4.7 Article

Adsorptive removal of sulfonamides, tetracyclines and quinolones from wastewater and water using carbon-based materials: Recent developments and future directions

期刊

JOURNAL OF CLEANER PRODUCTION
卷 349, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2022.131421

关键词

Emerging contaminants; Antibiotics; Adsorption; Carbon-based materials; Biochar; Hydrochar

资金

  1. National Research Foundation (NRF), Singapore
  2. Ministry of National Development, Singapore under its Cities of Tomorrow R&D Programme (CoT Award) [COT-V4-2019-6]

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This review critically analyzes the use of carbon based materials (biochar and hydrochar) for removing antibiotics from wastewater and water. Biochar and hydrochar both show excellent performance for adsorptive removal of antibiotics, with hydrochar having a higher adsorption capacity than biochar for tetracyclines. The key mechanisms for antibiotic adsorption onto biochar/hydrochar surfaces include 7C-7C electron donor-acceptor interactions and H-bonding. Thermodynamics studies indicate that the sorption process is mostly spontaneous and endothermic. Overall, the use of biochar/hydrochar for removing antibiotics from water has significant potential from both economic and environmental perspectives.
Antibiotics are widely used for treatment of diseases caused by bacteria. They reach the aquatic environment through urine and excreta. The dominant antibiotics that are commonly detected in aquatic environments include tetracyclines, sulfonamides and quinolones. This review critically analyzes the effectiveness of carbon based materials (biochar and hydrochar) for removal of antibiotics from wastewater and water. Both biochar and hydrochar show excellent performance for adsorptive removal of antibiotics from the aqueous medium. However, the adsorption capacity of hydrochar is relatively higher than that of biochar, specifically for the removal of tetracyclines. Insights into removal mechanisms, solution chemistry, adsorption kinetics, isotherms, adsorbent regeneration and cost-analysis are provided. The key mechanisms associated in the adsorption of antibiotics onto biochar/hydrochar surfaces include 7C-7C electron donor-acceptor interactions and H-bonding. Thermodynamics studies indicate the sorption process is mostly spontaneous and endothermic. In most cases, the adsorption data can best fit the pseudo-second-order kinetic and Langmuir isotherm models. Overall, biochar/ hydrochar-mediated adsorptive removal of antibiotics from aqueous solution merits serious considerations from both economic and environmental perspectives. The key knowledge gaps and future research directions are highlighted to expand the scope of ongoing research on engineered biochar/hydrochar and modification of their physicochemical characteristics to achieve effective removal of antibiotics and their metabolites.

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