4.7 Article

Rosin acid modification of bamboo powder and thermoplasticity of its products based on hydrothermal pretreatment

期刊

ADVANCED COMPOSITES AND HYBRID MATERIALS
卷 4, 期 3, 页码 584-590

出版社

SPRINGERNATURE
DOI: 10.1007/s42114-021-00266-5

关键词

Bamboo; Rosin acid; Hydrothermal pretreatment; Thermoplasticity; Modification

资金

  1. National Natural Science Foundation of China [31760195, 31971741]
  2. Specific Research Project of Guangxi for Research Bases and Talents [AD18126005]
  3. Science and Technology Research Program of Yunnan Province [2018FB066]

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By esterification reaction, natural rosin acid was efficiently grafted onto bamboo powder to enhance its thermoplasticity, resulting in improved C1/C3 ratio, decreased crystallization index, smooth surface, and a glass transition temperature of 200 degrees Celsius for the modified material BP-LHW-RA. This work offers a green and feasible approach to prepare bio-based materials with desired thermoplasticity.
Natural chemicals obtained from the renewable resources were widely used in the modification of plant fibers. In this report, in order to develop thermoplasticity of materials, the bamboo powder (BP) after hydrothermal pretreatment (BP-LHW) was efficiently modified with natural rosin acid (BP-LHW-RA) by esterification reaction under heterogeneous condition. The results indicate that the modified BP-LHW-RA presents a strong peak at 1743 cm(-1) in the FT-IR spectra, which attributed to the -C = O vibration of the ester group formed by the reaction between rosin acid and the BP-LHW, confirming that BPLHW was successfully grafted with rosin acid. The C1/C3 ratio of BP-LHW-RA increased 1.35 times as compared with BP-LHW in XPS analysis. Meanwhile, the crystallization index of BP-LHW-RA decreased by 4.62%, and its surface became smooth and full. Moreover, the glass transition temperature of BP-LHW-RA was 200 degrees C. The work presents a green and feasible route to prepare bio-based materials with desired thermoplasticity by grafting natural rosin onto biomass substrate.

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