Article
Nanoscience & Nanotechnology
Xiang Chen, Chenxi Hu, Yang Wang, Ting Li, Jie Jiang, Jing Huang, Shibo Wang, Tianxi Liu, Weifu Dong, Jinliang Qiao
Summary: Clusteroluminescence (CL) has gained significant attention, but the development of red emission clusteroluminogens (CLgens) with adjustable CL is still in its early stages. In this study, a simple heating process was used to prepare red emission poly(maleic anhydride-alt-vinyl acetate) (PMV) derivatives with a tunable maximum emission wavelength between 620 and 675 nm. The heating process promoted the formation of clusters and enhanced through-space conjugation, resulting in adjustable emission wavelength and higher quantum yield. Additionally, cost-effective and eco-friendly core-shell PMV particles were prepared as agricultural light conversion agents and demonstrated compatibility with polyethylene.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Bin Liu, Bo Chu, Lixun Zhu, Haoke Zhang, Wang-Zhang Yuan, Zheng Zhao, Wen-Ming Wan, Xing-Hong Zhang
Summary: Clusteroluminescence (CL) materials, a class of luminescent materials with unique properties, have gained increasing attention for their theoretical significance and potential in biological applications. However, the emission mechanism remains a challenge, although through-space interaction has been proposed as a preliminary mechanism. This review summarizes the current understanding of CL materials and discusses strategies to achieve high quantum yield and adjustable emission color. The review also provides a perspective on the mechanism and application of CL materials, inspiring researchers in the development of new functional materials.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Ziteng Zhang, Jianyu Zhang, Zuping Xiong, Bo Chu, Chengjian Zhang, Jing Zhi Sun, Haoke Zhang, Xing-Hong Zhang, Ben Zhong Tang
Summary: This work presents the design and synthesis of six phenolic resins with clusteroluminescence (CL) property. By increasing the number of through-space interactions (TSIs) units and introducing electron-donating/-withdrawing groups, these non-conjugated polymers achieve near-infrared (NIR) emission with high absolute quantum yield. Through experiments and theoretical analysis, the crucial roles of through-space locally excited state and through-space charge transfer state in achieving CL from non-conjugated polymers are revealed.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Haoke Zhang, Ben Zhong Tang
Summary: Non-conjugated and non-aromatic clusteroluminogens (CLgens) have unique luminescent features different from traditional chromophores, with emitting sources achieved through through-space interactions. The formation of network clusters is proposed as an efficient strategy to enhance performance, and CLgens have potential applications in anti-counterfeiting, photoelectronic devices, and bioimaging.
Article
Chemistry, Multidisciplinary
Ziteng Zhang, Zuping Xiong, Bo Chu, Zhiming Zhang, Yuan Xie, Lei Wang, Jing Zhi Sun, Haoke Zhang, Xing-Hong Zhang, Ben Zhong Tang
Summary: In this study, six nonconjugated carbonyl-based polymers with different structures were synthesized, and their luminescent properties were systematically investigated. Experimental and theoretical results showed that the luminescent properties of the polymers could be manipulated by changing the electronic structures of carbonyl groups and the rigidity of polymer chains.
Article
Chemistry, Physical
K. Abid, A. Samet, S. Pillet, Y. Abid
Summary: Clusterization-triggered emission (CTE) of nonconventional chromophores has recently gained increased interest for its synergetic photophysical properties and promising applications. This study focuses on the optical properties of an organic-inorganic hybrid (OIH) compound (TET)(2)[Pb4Cl16], which exhibits white-light emission, tunable excitation-wavelength-dependent emission, and room temperature phosphorescence (RTP) lasting for more than 0.63 s, all indicating CTE. The emission process involves resonant energy transfer (RET) and clusteroluminescence (CL) mechanisms.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Multidisciplinary
Zhuohua Dai, Guangfa Wang, Fangfang Xiao, Da Lei, Xincun Dou
Summary: Amorphous glutathione-functionalized copper nanoparticles (GSH-CuNPs) were synthesized by controlling solvent polarity and using glutathione as a ligand. These GSH-CuNPs showed phosphorescent performance and could be used for the detection of TNT. The GSH-CuNPs exhibited high quantum yield, excellent specificity, instantaneous response, and ultralow detection limit, making them promising for optical detection.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hongwei Lu, Yuan Xie, Ziteng Zhang, Zhiming Zhang, Jing Zhi Sun, Haoke Zhang, Ben Zhong Tang
Summary: This study explores a method to modulate the clusteroluminescent properties of non-conjugated systems through the formation of complex compounds, providing a new engineering approach for the construction of efficient clusteroluminescent materials.
CHINESE JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Applied
Yurika Tani, Ryo Yonenuma, Hideharu Mori
Summary: Nonconventional stimuli-responsive luminescent polymers have been synthesized by RAFT polymerization and subsequent deprotection, exhibiting concentration-enhanced and wavelength-dependent emissions. By utilizing electrostatic interactions and hydrogen bonds, unique self-assembled structures and stimuli-responsive and fluorescent properties have been achieved. The manipulation of the assembled structures with CTE features can be controlled by the comonomer sequence and external stimuli.
REACTIVE & FUNCTIONAL POLYMERS
(2023)
Article
Chemistry, Multidisciplinary
Peisheng Cao, Yanying Wang, Haoyue Zheng, Peng Wu
Summary: This study investigates the origin of unusual room-temperature phosphorescence from n electron-rich systems and proposes a verification protocol. By comparing with other luminophores, it is able to differentiate between impurity-induced and n electron-rich phosphors. This study deepens the understanding of nonconventional luminescence.
Article
Materials Science, Multidisciplinary
Peilong Liao, Tongyue Wu, Cheng Ma, Jianbin Huang, Yun Yan
Summary: Clusterization-triggered emission (CTE) is a powerful strategy for achieving useful luminescence, such as room-temperature phosphorescence (RTP). However, the recognition of CTE-RTP is still limited. In this study, the authors demonstrate phosphorescence resonance energy transfer (PRET) in the CTE-RTP system, allowing precise control over the color of the emission. PRET can occur between CTE-RTP and fluorescent dyes, resulting in delayed fluorescence spanning from green to near infrared. This system enables facile achievement of dynamic afterglow, making it highly appealing for anticounterfeiting applications.
ADVANCED OPTICAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Xiaoyue Wang, Jing Xu, Xinrui Zhang, Zenghui Yang, Yaoming Zhang, Tingmei Wang, Qihua Wang
Summary: Ultrastrong and supertough shape-memory poly(urea-urethane) material with excellent durability and fluorescence properties is fabricated through molecular engineering.
ADVANCED MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Xueqian Zhao, Parvej Alam, Jianyu Zhang, Shiyun Lin, Qian Peng, Jun Zhang, Guodong Liang, Sijie Chen, Jing Zhang, Herman H. Y. Sung, Jacky W. Y. Lam, Ian D. Williams, Xinggui Gu, Zheng Zhao, Ben Zhong Tang
Summary: Materials exhibiting metallophilic interactions have unique photophysical and stimuli-responsive behavior. This study reports a new phosphorescent gold(I) complex that displays mechanochromic and thermochromic luminescence properties in the crystalline state.
Article
Chemistry, Physical
Xin Liu, Maodi Wang, Xiaomin Ren, Miao Guo, Chunzhi Li, He Li, Qihua Yang
Summary: Synergistic catalysis with weak interactions is an efficient approach for the selective hydrogenation of substrates with multiple unsaturated groups.
Article
Chemistry, Multidisciplinary
Zuping Xiong, Jianyu Zhang, Lei Wang, Yuan Xie, Yipu Wang, Zujin Zhao, Haoke Zhang, Jing Zhi Sun, Feihe Huang, Ben Zhong Tang
Summary: Nonconjugated clusteroluminogens (CLgens), such as proteins and polystyrene, have become increasingly important in photophysics due to their advantages over traditional conjugated dyes in biological applications. However, their weak visible emissions in the aggregate state have hindered their development. This study proposes a strategy to construct a higher-level intramolecular through-space interaction (TSI) in multi-aryl-substituted alkanes, resulting in efficient clusteroluminescence (CL) with high luminescence quantum yield and long emission wavelength.
Article
Chemistry, Multidisciplinary
Bin Liu, Bo Chu, Lixun Zhu, Haoke Zhang, Wang-Zhang Yuan, Zheng Zhao, Wen-Ming Wan, Xing-Hong Zhang
Summary: Clusteroluminescence (CL) materials, a class of luminescent materials with unique properties, have gained increasing attention for their theoretical significance and potential in biological applications. However, the emission mechanism remains a challenge, although through-space interaction has been proposed as a preliminary mechanism. This review summarizes the current understanding of CL materials and discusses strategies to achieve high quantum yield and adjustable emission color. The review also provides a perspective on the mechanism and application of CL materials, inspiring researchers in the development of new functional materials.
CHINESE CHEMICAL LETTERS
(2023)
Article
Biochemistry & Molecular Biology
Tanxiao Shen, Manyu Chen, Haoke Zhang, Jing Zhi Sun, Ben Zhong Tang
Summary: By copolymerizing 4-trimethylsilyl diphenyl acetylene and 1-trimethylsilyl-1-propyne, PTMSDPA was successfully converted from aggregation-caused quenching (ACQ) to aggregation-induced emission (AIE) and aggregation-induced emission enhancement (AEE). A series of copolymers emitting blue-purple to orange-red light were obtained, demonstrating the feasibility of their application in explosive detection.
Article
Chemistry, Multidisciplinary
Zhiming Zhang, Longchen Zhu, Jiahui Feng, Haoke Zhang, Xin Zhang, Jing Zhi Sun, Ben Zhong Tang
Summary: Proteins exhibit abnormal visible emission at the clustering state, known as clusteroluminescence (CL). This study explores the CL properties of two proteins and successfully utilizes CL to monitor processes of protein fibrillation and denaturation, broadening the application and strategies for monitoring protein aggregation.
MATERIALS CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Multidisciplinary
Li Xin Hou, Huaqiang Ju, Xing Peng Hao, Haoke Zhang, Lei Zhang, Zhiyuan He, Jianjun Wang, Qiang Zheng, Zi Liang Wu
Summary: This study presents a glassy hydrogel with intrinsic anti-freezing capacity and excellent optical and mechanical properties at ultra-low temperatures. The hydrogel has a moderate water content and dense hydrogen-bond associations, and becomes stronger and stiffer, yet still ductile, as the temperature decreases. It retains high transparency even in liquid nitrogen and exhibits unique phosphorescence at subzero temperatures.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Kaiwu Yu, Haoying Huang, Haoke Zhang, Qinggang He, Zhurong Fu, Hong Zhang, Qinghua Zhang, Zhengwei Mao, Mei Tian
Summary: Breast cancer is a significant burden globally, and current diagnostic and therapeutic methods face challenges with incomplete tumor information and limited efficacy. AIEgens have shown promise for cancer treatment, but their limited penetration depth hinders deep-seated tumor diagnosis. In this study, a radiolabeled AIEgen-based organic photothermal agent was developed for bimodal PET/fluorescence imaging-guided breast tumor photothermal therapy. The multifunctional nanoparticles efficiently targeted and visualized tumor cells, inducing reactive oxygen species burst for enhanced photothermal treatment. PET and NIR-II fluorescence imaging achieved high tumor/muscle ratios, providing a promising tool for breast tumor theranostics.
CHEMISTRY-AN ASIAN JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Huaqiang Ju, Haoke Zhang, Li Xin Hou, Min Zuo, Miao Du, Feihe Huang, Qiang Zheng, Zi Liang Wu
Summary: We propose a facile strategy to achieve room-temperature phosphorescence in conventional hydrogels by polymerization-induced crystallization of dopant molecules, leading to clusterization-induced phosphorescence. Crown ethers dissolved in a concentrated acrylamide aqueous solution crystallize during polymerization to form large spherulites in the hydrogel, resulting in carbonyl clusters and phosphorescence emission. This strategy is universally applicable to hydrogels with different polymeric matrices and dopant molecules. The development of hydrogels with mechanical and phosphorescent properties holds great potential in the biomedical and engineering fields.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Huangtianzhi Zhu, Junkai Liu, Yitao Wu, Lei Wang, Haoke Zhang, Qi Li, Hu Wang, Hao Xing, Jonathan L. Sessler, Feihe Huang
Summary: In this study, a room-temperature phosphorescence (RTP) system responsive to alkyl halides was described. The system consisted of a meta-formylphenyl-bearing pillar[5]arene derivative that supported effective through-space charge transfer. Treatment with bromoethane enhanced the emission. An isomeric para-formylphenyl-bearing pillar[5]arene system proved ineffective in producing an RTP effect.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Review
Biochemistry & Molecular Biology
Manyu Chen, Guangze Hu, Tanxiao Shen, Haoke Zhang, Jing Zhi Sun, Ben Zhong Tang
Summary: As a low energy consumption, simple operation and environmentally friendly separation method, membrane separation has attracted extensive attention. Therefore, researchers have designed and synthesized various types of separation membrane, such as metal organic framework (MOF), covalent organic framework (COF), polymer of intrinsic micro-porosity (PIM) and mixed matrix membranes. This article mainly introduces the development and application of substituted polyacetylenes in gas separation and liquid separation based on membrane technology.
Article
Multidisciplinary Sciences
Jianyu Zhang, Yujie Tu, Hanchen Shen, Jacky W. Y. Lam, Jianwei Sun, Haoke Zhang, Ben Zhong Tang
Summary: This study systematically illustrates the impacts of proximity effect and aggregation-induced emission (AIE) on luminescent behaviors of heterocyclic luminogens. The authors report a series of methylquinoxaline derivatives and reveal the energy level changes and coupling effects of the closely related (n,& pi;*) and (& pi;,& pi;*) states, which intrinsically regulate proximity effect and AIE behaviors. The results provide insights into the development of functional and responsive luminogens with AIE properties.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Juechen Ni, Qiguang Zang, Haoke Zhang, Jing Zhi Sun, Ben Zhong Tang
Summary: We demonstrate a unique mechanoluminochromic (MLC) effect of an aggregation-induced emission (AIE)-active luminogen (AIEgen), DTPE-TB, characterized by changed emission intensity but unimpressively shifted emission colors of the molecular solid. This behavior, termed mechanofluoro enhancement (MFE), is distinct from commonly reported AIEgens with MLC property. The MFE effect is attributed to the special design of the DTPE-TB molecule, with the tetraphenylethene (TPE) units responsible for AIE and the Troger's base unit acting as a mechanical force supporter. Under mechanical forces, the lambda-shaped Troger's base unit releases external forces by changing its dihedral angle, while the TPE units remain nearly unchanged in molecular arrangement. As a result, the DTPE-TB solid exhibits enhanced emission under pressure due to the restricted intramolecular motions, accompanied by slight shifts in emission wavelength due to variations in molecular packing.
SCIENCE CHINA-MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Hongwei Lu, Yuan Xie, Ziteng Zhang, Zhiming Zhang, Jing Zhi Sun, Haoke Zhang, Ben Zhong Tang
Summary: This study explores a method to modulate the clusteroluminescent properties of non-conjugated systems through the formation of complex compounds, providing a new engineering approach for the construction of efficient clusteroluminescent materials.
CHINESE JOURNAL OF CHEMISTRY
(2023)
Review
Chemistry, Analytical
Jieyu Bao, Chuanye Tong, Mengxuan He, Haoke Zhang
Summary: This paper provides an overview of three distinct types of luminescent polypeptides: natural fluorescent proteins, luminophores-bioconjugated polypeptides, and clusteroluminescent polypeptides. It emphasizes the significance and prospects of clusteroluminescent polypeptides as crucial new-generation bioluminophores.
Article
Polymer Science
Jia-Hui Xin, Bian-Bian Guo, Chang Liu, Cheng-Ye Zhu, Haoke Zhang, Ben Zhong Tang, Zhi-Kang Xu
Summary: Interfacial polymerization is a widely used method for synthesizing high-performance materials, but monitoring the growth of polymers during this process has been challenging. To overcome this, we have utilized the aggregation-induced emission effect to observe the entire interfacial polymerization process in real time. Using a confocal laser scanning microscope, we obtained clear images of the polymer and characterized its structural heterogeneity. Interestingly, our study revealed that the polymer density is higher away from the interface, contrary to expectations of homogeneity. The changing ratio of monomers in the reaction region explains this density gradient. Additionally, we demonstrated the precise growth kinetics of the polymer under different conditions. Our results provide a novel platform for understanding the mechanisms and properties of interfacial polymerization.
Article
Chemistry, Inorganic & Nuclear
Wenxin Lin, Yijia Wang, Haoke Zhang, Kei Hoi Shan, Panpan Si, Shijiang Yu, Zhen Wang, Dian Zhao, Junkuo Gao, Minghua Wu, Ben Zhong Tang
Summary: A novel metal-organic framework with strong fluorescence was synthesized and showed ideal luminescent property in water. It exhibited differential fluorescent response to different types of amino acids, providing a potential strategy for designing MOF-based sensors for biomolecules.
DALTON TRANSACTIONS
(2023)