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohol oxidation with H2O2 catalyzed by a cheap and promptly available imine based iron complex

(2016) Giorgio Olivo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

One-step selective hydroxylation of benzene to phenol with hydrogen peroxide catalysed by copper complexes incorporated into mesoporous silica–alumina

(2016) Mihoko Yamada et al.   Chemical Science

Selective direct hydroxylation of benzene to phenol with hydrogen peroxide by iron and vanadyl based homogeneous and heterogeneous catalysts

(2016) Liliana Carneiro et al.   Catalysis Science & Technology

Selective hydroxylation of benzene derivatives and alkanes with hydrogen peroxide catalysed by a manganese complex incorporated into mesoporous silica–alumina

(2015) Yusuke Aratani et al.   CHEMICAL COMMUNICATIONS

Expanding the toolbox of organic chemists: directed evolution of P450 monooxygenases as catalysts in regio- and stereoselective oxidative hydroxylation

(2015) Gheorghe-Doru Roiban et al.   CHEMICAL COMMUNICATIONS

Synthesis and characterization of copper(ii) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol

(2015) Li Wu et al.   DALTON TRANSACTIONS

Aromatic hydroxylation using an oxo-bridged diiron(iii) complex: a bio-inspired functional model of toluene monooxygenases

(2015) Ambica Kejriwal et al.   DALTON TRANSACTIONS

Synthesis and Characterization of Bio-Inspired Diiron Complexes and Their Catalytic Activity for Direct Hydroxylation of Aromatic Compounds

(2015) Xiao Wang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Recent Advances in First-Row-Transition-Metal-Catalyzed Dehydrogenative Cou­pling of C(sp3)-H Bonds

(2015) Jinmin Miao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

C–H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight

(2015) Giorgio Olivo et al.   INORGANIC CHEMISTRY

Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands

(2015) Yuma Morimoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fe-Based Metal–Organic Frameworks for Highly Selective Photocatalytic Benzene Hydroxylation to Phenol

(2015) Dengke Wang et al.   ACS Catalysis

Tri- and tetradentate copper complexes: a comparative study on homogeneous and heterogeneous catalysis over oxidation reactions

(2015) Salam J. J. Titinchi et al.   Catalysis Science & Technology

One-Step Selective Hydroxylation of Benzene to Phenol

(2015) Shunichi Fukuzumi et al.   Asian Journal of Organic Chemistry

Efficient hydroxylation of aromatic compounds catalyzed by an iron(II) complex with H2O2

(2014) Xiao Wang et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Microwave-Assisted Hydroxylation of Benzene to Phenol Over Fe(III)/TiO2 Catalysts at Room Temperature

(2014)   ASIAN JOURNAL OF CHEMISTRY

Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand

(2014) Andreas Raba et al.   CHEMICAL COMMUNICATIONS

Nickel(II) Complexes of Pentadentate N5 Ligands as Catalysts for Alkane Hydroxylation by Usingm-CPBA as Oxidant: A Combined Experimental and Computational Study

(2014) Muniyandi Sankaralingam et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron(iii) complexes of multidentate pyridinyl ligands: synthesis, characterization and catalysis of the direct hydroxylation of benzene

(2014) Beibei Xu et al.   DALTON TRANSACTIONS

Synthesis, Characterization, X-ray Crystal Structure, DFT Calculations, and Catalytic Properties of a Dioxidovanadium(V) Complex Derived from Oxamohydrazide and Pyridoxal: A Model Complex of Vanadate-Dependent Bromoperoxidase

(2014) Chandrima Das et al.   INORGANIC CHEMISTRY

Cobalt-Catalyzed C–H Arylations, Benzylations, and Alkylations with Organic Electrophiles and Beyond

(2014) Lutz Ackermann   JOURNAL OF ORGANIC CHEMISTRY

Hydrocarbon oxidation catalyzed by a cheap nonheme imine-based iron(ii) complex

(2014) Giorgio Olivo et al.   Catalysis Science & Technology

Manganese(ii) complexes of tetradentate 4N ligands with diazepane backbones for catalytic olefin epoxidation: effect of nucleophilicity of peroxo complexes on reactivity

(2014) Natarajan Saravanan et al.   RSC Advances

Highly Selective Hydroxylation of Benzene to Phenol by Wild-type Cytochrome P450BM3 Assisted by Decoy Molecules

(2013) Osami Shoji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning the olefin epoxidation by manganese(iii) complexes of bisphenolate ligands: effect of Lewis basicity of ligands on reactivity

(2013) Muniyandi Sankaralingam et al.   DALTON TRANSACTIONS

Facile one-pot synthesis of VxOy@C catalysts using sucrose for the direct hydroxylation of benzene to phenol

(2013) Weitao Wang et al.   GREEN CHEMISTRY

Mixed ligand nickel(II) complexes as catalysts for alkane hydroxylation using m-chloroperbenzoic acid as oxidant

(2013) Muniyandi Sankaralingam et al.   INORGANICA CHIMICA ACTA

Diiron(III) complexes of tridentate 3N ligands as functional models for methane monooxygenases: Effect of the capping ligand on hydroxylation of alkanes

(2013) Muniyandi Sankaralingam et al.   POLYHEDRON

Selective oxidation of benzene to phenol by FeCl3/mpg-C3N4 hybrids

(2013) Pengfei Zhang et al.   RSC Advances

Alternating-Current Electrolysis for the Production of Phenol from Benzene

(2012) Byungik Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystallographic Analysis of Active Site Contributions to Regiospecificity in the Diiron Enzyme Toluene 4-Monooxygenase

(2012) Lucas J. Bailey et al.   BIOCHEMISTRY

Direct Hydroxylation of Benzene to Phenol Over Mixed-Crystal Particles of Mesoporous VO x /TiO2 Catalyst Mixed-Crystal VO x /TiO2 for Benzene Hydroxylation

(2012) Dan Xu et al.   CATALYSIS LETTERS

Highly Selective Synthesis of Phenol from Benzene over a Vanadium-Doped Graphitic Carbon Nitride Catalyst

(2012) Guodong Ding et al.   ChemCatChem

Spectroscopic capture and reactivity of S = 1/2 nickel(iii)–oxygen intermediates in the reaction of a NiII-salt with mCPBA

(2012) Florian Felix Pfaff et al.   CHEMICAL COMMUNICATIONS

Hydroxylation of Aromatics with the Help of a Non-Haem FeOOH: A Mechanistic Study under Single-Turnover and Catalytic Conditions

(2012) Aurore Thibon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Elucidating active species and mechanism of the direct oxidation of benzene to phenol with hydrogen peroxide catalyzed by vanadium-based catalysts using DFT calculations

(2012) Dianyong Tang et al.   RSC Advances

Electrochemical Oxidation of Benzene to Phenol

(2011) Byungik Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct, copper-catalyzed oxidation of aromatic C–H bonds with hydrogen peroxide under acid-free conditions

(2011) Ana Conde et al.   CHEMICAL COMMUNICATIONS

Biomimetic iron(iii) complexes of N3O and N3O2 donor ligands: protonation of coordinated ethanolate donor enhances dioxygenase activity

(2011) Karuppasamy Sundaravel et al.   DALTON TRANSACTIONS

Active species formed in a Fenton-like system in the medium of triethylammonium acetate ionic liquid for hydroxylation of benzene to phenol

(2011) Xiaoke Hu et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Regioselectivity of aliphatic versus aromatic hydroxylation by a nonheme iron(ii)-superoxo complex

(2011) Reza Latifi et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Aromatic Hydroxylation at a Non-Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

(2010) Olga V. Makhlynets et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Axial Ligand Effect on Aliphatic and Aromatic Hydroxylation by Non-heme Iron(IV)-oxo Biomimetic Complexes

(2010) Sam P. de Visser et al.   Chemistry-An Asian Journal

Novel square pyramidal iron(iii) complexes of linear tetradentate bis(phenolate) ligands as structural and reactive models for intradiol-cleaving 3,4-PCD enzymes: Quinone formation vs. intradiol cleavage

(2010) Ramasamy Mayilmurugan et al.   DALTON TRANSACTIONS

Reactive Intermediates in Oxygenation Reactions with Mononuclear Nonheme Iron Catalysts

(2009) Jihae Yoon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclohexane and toluene oxidation catalyzed by 1,10-phenantroline Cu(II) complexes

(2009) Chaline Detoni et al.   APPLIED CATALYSIS A-GENERAL

Remarks on studies for direct production of phenol in conventional and membrane reactors

(2009) Raffaele Molinari et al.   Asia-Pacific Journal of Chemical Engineering

Oxidation of Benzene Catalyzed by 2,2′-Bipyridine and 1,10-Phenantroline Cu(II) Complexes

(2009) Chaline Detoni et al.   CATALYSIS LETTERS

How Does the Axial Ligand of Cytochrome P450 Biomimetics Influence the Regioselectivity of Aliphatic versus Aromatic Hydroxylation?

(2009) Sam P. de Visser et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enhanced Reactivities of Iron(IV)-Oxo Porphyrin π-Cation Radicals in Oxygenation Reactions by Electron-Donating Axial Ligands

(2009) Yaeun Kang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tetranuclear copper(ii)–Schiff-base complexes as active catalysts for oxidation of cyclohexane and toluene

(2009) Partha Roy et al.   DALTON TRANSACTIONS

Diiron N-bridged species bearing phthalocyanine ligand catalyzes oxidation of methane, propane and benzene under mild conditions

(2009) Evgeny V. Kudrik et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Aliphatic C−H Bond Oxidation of Toluene Using Copper Peroxo Complexes That Are Stable at Room Temperature

(2009) Christian Würtele et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toluene and Ethylbenzene Aliphatic C−H Bond Oxidations Initiated by a Dicopper(II)-μ-1,2-Peroxo Complex

(2009) Heather R. Lucas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural Characterization and Oxidation Activity of a Nickel(II) Alkylperoxo Complex

(2008) Shiro Hikichi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Di-, Tetra-, and Polynuclear Copper(II) Complexes: Active Catalysts for Oxidation of Toluene and Benzene

(2008) Partha Roy et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Non-heme iron polyazadentate complexes as catalysts for aromatic hydroxylation by H2O2: Particular efficiency of tetrakis(2-pyridylmethyl)ethylenediamine–iron(II) complexes

(2008) Aurore Thibon et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE