Carbene‐Catalyzed Enantioselective Hydrophosphination of α‐Bromoenals to Prepare Phosphine‐Containing Chiral Molecules

Rapd Synthesis of Chiral 1,2-Bisphosphine Derivatives through Copper(I)-Catalyzed Asymmetric Conjugate Hydrophosphination

(2020) Wen-Jun Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective NHC-Catalyzed [3+3] Annulation of α-Bromoenals with 2-Aminobenzimidazoles

(2020) Yangxi Xie et al.   ORGANIC LETTERS

Bifunctional N-Heterocyclic Carbenes Derived from l-Pyroglutamic Acid and Their Applications in Enantioselective Organocatalysis

(2020) Xiang-Yu Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Asymmetric Diarylphosphine Addition to α-Diazoesters for the Synthesis of P-Stereogenic Phosphinates via P*—N Bond Formation

(2020) László B. Balázs et al.   JOURNAL OF ORGANIC CHEMISTRY

NHC-Catalyzed Enantioselective [3 + 3] Annulation to Construct 5,6-Dihydropyrimidin-4-ones

(2020) Di Meng et al.   ORGANIC LETTERS

Chiral Ugi-Type Amines: Practical Synthesis, Ligand Development, and Asymmetric Catalysis

(2020) Wu-Wei Dong et al.   ACS Catalysis

NHC-Catalyzed Generation of α,β-Unsaturated Acylazoliums for the Enantioselective Synthesis of Heterocycles and Carbocycles

(2019) Santigopal Mondal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis

(2019) Zhiwu Lu et al.   ACS Catalysis

Phosphine-Catalyzed (3+2) Annulation of Isoindigos with Allenes: Enantioselective Formation of Two Vicinal Quaternary Stereogenic Centers

(2019) Wai-Lun Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Catalyzed [3 + 3] Annulation of Thioamides and Modified Enals for the Enantioselective Synthesis of Functionalized Thiazinones

(2019) Arghya Ghosh et al.   ORGANIC LETTERS

Carbene-Catalyzed Enantioselective Addition of Thioamides to Bromoenals for Access to Thiazinone Heterocycles

(2019) Changyi Liu et al.   ORGANIC LETTERS

Key factors in pincer ligand design

(2018) Eduardo Peris et al.   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic Carbene-Catalyzed Enantioselective β-Amination of α-Bromoenals Enabled by a Proton-Shuttling Strategy

(2018) Ming Lang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Phosphine Organocatalysis

(2018) Hongchao Guo et al.   CHEMICAL REVIEWS

Sulfinate and Carbene Co-catalyzed Rauhut-Currier Reaction for Enantioselective Access to Azepino[1,2-a ]indoles

(2018) Xingxing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective N-Heterocyclic Carbene-Catalyzed Cascade Reaction for the Synthesis of Pyrroloquinolines via N–H Functionalization of Indoles

(2018) Subrata Mukherjee et al.   ORGANIC LETTERS

N-Heterocyclic Carbene Catalysis via the α,β-Unsaturated Acyl Azolium

(2017) Changhe Zhang et al.   ACS Catalysis

Amino Acid-Derived Bifunctional Phosphines for Enantioselective Transformations

(2016) Tianli Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Nucleophilic β-Carbon-Atom Amination of Enals: Carbene-Catalyzed Formal [3+2] Reactions

(2016) Xingxing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Applications and stereoselective syntheses of P-chirogenic phosphorus compounds

(2016) Mathieu Dutartre et al.   CHEMICAL SOCIETY REVIEWS

Organocatalytic Kinetic Resolution of Sulfoximines

(2016) Shunxi Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to P-Stereogenic Phosphinates via N-Heterocyclic Carbene-Catalyzed Desymmetrization of Bisphenols

(2016) Zhijian Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Catalyzed Dynamic Kinetic Resolution of Pyranones

(2015) Changgui Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

Pd-Catalyzed Enantiodivergent and Regiospecificphospha-Michael Addition of Diphenylphosphine to 4-oxo-Enamides: Efficient Access to Chiral Phosphinocarboxamides and Their Analogues

(2015) Renta Jonathan Chew et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Chromanones via a Peptidic Phosphane Catalyzed Rauhut–Currier Reaction

(2015) Robert J. H. Scanes et al.   ORGANIC LETTERS

Asymmetric 1,4-Conjugate Addition of Diarylphosphines to α,β,γ,δ-Unsaturated Ketones Catalyzed by Transition-Metal Pincer Complexes

(2015) Xiang-Yuan Yang et al.   ORGANOMETALLICS

On the Mechanism of N-Heterocyclic Carbene-Catalyzed Reactions Involving Acyl Azoliums

(2014) Jessada Mahatthananchai et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Synthesis of Highly Substituted β-Lactones through Oxidative Carbene Catalysis with LiCl as Cooperative Lewis Acid

(2014) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Cyclocondensation of α,β-Unsaturated Carboxylic Acids: Enantioselective Synthesis of Pyrrolidinone and Dihydropyridinone Derivatives

(2014) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral phosphines in nucleophilic organocatalysis

(2014) Yumei Xiao et al.   Beilstein Journal of Organic Chemistry

Enantioselective phospha-Michael addition of diarylphosphines to β,γ-unsaturated α-ketoesters and amides

(2014) Renta Jonathan Chew et al.   CHEMICAL COMMUNICATIONS

Palladacycle Catalyzed Asymmetric PH Addition of Diarylphosphines toN-Enoyl Phthalimides

(2014) Renta Jonathan Chew et al.   CHEMISTRY-A EUROPEAN JOURNAL

Contemporary avenues in catalytic PH bond addition reaction: A case study of hydrophosphination

(2014) Vijay Koshti et al.   COORDINATION CHEMISTRY REVIEWS

Asymmetric Construction of a Ferrocenyl Phosphapalladacycle from Achiral Enones and a Demonstration of Its Catalytic Potential

(2014) Kennard Gan et al.   ORGANOMETALLICS

Enantioselective Addition of Diphenylphosphine to 3-Methyl-4-nitro-5-alkenylisoxazoles

(2013) Renta Jonathan Chew et al.   ADVANCED SYNTHESIS & CATALYSIS

Chiral Magnesium(II) Binaphtholates as Cooperative Brønsted/Lewis Acid-Base Catalysts for the Highly Enantioselective Addition of Phosphorus Nucleophiles to α,β-Unsaturated Esters and Ketones

(2013) Manabu Hatano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed asymmetric 1,6-addition of diarylphosphines to α,β,γ,δ-unsaturated sulfonic esters: controlling regioselectivity by rational selection of electron-withdrawing groups

(2013) Junzhu Lu et al.   CHEMICAL COMMUNICATIONS

Acyl anion free N-heterocyclic carbene organocatalysis

(2013) Sarah J. Ryan et al.   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic Carbene-Catalyzed Stereoselective Cascade Reaction: Synthesis of Functionalized Tetrahydroquinolines

(2013) Hai-Rui Zhang et al.   ORGANIC LETTERS

Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to α,β-Unsaturated Sulfonic Esters for the Synthesis of Chiral Phosphine Sulfonate Compounds

(2013) Junzhu Lu et al.   ORGANIC LETTERS

NHC–copper-catalyzed asymmetric 1,4-addition of diarylphosphines to α,β-unsaturated ketones

(2013) Yun-Rong Chen et al.   TETRAHEDRON LETTERS

Palladium-catalyzed Asymmetric 1,4-Addition of Diarylphosphines to α,β-Unsaturated Carboxylic Esters

(2013) Dan Du et al.   Asian Journal of Organic Chemistry

Palladium-Catalyzed Asymmetric 1,4-Addition of Diarylphosphines to Nitroalkenes for the Synthesis of Chiral P,N-Compounds

(2012) Jian-Jun Feng et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective, NHC-Catalyzed Annulations of Trisubstituted Enals and CyclicN-Sulfonylimines via α,β-Unsaturated Acyl Azoliums

(2012) Alberto G. Kravina et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Continuum of Progress: Applications of N-Hetereocyclic Carbene Catalysis in Total Synthesis

(2012) Javier Izquierdo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Asymmetric Michael Addition of Diaryl Phosphine Oxides to α,β-Unsaturated N-Acylated Oxazolidin-2-ones

(2012) Depeng Zhao et al.   Chemistry-An Asian Journal

Asymmetric Synthesis of Enaminophosphines via Palladacycle-Catalyzed Addition of Ph2PH to α,β-Unsaturated Imines

(2012) Yinhua Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Phosphapalladacycles as Efficient Catalysts for the Asymmetric Hydrophosphination of Substituted Methylidenemalonate Esters: Direct Access to Functionalized Tertiary Chiral Phosphines

(2012) Chang Xu et al.   ORGANOMETALLICS

Extending NHC-Catalysis: Coupling Aldehydes with Unconventional Reaction Partners

(2011) Akkattu T. Biju et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Asymmetric NHC-Catalyzed Hydroacylation of Unactivated Alkenes

(2011) Isabel Piel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed 1,4-addition of diarylphosphines to α,β-unsaturated N-acylpyrroles

(2011) Dan Du et al.   CHEMICAL COMMUNICATIONS

Catalytic asymmetric construction of tetrasubstituted carbon stereocenters by conjugate addition of dialkyl phosphine oxides to β,β-disubstituted α,β-unsaturated carbonyl compounds

(2011) Depeng Zhao et al.   CHEMICAL COMMUNICATIONS

Employing homoenolates generated by NHC catalysis in carbon–carbon bond-forming reactions: state of the art

(2011) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in metal catalyzed asymmetric addition of phosphorus nucleophiles

(2011) Depeng Zhao et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Preparation ofP-Chiral Phosphine Oxides

(2011) Harry Adams et al.   ORGANIC LETTERS

Palladium-Catalyzed 1,4-Addition of Diarylphosphines to α,β-Unsaturated Aldehydes

(2011) Yun-Rong Chen et al.   ORGANIC LETTERS

Direct Synthesis of Chiral Tertiary DiphosphinesviaPd(II)-Catalyzed Asymmetric Hydrophosphination of Dienones

(2011) Yinhua Huang et al.   ORGANIC LETTERS

EnantioselectiveN-Heterocyclic Carbene-Catalyzed Michael Addition to α,β-Unsaturated Aldehydes by Redox Oxidation

(2011) Zi-Qiang Rong et al.   ORGANIC LETTERS

Catalytic enantioselective Steglich rearrangements using chiral N-heterocyclic carbenes

(2011) Craig D. Campbell et al.   TETRAHEDRON-ASYMMETRY

Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions

(2010) Yin Wei et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(ii)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines

(2010) Yinhua Huang et al.   CHEMICAL COMMUNICATIONS

Zinc-Mediated Asymmetric Additions of Dialkylphosphine Oxides to α,β-Unsaturated Ketones andN-Sulfinylimines

(2010) Depeng Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines

(2010) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Hydrophosphinylation of α,β-UnsaturatedN-Acylpyrroles: Application of Dialkyl Phosphine Oxides in Enantioselective Synthesis of Chiral Phosphine Oxides or Phosphines

(2010) Depeng Zhao et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Hydrophosphination of α,β-Unsaturated Aldehydes: Development, Mechanism and DFT Calculations

(2008) Ismail Ibrahem et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent advances in carbon–carbon bond-forming reactions involving homoenolates generated by NHC catalysis

(2008) Vijay Nair et al.   CHEMICAL SOCIETY REVIEWS