4.4 Review

Advance of click chemistry in anion exchange membranes for energy application

期刊

JOURNAL OF POLYMER SCIENCE
卷 60, 期 4, 页码 627-649

出版社

WILEY
DOI: 10.1002/pol.20210819

关键词

anion exchange membranes; click chemistry; fuel cells; post-polymerization modification

资金

  1. National Nature Science Foundation of China [21975205, 21504068]
  2. Natural Science Foundation of Chongqing [cstc2020jcyj-msxmX1078]
  3. Shaanxi National Science Foundation [2020JM-138]
  4. Fundamental Research Funds for the Central Universities [3102017jc01001]
  5. Open Project of State Key Laboratory of Supramolecular Structure and Materials [sklssm2021025]

向作者/读者索取更多资源

Click chemistry has gained significant attention in polymer synthesis due to its high efficiency, simple processes, and diverse architectures. In particular, it has been widely used in the preparation of anion exchange membranes (AEMs), which show robust performance in energy-related fields.
Click chemistry has attracted tremendous attention in polymer synthesis due to its high efficiency, considerable yield, and simple synthesis/work-up procedures. Among the various functional polymer materials prepared by click chemistry, anion exchange membrane (AEM) is a kind of polyelectrolyte which contains cations attached to the polymer skeleton. Click chemistry not only provides facile pathways for the preparation of AEMs but also generates diverse architectures of AEMs with robust performance. The commonly used click chemistry in AEMs consists of: (i) Diels-Alder reaction, (ii) thiol-ene, and (iii) Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC). This review will focus on the advance of click chemistry in the preparation of AEMs, especially synthetic approaches for different AEMs and their corresponding application in energy-related fields, such as fuel cells, redox flow battery, electrodialysis, and so on.

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