Stereoselective gem-Difluorovinylation of gem-Difluorinated Cyclopropanes Enabled by Ni/Pd Cooperative Catalysis

Rhodium Catalyzed Regioselective C−H Allylation of Simple Arenes via C−C Bond Activation of Gem‐difluorinated Cyclopropanes

(2021) Zhong-Tao Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium‐Catalyzed Defluorinative Alkylation of gem ‐Difluorocyclopropanes: Switching Regioselectivity via Simple Hydrazones

(2021) Leiyang Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu/Pd-Catalyzed cis-Borylfluoroallylation of Alkynes for the Synthesis of Boryl-Substituted Monofluoroalkenes

(2021) Ayman M. Y. Suliman et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Allylation of Electron-Deficient Polyfluoroarenes with gem-Difluorinated Cyclopropanes

(2021) Ping-Xin Zhou et al.   ORGANIC LETTERS

Rhodium-Catalyzed Direct Allylation of Simple Arenes by Using Gem-Difluorinated Cyclopropanes as Allyl Surrogates

(2021) Ying Xia et al.   SYNLETT

Access to Divergent Fluorinated Enynes and Arenes via Palladium-Catalyzed Ring-Opening Alkynylation of gem-Difluorinated Cyclopropanes

(2020) Ebrahim-Alkhalil M. A. Ahmed et al.   ORGANIC LETTERS

Sulfonate Versus Sulfonate: Nickel and Palladium Multimetallic Cross-Electrophile Coupling of Aryl Triflates with Aryl Tosylates

(2020) Kai Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Nickel-/Palladium-Catalyzed Reductive Cross-Coupling Reactions between Two Phenol Derivatives

(2020) Baojian Xiong et al.   ORGANIC LETTERS

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions

(2020) Kelsey E. Poremba et al.   ACS Catalysis

LiCl-Accelerated Multimetallic Cross-Coupling of Aryl Chlorides with Aryl Triflates

(2019) Liangbin Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Stereoselective Defluorination Arylation/Alkenylation/Alkylation of gem-Difluorinated Cyclopropanes

(2019) Ebrahim-Alkhalil M. A. Ahmed et al.   ORGANIC LETTERS

Generation of Organozinc Reagents by Nickel Diazadiene Complex Catalyzed Zinc Insertion into Aryl Sulfonates

(2019) Philippe Klein et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Ring-Opening Coupling of gem-Difluorocyclopropanes for the Construction of 2-Fluoroallylic Sulfones

(2019) Jiabin Ni et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition Metal-Mediated and -Catalyzed C-F Bond Activation via Fluorine Elimination

(2018) Takeshi Fujita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multimetallic Ni- and Pd-Catalyzed Cross-Electrophile Coupling To Form Highly Substituted 1,3-Dienes

(2018) Astrid M. Olivares et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Phenol Derivatives with Umpolung Aldehydes Catalyzed by Nickel

(2018) Leiyang Lv et al.   ACS Catalysis

N2H4 as traceless mediator for homo- and cross- aryl coupling

(2018) Leiyang Lv et al.   Nature Communications

Ring-Opening Diarylation of Siloxydifluorocyclopropanes by Ag(I) Catalysis: Stereoselective Construction of 2-Fluoroallylic Scaffold

(2017) Xiaoning Song et al.   ORGANIC LETTERS

China's flourishing synthetic organofluorine chemistry: innovations in the new millennium

(2017) Qinghe Liu et al.   National Science Review

Catalytic C–F bond activation of geminal difluorocyclopropanes by nickel(i) complexes via a radical mechanism

(2016) Jan Wenz et al.   CHEMICAL COMMUNICATIONS

Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles

(2015) Daniel J. Weix   ACCOUNTS OF CHEMICAL RESEARCH

Pd-Catalyzed Regioselective Activation ofgem-Difluorinated Cyclopropanes: A Highly Efficient Approach to 2-Fluorinated Allylic Scaffolds

(2015) Jun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates

(2015) Laura K. G. Ackerman et al.   NATURE

Nickel-catalyzed reductive coupling of alkyl halides with other electrophiles: concept and mechanistic considerations

(2015) Jun Gu et al.   Organic Chemistry Frontiers

Cross-Electrophile Coupling: Principles of Reactivity and Selectivity

(2014) Daniel A. Everson et al.   JOURNAL OF ORGANIC CHEMISTRY

Ni-Catalyzed Direct Reductive Amidation via C–O Bond Cleavage

(2014) Arkaitz Correa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source

(2011) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic approaches to monofluoroalkenes

(2011) Grégory Landelle et al.   CHEMICAL SOCIETY REVIEWS

Fluoroalkene modification of mercaptoacetamide-based histone deacetylase inhibitors

(2009) Satoshi Osada et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Isocombretastatins A versus Combretastatins A: The ForgottenisoCA-4 Isomer as a Highly Promising Cytotoxic and Antitubulin Agent

(2009) Samir Messaoudi et al.   JOURNAL OF MEDICINAL CHEMISTRY

Peptide bond mimicry by (E)-alkene and (Z)-fluoroalkene peptide isosteres: synthesis and bioevaluation of α-helical anti-HIV peptide analogues

(2009) Shinya Oishi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS