The α-effect in the SNAr reaction of 1-(4-nitrophenoxy)-2,4-dinitrobenzene with anionic nucleophiles: effects of solvation and polarizability on the α-effect

Kinetic Study on SNAr Reaction of 1-Y-Substituted-phenoxy-2,4-dinitrobenzenes with Hydroxide Ion: Effect of Substituent Y on Reactivity and Reaction Mechanism

(2014) Tae-Ah Kang et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Exploration of the α-effect by substitution on hydroxylamine anions. I. Effects of alkyl- and fluoroalkylation

(2014) D. Afzal et al.   CANADIAN JOURNAL OF CHEMISTRY

Alkali-Metal Ion Catalysis and Inhibition in SNAr Displacement: Relative Stabilization of Ground State and Transition State Determines Catalysis and Inhibition in SNAr Reactivity

(2014) Ik-Hwan Um et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic Study on SNAr Reaction of 1-(Y-Substituted-phenoxy)-2,4-dinitrobenzenes with Cyclic Secondary Amines in Acetonitrile: Evidence for Cyclic Transition-State Structure

(2014) Ik-Hwan Um et al.   JOURNAL OF ORGANIC CHEMISTRY

The α-effect exhibited in gas-phase SN2@N and SN2@C reactions

(2013) Yi Ren et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Dissection of Activation Parameters in the Bell-Shaped α-Effect Following Solvent Modulation (DMSO–H2O Media)

(2013) Ik-Hwan Um et al.   JOURNAL OF ORGANIC CHEMISTRY

Resolving the α-effect in gas phase SN2 reactions: A Marcus theory approach

(2012) John M. Garver et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

The α-effect in elimination reactions and competing mechanisms in the gas phase

(2012) John M. Garver et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

Density functional study of SN2 substitution reactions for CH3Cl + CX1X2•− (X1X2 = HH, HF, HCl, HBr, HI, FF, ClCl, BrBr, and II)

(2012) Jun-Xi Liang et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Mechanistic Assessment of SNAr Displacement of Halides from 1-Halo-2,4-dinitrobenzenes by Selected Primary and Secondary Amines: Brønsted and Mayr Analyses

(2012) Ik-Hwan Um et al.   JOURNAL OF ORGANIC CHEMISTRY

Nucleophilic Reactivities of Hydrazines and Amines: The Futile Search for the α-Effect in Hydrazine Reactivities

(2012) Tobias A. Nigst et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydroxylamine as an oxygen nucleophile: substitution of sulfonamide by a hydroxyl group in benzothiazole-2-sulfonamides

(2012) Jos J. A. G. Kamps et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Super-electrophilic 10π Heteroaromatics. New Mechanistic and Synthetic Applications

(2012) Sergey Kurbatov et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

Theoretical investigation of experimentally determined α-εffects — The role of electronics

(2011) D. Afzal et al.   CANADIAN JOURNAL OF CHEMISTRY

Experimental Validation of the α-Effect in the Gas Phase

(2011) John M. Garver et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual super-electrophilic and Diels–Alder reactivity of neutral 10π heteroaromatic substrates

(2011) François Terrier et al.   TETRAHEDRON

Ammonia oxide makes up some 20% of an aqueous solution of hydroxylamine

(2010) Anthony J. Kirby et al.   CHEMICAL COMMUNICATIONS

Pitfalls in Assessing the α-Effect: Reactions of Substituted Phenyl Methanesulfonates with HOO−, OH−, and Substituted Phenoxides in H2O

(2010) Ik-Hwan Um et al.   JOURNAL OF ORGANIC CHEMISTRY

Enhanced Reactivity of RC≡CZ−(R = H and Cl; Z = O, S, and Se) and the Influence of Leaving Group on the α-Effect in the E2 Reactions

(2010) Xi-Guang Wei et al.   JOURNAL OF ORGANIC CHEMISTRY

Cationic Micellar-Catalyzed Hydrolysis of Pesticide Fenitrothion Using α-Nucleophiles

(2010) Shuchi Tiwari et al.   Letters in Drug Design & Discovery

Efficient Intramolecular General-Acid Catalysis of the Reactions of α-Effect Nucleophiles and Ammonia Oxide with a Phosphate Triester

(2009) Anthony J. Kirby et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of α-Nucleophiles with Alkyl Chlorides: Competition between SN2 and E2 Mechanisms and the Gas-Phase α-Effect

(2009) Stephanie M. Villano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effects on the Reactivity by Changing the Electrophilic Center from CO to CS: Contrasting Reactivity of Hydroxide,p-Chlorophenoxide, and Butan-2,3-dione Monoximate in DMSO/H2O Mixtures

(2008) Ik-Hwan Um et al.   CHEMISTRY-A EUROPEAN JOURNAL

Does α-effect exist in E2 reactions? A G2(+) investigation

(2008) Yi Ren et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Electrophilicity of aromatic triflones in σ-complexation processes

(2008) Nizar El Guesmi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Reactions of the hydroperoxide anion with dimethyl methylphosphonate in an ion trap mass spectrometer: evidence for a gas phase α-effect

(2008) Andrew Michael McAnoy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY