Striding the threshold of an atom era of organic synthesis by single-atom catalysis

Atmosphere-Pressure Methane Oxidation to Methyl Trifluoroacetate Enabled by a Porous Organic Polymer-Supported Single-Site Palladium Catalyst

(2021) Yiwen Zhang et al.   ACS Catalysis

Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids

(2021) Estefanía Tiburcio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Deciphering the Local Environment of Single-Atom Catalysts with X-ray Absorption Spectroscopy

(2021) Yuanyuan Li et al.   ACCOUNTS OF CHEMICAL RESEARCH

Zeolite Fixed Metal Nanoparticles: New Perspective in Catalysis

(2021) Yeqing Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Isolated metal atoms and clusters for alkane activation: translating knowledge from enzymatic and homogeneous to heterogeneous systems

(2021) Lichen Liu et al.   Chem

Accelerated Anti‐Markovnikov Alkene Hydrosilylation with Humic‐Acid‐Supported Electron Deficient Platinum Single Atoms

(2021) Kairui Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Electronic Metal–Support Interaction Directing the Design of Single Atomic Site Catalysts: Achieving High Efficiency Towards Hydrogen Evolution

(2021) Jiarui Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tridentate Ligands in Transition Metal-Catalyzed Asymmetric Hydrogenation

(2021) Heng Wang et al.   CHEMICAL REVIEWS

Creating High Regioselectivity by Electronic Metal–Support Interaction of a Single-Atomic-Site Catalyst

(2021) Wen-Hao Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefins

(2021) Peng Gao et al.   Nature Communications

A heterogeneous iridium single-atom-site catalyst for highly regioselective carbenoid O–H bond insertion

(2021) Jie Zhao et al.   Nature Catalysis

Styrene Hydroformylation with In situ H: Regioselectivity Control by Coupling with Low-temperature Water Gas Shift Reaction

(2020) Botao Qiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Prospects of Heterogeneous Hydroformylation with Supported Single Atom Catalysts

(2020) Jonas Amsler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable single platinum atoms trapped in sub-nanometer cavities in 12CaO·7Al2O3 for chemoselective hydrogenation of nitroarenes

(2020) Tian-Nan Ye et al.   Nature Communications

Tuning Polarity of Cu-O Bond in Heterogeneous Cu Catalyst to Promote Additive-free Hydroboration of Alkynes

(2020) Jian Zhang et al.   Chem

Nanostructuring unlocks high performance of platinum single-atom catalysts for stable vinyl chloride production

(2020) Selina K. Kaiser et al.   Nature Catalysis

Integration of Metal Single Atoms on Hierarchical Porous Nitrogen-Doped Carbon for Highly Efficient Hydrogenation of Large-Sized Molecules in the Pharmaceutical Industry

(2020) Runkun Huang et al.   ACS Applied Materials & Interfaces

Chemical Synthesis of Single Atomic Site Catalysts

(2020) Shufang Ji et al.   CHEMICAL REVIEWS

Carbon Nitride-Based Single-Atom Cu Catalysts for Highly Efficient Carboxylation of Alkynes with Atmospheric CO2

(2020) Peng Yang et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Modulating the local coordination environment of single-atom catalysts for enhanced catalytic performance

(2020) Xinyuan Li et al.   Nano Research

Strong metal-support interaction promoted scalable production of thermally stable single-atom catalysts

(2020) Kaipeng Liu et al.   Nature Communications

Single-Atom Alloy Catalysis

(2020) Ryan T. Hannagan et al.   CHEMICAL REVIEWS

Single-atom site catalysts for environmental catalysis

(2020) Ningqiang Zhang et al.   Nano Research

Iridium single-atom catalyst on nitrogen-doped carbon for formic acid oxidation synthesized using a general host–guest strategy

(2020) Zhi Li et al.   Nature Chemistry

Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination

(2020) Bingzhang Lu et al.   ACS Catalysis

Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes

(2020) Wen-Yong Huang et al.   Chem

Confining isolated atoms and clusters in crystalline porous materials for catalysis

(2020) Lichen Liu et al.   Nature Reviews Materials

“More is Different:” Synergistic Effect and Structural Engineering in Double‐Atom Catalysts

(2020) Yiran Ying et al.   ADVANCED FUNCTIONAL MATERIALS

A high-energy and long-cycling lithium–sulfur pouch cell via a macroporous catalytic cathode with double-end binding sites

(2020) Chen Zhao et al.   Nature Nanotechnology

Shape-selective C–H activation of aromatics to biarylic compounds using molecular palladium in zeolites

(2020) Jannick Vercammen et al.   Nature Catalysis

Constructing mononuclear palladium catalysts by precoordination/solvothermal polymerization platform: a recyclable catalyst for regioselective oxidative Heck reaction

(2019) Wen-Hao Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ/Operando Techniques for Characterization of Single-Atom Catalysts

(2019) Xuning Li et al.   ACS Catalysis

A highly CO-tolerant atomically dispersed Pt catalyst for chemoselective hydrogenation

(2019) Lili Lin et al.   Nature Nanotechnology

Atomically Dispersed Ruthenium Species Inside Metal-Organic Frameworks: Combining the High Activity of Atomic Sites and the Molecular Sieving Effect of MOFs

(2019) Shufang Ji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Holistic prediction of enantioselectivity in asymmetric catalysis

(2019) Jolene P. Reid et al.   NATURE

Zeolite-Encaged Single-Atom Rhodium Catalysts: Highly-Efficient Hydrogen Generation and Shape-Selective Tandem Hydrogenation of Nitroarenes

(2019) Qiming Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction: Industrial Perspective on Single-Atom Catalysis

(2019) Chuan-Ming Wang et al.   Chem

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

(2019) Tom W. van Deelen et al.   Nature Catalysis

Expedient synthesis of E-hydrazone esters and 1H-indazole scaffolds through heterogeneous single-atom platinum catalysis

(2019) Cuibo Liu et al.   Science Advances

Maximizing the Number of Interfacial Sites in Single-Atom Catalysts for the Highly Selective, Solvent-Free Oxidation of Primary Alcohols

(2018) Tianbo Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd Metal Catalysts for Cross-Couplings and Related Reactions in the 21st Century: A Critical Review

(2018) Andrea Biffis et al.   CHEMICAL REVIEWS

Discovering Partially Charged Single-Atom Pt for Enhanced Anti-Markovnikov Alkene Hydrosilylation

(2018) Yuanjun Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-site catalyst promoters accelerate metal-catalyzed nitroarene hydrogenation

(2018) Liang Wang et al.   Nature Communications

Cation vacancy stabilization of single-atomic-site Pt1/Ni(OH)x catalyst for diboration of alkynes and alkenes

(2018) Jian Zhang et al.   Nature Communications

Single-atom catalysts and their applications in organic chemistry

(2018) Huan Yan et al.   Journal of Materials Chemistry A

Electrochemical Oxidative Cross-coupling with Hydrogen Evolution: A Green and Sustainable Way for Bond Formation

(2018) Shan Tang et al.   Chem

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Design of Effective Catalysts for Selective Alkyne Hydrogenation by Doping of Ceria with a Single-Atom Promotor

(2018) Christopher Riley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative sp3 C–N coupling via dual copper and photoredox catalysis

(2018) Yufan Liang et al.   NATURE

Single-atom catalyst: a rising star for green synthesis of fine chemicals

(2018) Leilei Zhang et al.   National Science Review

Xantphos doped Rh/POPs-PPh 3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of Xantphos and PPh 3

(2017) Cunyao Li et al.   JOURNAL OF CATALYSIS

MoS2 monolayer catalyst doped with isolated Co atoms for the hydrodeoxygenation reaction

(2017) Guoliang Liu et al.   Nature Chemistry

The MOF-driven synthesis of supported palladium clusters with catalytic activity for carbene-mediated chemistry

(2017) Francisco R. Fortea-Pérez et al.   NATURE MATERIALS

A Ligand-Directed Catalytic Regioselective Hydrocarboxylation of Aryl Olefins with Pd and Formic Acid

(2017) Wei Liu et al.   ORGANIC LETTERS

Activation of surface lattice oxygen in single-atom Pt/CeO2for low-temperature CO oxidation

(2017) Lei Nie et al.   SCIENCE

Identification of single-site gold catalysis in acetylene hydrochlorination

(2017) Grazia Malta et al.   SCIENCE

Supported Palladium–Gold Alloy Catalysts for Efficient and Selective Hydrosilylation under Mild Conditions with Isolated Single Palladium Atoms in Alloy Nanoparticles as the Main Active Site

(2017) Hiroki Miura et al.   ACS Catalysis

Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions

(2017) Guang Xian Pei et al.   ACS Catalysis

Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions

(2017) Xinjiang Cui et al.   ACS Central Science

Subnanometric Hybrid Pd-M(OH) 2 , M = Ni, Co, Clusters in Zeolites as Highly Efficient Nanocatalysts for Hydrogen Generation

(2017) Qiming Sun et al.   Chem

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Hydroformylation of Olefins by a Rhodium Single-Atom Catalyst with Activity Comparable to RhCl(PPh3)3

(2016) Rui Lang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene

(2016) Cunyao Li et al.   GREEN CHEMISTRY

Metal–Organic Framework Nodes Support Single-Site Magnesium–Alkyl Catalysts for Hydroboration and Hydroamination Reactions

(2016) Kuntal Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploration of Single-Atom X-ray Analysis in an Analytical Electron Microscope

(2016) M. Watanabe   MICROSCOPY AND MICROANALYSIS

Photochemical route for synthesizing atomically dispersed palladium catalysts

(2016) P. Liu et al.   SCIENCE

Single-atom dispersed Co–N–C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes

(2016) Wengang Liu et al.   Chemical Science

Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst

(2016) Liangbing Wang et al.   Nature Communications

A Stable Single-Site Palladium Catalyst for Hydrogenations

(2015) Gianvito Vilé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Heterogeneous Hydroformylation over Rh-Metalated Porous Organic Polymers: Synergistic Effect of High Ligand Concentration and Flexible Framework

(2015) Qi Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Site Palladium(II) Catalyst for Oxidative Heck Reaction: Catalytic Performance and Kinetic Investigations

(2015) Hui Duan et al.   ACS Catalysis

Co–N–C Catalyst for C–C Coupling Reactions: On the Catalytic Performance and Active Sites

(2015) Leilei Zhang et al.   ACS Catalysis

Privileged Phosphine-Based Metal–Organic Frameworks for Broad-Scope Asymmetric Catalysis

(2014) Joseph M. Falkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols

(2014) Liping Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective construction of remote quaternary stereocentres

(2014) Tian-Sheng Mei et al.   NATURE

Superhydrophobic, chiral, and mesoporous TsDPEN copolymer coordinated to ruthenium species as an efficient catalyst for asymmetric transfer hydrogenation

(2013) Qi Sun et al.   Nano Today

Compositional segregation in shaped Pt alloy nanoparticles and their structural behaviour during electrocatalysis

(2013) Chunhua Cui et al.   NATURE MATERIALS

Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations

(2012) Georgios Kyriakou et al.   SCIENCE

Single-atom catalysis of CO oxidation using Pt1/FeO x

(2011) Botao Qiao et al.   Nature Chemistry

Palladium Nanoparticles on Graphite Oxide and Its Functionalized Graphene Derivatives as Highly Active Catalysts for the Suzuki−Miyaura Coupling Reaction

(2009) Gil M. Scheuermann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Supported gold nanoparticles as catalysts for organic reactions

(2008) Avelino Corma et al.   CHEMICAL SOCIETY REVIEWS